Determine the number of atoms in 3.14 g gold

Answers

Answer 1
The answer for sure is 95.99922

Related Questions

Ammonium perchlorate is the solid rocket fuel used by the U.S. Space Shuttle. It reacts with itself to produce nitrogen gas , chlorine gas , oxygen gas , water , and a great deal of energy. What mass of water is produced by the reaction of of ammonium perchlorate? Be sure your answer has the correct number of significant digits.

Answers

Answer:

2.9 g of water are produced by 9.6 g of ammonium perchlorate

Note: The question is incomplete. The complete question is given below:

Ammonium perchlorate (NH₄ClO₄) is the solid rocket fuel used by the U.S. Space Shuttle. It reacts with itself to produce nitrogen gas (N₂) , chlorine gas (Cl₂), oxygen gas (O₂), water (H₂O) , and a great deal of energy. What mass of water is produced by the reaction of 9.6 g of ammonium perchlorate? Be sure your answer has the correct number of significant digits.

Explanation:

The reaction of ammonium perchlorate (NH₄ClO₄) to produce nitrogen gas (N₂) , chlorine gas (Cl₂), oxygen gas (O₂), water (H₂O) is shown in the balanced chemical equation given below:

2 NH₄ClO₄ →  N₂ +  Cl₂ + 2 O₂ + 4 H₂O

From the equation, 2 moles of ammonium perchlorate produces 4 moles of water, i.e. mole ratio of NH₄ClO₄ to H₂O = 2 : 4 = 1 : 2

molar mass of ammonium perchlorate, NH₄ClO₄ = (14 + 4 * 1 + 35.5 +16 * 4) = 117.5

molar mass of water,  H₂O = (2 * 1 + 16) = 18.0 g

mass of water produced = moles of ammonium perchlorate * 2 * molar mass of water

moles of perchlorate = mass / molar mass = 9.6/117.5

mass of water produced = 9.6/117.5 * 2 * 18.0 g  = 2.94 g of water

Therefore, 2.9 g of water are produced by 9.6 g of ammonium perchlorate

Please help me
5. Where is potential energy decreasing?
А B C D

Answers

Answer:

D

Explanation:

I believe it is D. your kinetic energy would be at b. A, the cart would be going at a constant rate, because there is no hill or steep slope.

B it is goin down hill and that means it decreased

if the amounts of greenhouse gases such as carbon dioxide and methane continue to increase in the atmosphere, what will happen to the average temperature of Earth?

Answers

I honestly have no idea but brainly is making me answer this :)

If greenhouse gases in the atmosphere continues to increase, then the  

average temperature of Earth will increase too.

Greenhouse gases such as carbon dioxide and methane deplete the ozone

layer which shields the earth from radiations from the Sun. An increase in

these gases will therefore allow for more radiations to get to the earth.

This therefore brings about an increase in the average temperature of the

earth.

Read more about greenhouse gases on https://brainly.com/question/20349818

The following pairs of soluble solutions can be mixed. In some cases, this leads to the formation of an insoluble precipitate. Decide, in each case, whether or not an insoluble precipitate is formed.

a. AlCl3 and K3PO4
b. RbCO3 and NaCl
c. Na2CO3 and MnCl2
d. K2S and NH4Cl
e. CaCl2 and (NH4)2CO3

Answers

Answer:

See explanation

Explanation:

Let us see what happens when each solution is mixed;

a) AlCl3(aq) + K3PO4(aq) ------> 3KCl(aq) + AlPO4(s)

A precipitate is formed here

b) RbCO3(aq) + NaCl(aq) -------> This is an impossible reaction hence no solid precipitate is formed here

c) MnCl2(aq) + Na2CO3(aq) → 2NaCl(aq) + MnCO3(s)

A precipitate is formed.

d) K2S(aq) + 2NH4Cl(aq) ------> 2KCl(aq) + (NH4)2S(aq)

No solid precipitate is formed

e) CaCl2(aq) + (NH4)2CO3(aq) → CaCO3(s) + 2NH4Cl(aq)

A solid precipitate is formed

ASAP PLEASE!!! Approximately how much more of the solute potassium chlorate can be added to water if the temperature increases from 30°C to 65°C?

