In all ortho-para directing groups, the atom attached to the aromatic ring possesses an unshared pair of electrons. The ortho-para directing groups in organic chemistry refer to a group of functional groups that have the ability to direct substitution reactions towards either ortho or para positions in the aromatic ring.
The mechanism behind this behavior is attributed to the resonance or inductive effects of the substituent functional group.The ortho-para directing groups, unlike meta-directing groups, don't block the substitution reaction of the aromatic ring. They favor substitution at ortho and para positions of the ring. The feature common to all ortho-para directing groups is that the atom directly attached to the aromatic ring has a lone pair of electrons. This property allows them to stabilize positive charges generated on the aromatic ring during substitution reactions.
Hence, they direct the substitution reaction towards the ortho- or para-position. For instance, in nitrobenzene, the nitro group directs the incoming electrophile towards the ortho and para position as the nitrogen atom attached to the aromatic ring has a lone pair of electrons.
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Answer:
C. The atom directly attached to the aromatic ring is more electronegative than carbon.
Step-by-step explanation:
In ortho-para directing groups, the atom directly attached to the aromatic ring is more electronegative than carbon. This electronegativity difference creates a polar bond, which allows for efficient delocalization of the positive charge in the arenium ion. This polarization facilitates the stabilization of positive charge and makes the ortho and para positions more favorable for electrophilic aromatic substitution reactions.
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1.Which country is found at 30 N latitude and 30E longitude?
Egypt Argentina
Brazil Algeria
2Which country is found at 30 N latitude and 90 W longitude?
Argentina United States Iran Russia
The country found at 30° N latitude and 30° E longitude is Egypt.
The country found at 30° N latitude and 90° W longitude is the United States.
1) The country found at 30° N latitude and 30° E longitude is Egypt. Latitude and longitude are geographical coordinates used to determine specific locations on the Earth's surface. Latitude measures the distance north or south of the equator, while longitude measures the distance east or west from the Prime Meridian (0° longitude).
When we look at the coordinates 30° N latitude and 30° E longitude, it indicates a location that is 30 degrees north of the equator and 30 degrees east of the Prime Meridian. By referring to a map or using a geographic information system (GIS), we can find that this location corresponds to the country of Egypt.
2) The country found at 30° N latitude and 90° W longitude is the United States. Again, by using latitude and longitude coordinates, we can determine specific locations on the Earth's surface. In this case, the coordinates 30° N latitude and 90° W longitude indicate a location that is 30 degrees north of the equator and 90 degrees west of the Prime Meridian.
By referring to a map or using GIS, we can identify that this location corresponds to a region within the United States. The United States is a large country that spans across multiple latitudes and longitudes, so it encompasses areas that can be found at 30° N latitude and 90° W longitude.
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A reducing elbow in a horizontal pipe is used to deflect water flow by an angle of 45° from the flow direction while accelerating it. The elbow discharges water into the atmosphere at 30kg/s. The cross-sectional area of the elbow is 150cm² at the inlet and 25cm² at the exit. The elevation difference between the centers of the exit and the inlet is 40 cm. The total energy loss through the bend is 1.4169m of water. Determine the inlet pressure into the reducing bend Determine the total force in the X and Y directions Determine the pressure force in the X and Y directions Determine the anchoring force needed to hold the elbow in place
The inlet pressure into the reducing bend is 1.8 x [tex]10^6[/tex] Pa, the total force in the X and Y directions are 2.638 x [tex]10^5[/tex] N and 294.3 N, respectively, the pressure force in the X and Y directions are 4243.4 N and 9.81 N, respectively, and the anchoring force needed to hold the elbow in place is 4249.5 N.
How to calculate the inlet pressureFirst, let's determine the velocity of the water at the inlet and exit of the elbow
At the inlet:
Q = Av, where Q is the volumetric flow rate, A is the cross-sectional area, and v is the velocity of the water.
150 cm² = 0.015 m²
Q = 30 kg/s
30 kg/s = 0.015 m² x v
v = 2000 m/s
At the exit:
25 cm² = 0.0025 m²
Q = 30 kg/s
30 kg/s = 0.0025 m² x v
v = 12000 m/s
inlet pressure can be determined using Bernoulli's equation
[tex]P_1 + (1/2) \rho v_1^2 + \rho gh_1 = P_2 + (1/2) \rho v_2^2 + \rho gh_2[/tex]
where P is the pressure, ρ is the density of water, v is the velocity, and h is the elevation difference.