Answers

Answer: You have a solution of potassium chlorate containing 4 g at 65º C. How many additional grams of solute must be added to it, to make the solution saturated ? approximately 26 more grams [the solubility of potassium chlorate is ... water. The solution is allowed to cool. At what new temperature would crystals begin to.

Explanation:

What is the relationship between radius and diameter

Answers

Answer:

the radius is half the diameter

The radius of a circle is equal to half the diameter.

3.00 g of a fuel (MW = 650.0 g/mol) is combusted in a bomb calorimeter. The temperature of the calorimeter increases by 25.0 degrees Celsius. The heat capacity for the calorimeter has been determined to be 9.001kJ/C. What is the heat of reaction (in kJ/mol)?​

Answers

Answer:

-4.88 × 10⁴ kJ/mol

Explanation:

Step 1: Calculate the heat gained by the calorimeter (Qcal)

We will use the following expression.

Qcal = C × ΔT

where,

C: heat capacity of the calorimeterΔT: temperature change

Qcal = 9.001 kJ/°C × 25.0°C = 225 kJ

Step 2: Calculate the heat released by the fuel

According to the law of conservation of energy, the sum of the heat released by the fuel (Qf) and the heat absorbed by the calorimeter is zero.

Qf + Qcal = 0

Qf = -Qcal = -225 kJ

Step 3: Calculate the heat of reaction in kJ/mol

3.00 g of a fuel (MW = 650.0 g/mol) released 225 kJ of heat. The heat of reaction is:

-225 kJ/3.00 g × 650.0 g/mol = -4.88 × 10⁴ kJ/mol

Which affects both deep water and surface currents in the ocean? the wind the temperature of the water the Coriolis effect None of the above​

Answers

Answer:

the wind and the temperature of water both drive ocean currents

Answer:

B. Write 'T' for true or 'F' for false statements :

1. Publisher works only with document in fixed shapes and sizes.

2. Viewing tools are only for editing purpose.

3. Text box icon is found in Styles group.

4. Publisher does not allow you to add images to your document.

5. Margin guides are blue lines that mark the edges.

What is the correct sequence of chemical transformations with the correct phases?

Answers

Answer:

1. Cu(s) 2. Cu(NO3)2 (aq) 3. Cu(OH)2 (s) 4. CuO (s) 5. CuSO4 (aq)  6. Cu(s)

Explanation:

Nickel carbonyl decomposes to form nickel and carbon monoxide, like this:
Ni(CO)4 → Ni + 4CO

At a certain temperature, a chemist finds that a 2.7L reaction vessel containing a mixture of nickel carbonyl, nickel, and carbon monoxide at equilibrium has the following composition:

Compound Amount
Ni(CO)4 0.597g
Ni 12.7g
CO 1.98g

Calculate the value of the equilibrium constant for this reaction. Round your answer to significant digits.

Answers

Answer: The value of the equilibrium constant for this reaction is [tex]2.8\times 10^{-5}[/tex]

Explanation:

To calculate the moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text {Molar mass}}[/tex]

Moles of  [tex]Ni(CO)_4[/tex] = [tex]\frac{0.597g}{170.7g/mol}=0.0035moles[/tex]

Moles of  [tex]Ni[/tex] =  [tex]\frac{12.7g}{58.7g/mol}=0.216moles[/tex]

Moles of  [tex]CO[/tex] =  [tex]\frac{1.98g}{28.01g/mol}=0.071moles[/tex]

Volume of solution = 2.7 L

Equilibrium concentration of [tex]Ni(CO)_4[/tex] = [tex]\frac{0.0035mol}{2.7L}=1.29\times 10^{-3}M[/tex]

Equilibrium concentration of [tex]Ni[/tex] = [tex]\frac{0.216mol}{2.7L}=0.08M[/tex]

Equilibrium concentration of [tex]CO[/tex] = [tex]\frac{0.071mol}{2.7L}=0.026M[/tex]

The given balanced equilibrium reaction is,

                            [tex]Ni(CO)_4\rightleftharpoons Ni+4CO[/tex]

The expression for equilibrium constant for this reaction will be,

[tex]K_c=\frac{[Ni]^1\times [CO]^4}{[Ni(CO_4]^1}[/tex]

Now put all the given values in this expression, we get :

[tex]K_c=\frac{(0.08)^1\times (0.026)^4}{(1.29\times 10^{-3})^1}[/tex]

[tex]K_c=2.8\times 10^{-5}[/tex]

Thus the value of the equilibrium constant for this reaction is [tex]2.8\times 10^{-5}[/tex]

Combustion of hydrocarbons such as octane (C_8H_18) produces carbon dioxide, a "greenhouse gas." Greenhouse gases in the Earth's atmosphere can trap the Sun's heat, raising the average temperature of the Earth. For this reason there has been a great deal of international discussion about whether to regulate the production of carbon dioxide.
1. Write a balanced chemical equation, including physical state symbols, for the combustion of liquid octane into gaseous carbon dioxide and gaseous water.
2. Suppose 0.330 kg of octane are burned in air at a pressure of exactly 1 atm and a temperature of 10.0 ?C. Calculate the volume of carbon dioxide gas that is produced. Round your answer to 3 significant digits.

Answers

Answer: 1. [tex]2C_8H_{18}(l)+25O_2(g)\rightarrow 16CO_2(g)+18H_2O(g)[/tex]

2. The volume of carbon dioxide gas that is produced is 537 L

Explanation:

1. Combustion is defined as the type of chemical reaction where a hydrocarbon is combusted in the presence of oxygen to give carbon dioxide and water.

The balanced reaction for combustion of octane is:

[tex]2C_8H_{18}(l)+25O_2(g)\rightarrow 16CO_2(g)+18H_2O(g)[/tex]

2.

To calculate the moles :

[tex]\text{Moles of solute}=\frac{\text{given mass}}{\text{Molar Mass}}[/tex]   [tex]\text{Moles of octane}=\frac{0.330\times 1000g}{114.23g/mol}=2.89moles[/tex]

According to stoichiometry:

2 moles of octane produce = 16 moles of carbon dioxide

2.89 moles of octane produce = [tex]\frac{16}{2}\times 2.89=23.1moles[/tex] of carbon dioxide

According to ideal gas equation:

[tex]PV=nRT[/tex]

P = pressure of gas = 1 atm

V = Volume of gas = ?

n = number of moles = 23.1

R = gas constant =[tex]0.0821Latm/Kmol[/tex]

T =temperature =[tex]10.0^0C=(10+273)K=283K[/tex]

[tex]V=\frac{nRT}{P}[/tex]

[tex]V=\frac{23.1\times 0.0821Latm/K mol\times 283K}{1atm}=537L[/tex]

Thus the volume of carbon dioxide gas that is produced is 537 L

How much heat (in kJ) would need to be removed to cool 150.3 g of water from 25.60°C to -10.70°C?

Answers

Answer:

Q = -22.9 kJ

Explanation:

Given that,

Mass of water, m = 150.3 g

Water gets cool from 25.60°C to -10.70°C.

The specific heat of water, c = 4.2 J/g°C

The formula for heat needed is given by :

[tex]Q=mc\Delta T\\\\Q=150.3\times 4.2 \times (-10.7-25.6)\\\\Q=-22914.738\\\\or\\\\Q=22.9\ kJ[/tex]

So, 22.9 kJ of heat is needed to be removed to cool.

O2 + 2C0-2CO2

4.62 grams of oxygen and 2.98 grams of carbon monoxide are placed in a closed

reaction vessel and the mixture is ignited. Combustion occurs until one of the

gases is totally consumed.

1. Identify the limiting reagent and the excess reagent

2. Determine the amount of excess reagent.

3. Calculate the grams of carbon dioxide produced.

Answers

Answer: 1. [tex]CO[/tex] is the limiting reagent and [tex]O_2[/tex] is the excess reagent.

2. 2.91 g of excess reagent

3. 4.66 g of carbon dioxide produced.

Explanation:

To calculate the moles :

[tex]\text{Moles of solute}=\frac{\text{given mass}}{\text{Molar Mass}}[/tex]    

[tex]\text{Moles of} CO=\frac{2.98g}{28g/mol}=0.106moles[/tex]

[tex]\text{Moles of} O_2=\frac{4.62g}{32g/mol}=0.144moles[/tex]

[tex]O_2+2CO\rightarrow 2CO_2[/tex]  

According to stoichiometry :

2 moles of [tex]CO[/tex] require = 1 mole of [tex]O_2[/tex]

Thus 0.106 moles of [tex]CO[/tex] will require=[tex]\frac{1}{2}\times 0.106=0.053moles[/tex]  of [tex]O_2[/tex]

Thus [tex]CO[/tex] is the limiting reagent as it limits the formation of product and [tex]O_2[/tex] is the excess reagent.