Assuming that the pressure at the exit is atmospheric pressure (101325 Pa)
[tex]P_1 + (1/2)\rho v_1^2 + \rho gh_1 = 101325 Pa + (1/2)\rho v_2^2 + \rho gh_2[/tex]
Substitute the values
[tex]P_1 + (1/2)(1000 kg/m^3)(2000 m/s)^2 + (1000 kg/m^3)(9.81 m/s^2)(0.4 m) = 101325 Pa + (1/2)(1000 kg/m^3)(12000 m/s)^2 + (1000 kg/m^3)(9.81 m/s^2)(0 m)[/tex]
Solving for P₁, we get:
P₁ = 1.8 x [tex]10^6[/tex] Pa
To determine the total force in the X and Y directions
The total force in the X direction is equal to the change in momentum of the water as it flows through the elbow:
F_x = ρQv₂ cos(45°) - ρQv₁
Substitute the values
F_x = (1000 kg/m³)(30 kg/s)(12000 m/s)(1/√2) - (1000 kg/m³)(30 kg/s)(2000 m/s)
F_x = 2.638 x [tex]10^5[/tex] N
The total force in the Y direction is equal to the weight of the water
F_y = mg
F_y = (30 kg/s)(9.81 m/s²)
F_y = 294.3 N
To determine the pressure force in the X and Y directions:
The pressure force in the X direction is equal to the difference in pressure at the inlet and outlet of the elbow multiplied by the area of the elbow
F_px = (P₁ - P₂)A₂
F_px = (1.8 x [tex]10^6[/tex] Pa - 101325 Pa)(0.0025 m²)
F_px = 4243.4 N
The pressure force in the Y direction is equal to the weight of the water in the elbow:
F_py = ρVg
V = Ah
V = (0.0025 m²)(0.4 m)
V = 0.001 m³
F_py = (1000 kg/m³)(0.001 m³)(9.81 m/s²)
F_py = 9.81 N
To determine the anchoring force needed to hold the elbow in place
The anchoring force is equal to the vector sum of the pressure force and the weight of the elbow:
F_anchor = √(F_p[tex]x^2[/tex] + (F_y - F_py[tex])^2)[/tex]
F_anchor = √((4243.4 N[tex])^2[/tex] + (294.3 N - 9.81 [tex]N)^2)[/tex]
F_anchor = 4249.5 N
Therefore, the inlet pressure into the reducing bend is 1.8 x [tex]10^6[/tex] Pa, the total force in the X and Y directions are 2.638 x [tex]10^5[/tex] N and 294.3 N, respectively, the pressure force in the X and Y directions are 4243.4 N and 9.81 N, respectively, and the anchoring force needed to hold the elbow in place is 4249.5 N.
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conventional, rectangular flocculation basin is 38 ft. wide, 90 ft. long and 16 ft. deep. The flow through the basin is 24 MGD and the water horsepower input by the reel type paddles is 15 hp. The dynamic viscosity of water is 2.73 E -5 lb/sec/ft2 at 50 degrees Fahrenheit.
a. What is the nominal detention time?
b. What velocity gradient is induced by the reel paddles?
c. What is the GT value?
The nominal detention time is the time needed for a small particle of water in the system to flow from the inlet of the system to the outlet. The nominal detention time is 24.6 min. The velocity gradient is 7.5. The GT value is 184.5.
(a) The nominal detention time is the time needed for a small particle of water in the system to flow from the inlet of the system to the outlet. The formula for the nominal detention time is as follows;
Nominal detention time = Volume of basin / Flow rate
The volume of the basin is given by; V = L x W x DV
= 90 ft. x 38 ft. x 16 ft.
= 54,720 cubic feet
Note: 1 cubic foot = 7.48 gallons (US) Therefore, the volume of the basin in gallons is;
V = 54,720 cubic feet x 7.48 gallons/cubic feet = 409,369 gallons
Flow rate = 24 MGD = 24 x 1,000,000 / 1440 = 16,667 gallons/min
Nominal detention time = Volume of basin / Flow rate
Nominal detention time = 409,369 gallons / 16,667 gallons/min
Nominal detention time = 24.6 min
Therefore, the nominal detention time is 24.6 min.