Amount of excess reagent = ( 0.144-0.053) moles = 0.091 moles

Mass of excess reagent [tex]O_2=moles\times {\text {Molar mass}}=0.091moles\times 32g/mol=2.91g[/tex]

As 2 moles of [tex]CO[/tex] give = 2 moles of [tex]CO_2[/tex]

Thus 0.106 moles of [tex]CO[/tex] give =[tex]\frac{2}{2}\times 0.106=0.106moles[/tex]  of [tex]CO_2[/tex]

Mass of [tex]CO_2=moles\times {\text {Molar mass}}=0.106moles\times 44g/mol=4.66g[/tex]

Which of the following would form a spontaneous reaction at 298 K?
O A. AH = 28 kJ/mol, AS = 0.109 kJ/(mol-K)
B. AH = 31 kJ/mol, AS = 0.093 kJ/(mol-K)
C. AH = 8.7 kJ/mol, AS = 0.008 kJ/(mol-K)
D. AH = 205 kJ/mol, AS = 0.210 kJ/(mol-K)

Answers

Answer:

A

∆H = 28 kJ/mol, ∆S = 0.109 kJ/(mol-k)

Explanation:

A P E X

The spontaneous reaction at 298 K is the one having

ΔH = 28 kJ/mol, ΔS = 0.109 kJ/(mol-K)

We know the formula of Gibb's free energy as-

ΔG = ΔH - TΔS

ΔG = 28 - (298 × 0.109)

ΔG = -4.48

If a reaction is spontaneous, change in Gibb's free energy is negative and change in entropy is positive.

Therefore, The spontaneous reaction at 298 K is the one having

ΔH = 28 kJ/mol, ΔS = 0.109 kJ/(mol-K)

To learn more about spontaneous reaction click:

https://brainly.com/question/13790391

#SPJ7

For the reaction shown, drsw the major(s) expected product.​

Answers

Answer:

2

Explanation:

3. How many particles are present in 13.4 moles of carbon dioxide?
8.07. 1024 particles
04.49. 1022 particles
6.02. 1024 particles
6.02. 1023 particles

Answers

Answer:

[tex]\boxed {\boxed {\sf 8.07 *10^{24} \ particles}}[/tex]

Explanation:

To convert from moles to representative particles, Avogadro's number: 6.02*10²³ is used. This number tells us the amount of particles in 1 mole of a substance. We can use it as a ratio.

[tex]\frac {6.02*10^{23} \ particles}{1 \ mol \ CO_2}}[/tex]

Multiply by the given number of moles.

[tex]13.4 \ mol \ CO_2 *\frac {6.02*10^{23} \ particles}{1 \ mol \ CO_2}}[/tex]

The moles of carbon dioxide will cancel out.

[tex]13.4 *\frac {6.02*10^{23} \ particles}{1}}[/tex]

The denominator of 1 can be ignored and this becomes a simple multiplication problem.

[tex]13.4 * {6.02*10^{23} \ particles[/tex]

[tex]8.0668*10^{24} \ particles[/tex]

The original number of moles has 3 significant figures, so our answer must have the same. For the number we calculated, that is the hundredth place. The 6 in the thousandth place tells us round the 6 to a 7.

[tex]8.07 *10^{24} \ particles[/tex]

13.4 moles of carbon dioxide has approximately 8.07*10²⁴ particles.

True or false, rewrite it to make it true.
To balance a chemical equation, only the subscripts of a reactant and product can be changes

Answers

Answer:

false

Explanation:

Gallium (Ga, 69.723 g/mol) is a metalloid obtained from its salts during the smelting of ores of other elements, like Zinc. has broad applicability in the electronics industry. It is also used as a safe replacement for mercury in thermometers as it melts at 29.8 °C and has a heat of fusion of 5.59 kJ/mol. What is the entropy change of 22 g of gallium in J/K as it melts when placed on a surface at 29.8°C?

Answers

Answer:

4.255 J/ K

Explanation:

Given data :

mass of Gallium = 16 gm

molar mass = 69.723 g/mol

hence no of moles = 16 / 69.723 = 0.23 moles --------- ( 1 )

Δh ( heat fusion ) = 5.59 KJ/mol

Temperature = 29.8°C = 302.8 k

Determine the entropy change of gallium

Δs ( entropy change ) =  heat fusion / temperature

 = ( 5.59 * 1000) J/mol / 302.8 = 18.46 J/k*mol

Hence entropy change of gallium

= Δs * no of Gallium moles

= 18.46 * 0.23 = 4.255 J/ k

I hope this is right haha

describe one similarity and one difference between amylopectin and glycogen?

Answers

Answer: The main difference between amylopectin and glycogen is that amylopectin is an insoluble form whereas glycogen is a soluble form. The 1,4-alpha glycosidic bonds form the linear chain of both amylopectin and glycogen while 1,6-alpha glycosidic bonds form the branches.

Explanation:

what is elimination reaction​

Answers

It’s in the link below to help u

What is the name of PbS2

Answers

Answer:

Lead  sulfide.

Explanation:

how many core electrons does magnesium ion have​

Answers

Answer:

10 core electrons

Explanation:

Answer:

Magnesium has 10 core electrons

plz someone help me i dont get this and i need to finish this

Answers

Answer:

The height of A is 900

Explanation: Beside A, there is a number which explains what the height is so the answer is A.

What is the number of moles in 546 g strontium nitrite?

A. 0.388 mol
B. 2.58 mol
C. 329 mol
D. 3.04 mol

Answers

The answer is 2.58 mol

How is this effect of dissolved
substances important in nature?​

Answers

Explanation:

Water is called the "universal solvent" because it is capable of dissolving more substances than any other liquid. This is important to every living thing on earth. It means that wherever water goes, either through the air, the ground, or through our bodies, it takes along valuable chemicals, minerals, and nutrients.

Nitrogen monoxide is produced by combustion in an automobile engine. For the following reaction, 6.42 grams of nitrogen monoxide are mixed with excess oxygen gas . The reaction yields 8.53 grams of nitrogen dioxide . nitrogen monoxide ( g ) oxygen ( g ) nitrogen dioxide ( g ) What is the theoretical yield of nitrogen dioxide

Answers

Explanation:

[tex]6.42 \times \frac{1}{30} \times \frac{1}{1} \times \frac{46}{1} = 9.844[/tex]

[tex]8.53 \div 9.844 \times 100 = 86.65\%[/tex]

Give the IUPAC name for the following alkanes and cycloalkanes​

Answers

Answer:

1.3-bromo,2-chloro,4-floro hexane

3.bromocyclo pentane

Put the following experimental steps for the Acid-Base Equilibria (HCL and NaOH) in the correct order:

a. Perform a scout colorimetric titration. of diluted vinegar with NaOH.
b. One pair performs a careful colorimetric titration of diluted vinegar with NaOH and the other pair performs a potentiometic titration of diluted vinegar with NaOH.
c. Perform a scout colorimetric titration of HCl with NaOH.
d. One pair performs a careful colorimetric titration of HCl with NaOH and the other pair performs a potentiometic titration of HCl with NaOH.
e. Dilute a solution of commercial vinegar to prepare it for titration.

Answers

Answer:

e. Dilute a solution of commercial vinegar to prepare it for titration.

a. Perform a scout colorimetric titration of diluted vinegar with NaOH.

b. One pair performs a careful colorimetric titration of diluted vinegar with NaOH and the other pair performs a potentiometric titration of diluted vinegar with NaOH.

c. Perform a scout colorimetric titration of HCL with NaOH.

d. One pair performs a careful colorimetric titration of HCL with NaOH and the other pair performs a potentiometric titration of HCL with NaOH.

Explanation:

Titration is a process in which acid and base are introduced together to determine unknown concentration of acid or base. This is also known as neutralization reaction. The chemical process form salt and water as by products because acid molecules react with base molecules.

The experimental steps for the Acid-Base Equilibria in the correct order is e, a, b, c and d.

What is titration?

Titration is a process in which we determine the concentration of any unknown acid and base by titrating them with the standard known concentration of base or acid.