(b) Velocity gradient is given by the formula; Velocity gradient, G = 8U / D
Where; U = water horsepower input by the reel type paddles
D = depth of the tank in ft
Velocity gradient, G = (8 x 15) / 16G
= 7.5
Therefore, the velocity gradient is 7.5.
(c) GT value is given by the formula; GT = G x t
Where; G = Velocity gradient
t = nominal detention time
GT = 7.5 x 24.6GT
= 184.5
Therefore, the GT value is 184.5.
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Determine the hybridization about Br in BrF_3. a.sp b. sp² c.sp³d d.sp³
The correct answer is d. sp³d. To determine the hybridization about Br (bromine) in BrF3 (bromine trifluoride), we need to count the number of regions of electron density around the central atom and apply the concept of hybridization.
In BrF3, bromine (Br) is bonded to three fluorine atoms (F). Additionally, there is one lone pair of electrons on bromine. The total number of regions of electron density is therefore 4.
The possible hybridization states for 4 regions of electron density are:
a. sp
b. sp²
c. sp³
d. sp³d
To determine the correct hybridization, we need to look at the geometry of the molecule.
In BrF3, the molecular geometry is trigonal bipyramidal, with three fluorine atoms bonded to the equatorial positions and the lone pair occupying one of the axial positions.
Based on the trigonal bipyramidal geometry, the hybridization of bromine (Br) in BrF3 is sp³d.
This means that the 4 electron density regions around bromine involve one s orbital, three p orbitals, and one d orbital, leading to the formation of five sp³d hybrid orbitals.
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4. Explain the interaction diagrams for reinforced concrete columns and divide into the three regions indicating three modes of failure and identify the three modes of failure? Balanced failure • Compression failure Tension failure
The interaction diagrams for reinforced concrete columns provide a graphical representation of the interaction between axial force and bending moment.
1. Balanced Failure: In this region, both compression and tension forces are present, but they are balanced. The column can resist both compression and tension loads without experiencing significant failure. The balanced failure occurs when the axial force is relatively small compared to the maximum axial capacity of the column. In this case, the column behaves like a pure compression member.
2. Compression Failure: In this region, the column experiences a high compressive force, causing the concrete to crush or fail in compression. The failure occurs when the axial force exceeds the maximum compressive strength of the concrete. This mode of failure is also known as crushing failure and can lead to significant damage to the column.
3. Tension Failure: In this region, the column experiences a high tensile force, causing the steel reinforcement to yield or fail in tension. The failure occurs when the axial force exceeds the tensile strength of the steel reinforcement. This mode of failure is also known as yielding failure and results in significant deformation and collapse of the column.
It is important to note that the interaction diagrams provide valuable information about the behavior of reinforced concrete columns under different loading conditions.
In summary, the interaction diagrams for reinforced concrete columns divide into three regions: balanced failure, compression failure, and tension failure. Balanced failure occurs when compression and tension forces are balanced, while compression failure occurs when the column fails in compression and tension failure occurs when the column fails in tension.
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Using the following balanced chemical equation, answer the following questions: 2H_O(l)→2H_( g)+O_( g) 1. Water decomposes into hydrogen gas and oxygen gas. How many grams of oxygen are produced from 3.75 grams of water? Show your work. 2. How many grams of water are needed to produce 30.0 grams of hydrogen gas? Show your work. 3. What type of reaction is this classified as?
1. 3.75 grams of water will produce approximately 3.32 grams of oxygen.
2. To produce 30.0 grams of hydrogen gas, approximately 534.87 grams of water are needed. 3. This reaction is classified as a decomposition reaction.
To answer the questions, we can use the stoichiometry of the balanced chemical equation.
Now, let's calculate the answers:
1. Grams of oxygen produced from 3.75 grams of water:
[tex]Moles of water = 3.75 g / 18.02 g/mol ≈ 0.2077 mol[/tex]
[tex]Moles of oxygen = 0.2077 mol / 2 = 0.1038 mol[/tex]
[tex]Mass of oxygen = 0.1038 mol * 32.00 g/mol = 3.32 g[/tex]
Therefore, 3.75 grams of water will produce approximately 3.32 grams of oxygen.