In potentiometric titration, in the place of indicator potential difference is used across the analyte of electrolytic solution. And in colorimetric titration, absorbance of light is measured by the solution. Process of method which is involved in the titration is:
e. Dilute a solution of commercial vinegar to prepare it for titration.

a. Perform a scout colorimetric titration of diluted vinegar with NaOH.

b. One pair performs a careful colorimetric titration of diluted vinegar with NaOH and the other pair performs a potentiometric titration of diluted vinegar with NaOH.

c. Perform a scout colorimetric titration of HCL with NaOH.

d. One pair performs a careful colorimetric titration of HCL with NaOH and the other pair performs a potentiometric titration of HCL with NaOH.

Hence correct sequence is e, a, b, c and d.

To know more about titration, visit the below link:
https://brainly.com/question/12162076

Consider this chemical equation:
2AgNO3(aq) + Cu(s) → Cu(NO3)2(aq) + 2Ag(s)
Which substances dissolve in solution? Select all
that apply.
AgNO3
Cu
Cu(NO3)2
Ag
Answer is:AgNO3 and Cu(NO3)2

Answers

Answer:

the answer is very correct as AgNO3 and Cu(NO3)2

Answer:

A,C

Explanation:

the person above me is correct

does anyone know the answer to this​

Answers

It’s Tetracarbon dioxide :)
Other Questions
my teacher just put out an email saying that next month's assignment is to make a small clay figure of ourselves, do you think I should use this picture? t a 7x? 2 PLS HELP ME!!describe an example of a situation when the graph would be represented with a constant interval. Helppppp!!!!!!!!!!!!!! It's due Today!!!!!!!!!!!! NO LINK PLEASE!!!!!!!!!!!!!!!!!!!!!!!!!! WILL GIVE BRAINLIESTIn your own words, please explain how gender of nouns work in the Spanish language. I'd like to see 2 general rules, 2 exceptions, and examples for every case.will report if u write absurd and irrelevant things. Can anyone help me with this? Question 2 of 5Based on your knowledge of roots and affixes, which is the most likelydefinition for the word academician?A. HomeworkB. ProfessorC. DentistD. School In what way were the Mongol invasions of Russia and Persia similar?A. In both regions, the Mongols established an irrigation system to help make agriculture successful.B. In both regions, the Mongols allowed native leaders to serve in administrative positions.C. In both regions, the Mongols established strong administrative policies, which created stability.D. In both regions, the Mongols joined the native religions in order to please the conquered people. PLEASE HELP MEEE I NEED HELP PLEASEWrite a mathematical sentence that expresses the information given below. Use p as your variable name. If necessary: type < = to mean < or > = to mean . A football team had 52 players at the start of the season, but then some players left the team. After that, the team had 43 players. Patrick borrowed his friend's John's car to impress a young lady he was dating. It was a new luxury car that John saved four years to purchase. The paint on the car turned coors under various climatic and light conditions. While on the date, Patrick drove the car down a public road that had just been repaved with hot oil and gravel. The result was streaks of hot oil glued to the sides of the car and several nicks in the paint from flying rocks. Patrick then parked in front of his favorite restaurant, a sports pub on the far side of town. While in the restaurant, Patrick heard a special weather report that a thunderstorm with large hail was sweeping across the area and would arrive over the restaurant in ten minutes. Unfortunately for John's car, the date was going too well to break off and move the car under cover. Consequently, the hail left a multitude of pock marks on the top of the car. Is Patrick legally responsible for the damage done by the gravel, oil, and hail? Why or why not? Find the premiemter of the poly gon shown.pls help pls Identify the subject of this sentence: The bus lost its wheel.a) busb) lostc)wheel Suppose that a sequence is defined as follows. And find the next 4 terms.a1= -1an=-4an-1 +2n>= 2 what does nbt stand for Jocelyn's income was $243,358. How much did she pay in Social Security tax? How much did Jocelyn pay for Medicare tax? What total amount was remitted on Jocelyn's behalf for Social Security and Medicare? Determine the speed in km/h if you travel a distance of 160 km in 2 hours Help me please with math please help me please i really need help please what is 184.26 in standard form What is the reason for President Roosevelt's enormous popularity?A. He worked to pass laws that gave women and young people theright to vote.O B. He promised to keep American soldiers out of harm's way duringWorld War I.C. He was a civil rights activist and was responsible for many lawsagainst discrimination.O D. Americans believed his policies helped the country recover fromthe Depression