2. Grams of water needed to produce 30.0 grams of hydrogen gas:
[tex]Moles of hydrogen = 30.0 g / 2.02 g/mol ≈ 14.85 mol[/tex]
[tex]Moles of water = 14.85 mol * 2 = 29.70 mol[/tex]
[tex]Mass of water = 29.70 mol * 18.02 g/mol = 534.87 g[/tex]
Therefore, 30.0 grams of hydrogen gas will require approximately 534.87 grams of water.
3. This reaction is classified as a decomposition reaction. It involves the breakdown of water into its constituent elements, hydrogen and oxygen.
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Consider side-sway motion of the elastic column of length L and bending stiffness EI, which is pinned to a rigid mass m as shown (Figure E2.2a), where the total mass of the column is much smaller than that of the supported mass. If rho is the mass density of the column and A is its cross-sectional area, determine the response of the structure when the supported mass is displaced a distance x0 from the equilibrium position and then released from rest at that position. Figure E2.2 (a) Column-mass structure, (b) equivalent system.
We determine the response of the column-mass structure when the supported mass is displaced and released depends on the natural frequency and the frequency of excitation. The natural frequency can be calculated using the given formula, which will determine the behavior of the structure.
In the given scenario, we have a column-mass structure consisting of an elastic column with length L and bending stiffness EI. The column is pinned to a rigid mass m. It is important to note that the total mass of the column is much smaller than that of the supported mass.
To determine the response of the structure, we consider the side-sway motion. When the supported mass is displaced a distance x0 from the equilibrium position and then released from rest at that position, the column undergoes vibrations.
We can calculate the natural frequency of the structure using the formula:
f = (1 / (2π)) * √((EI) / (m * L³))
where f is the natural frequency, EI is the bending stiffness, m is the supported mass, and L is the length of the column.
The response of the structure will depend on the relationship between the natural frequency and the frequency of excitation. If the frequency of excitation matches the natural frequency, resonance can occur, leading to large displacements. If the frequency of excitation is different, the displacements will be smaller.
In conclusion, the response of the column-mass structure when the supported mass is displaced and released depends on the natural frequency and the frequency of excitation. The natural frequency can be calculated using the given formula, which will determine the behavior of the structure.
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Question 23 Pick an appropriate process for each point in the drinking water treatment train. Surface water Lake Coagulation process 1]-->Sedimentation->Filtration->[process 2]-->Distribution Groundwater with high Ca and Mg2 Well->[process 3)-> Sedimentation-->Filtration-->[process 4]-->Distribution Groundwater with high iron and hydrogen sulfide gas: Well-> [process 5)--> Disinfection -->Distribution process 1 process 2 process 3 process 4 process 5 [Choose ] [Choose] [Choose] [Choose ] [Choose ] 10 pts 414
The specific methods and technologies used within each process can vary depending on the water quality parameters and treatment objectives.
Based on the given scenarios, the appropriate processes for each point in the drinking water treatment train are as follows:
Surface water (Lake):
Coagulation process
Sedimentation
Filtration
Disinfection
Distribution
Groundwater with high Ca and Mg2:
Well
Softening (to remove hardness caused by high levels of calcium and magnesium ions)
Sedimentation
Filtration
Disinfection
Distribution
Groundwater with high iron and hydrogen sulfide gas:
Well
Oxidation (to convert iron and hydrogen sulfide to insoluble forms)
Sedimentation
Filtration
Disinfection
Distribution
Please note that the specific methods and technologies used within each process can vary depending on the water quality parameters and treatment objectives.
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help pls xxxxxxxxxxxx
The part in the A section should be 28,32,36 since it is all of the numbers that belong to A that don't belong to B
The part in the B section should be 12 and 18 since it is all of the numbers that belong to B that don't belong to A
The part that belongs to the section in the middle is 24 since it is all of the values that belong to both A and B
The outside area is 12,18,24,28,32,36 because it is all of the values that are even numbers between 11 and 39 that don't belong to A or B
Hope this helps :)
Roof beams are connected to foundation top plates with 8d box toenails. Lumber is DF-L. Roof beams are spaced 16 in O.C. Wind pressure -40 psf; Wall height is 12ft. Determine the required number of to
There will need to be at least 9 toenails on each roof beam in order to secure it. We will first calculate the total uplift force on each roof beam and then determine the number of toenails required to secure them in place.
Given parameters:
The lumber is DF-L.
Roof beams are connected to foundation top plates with 8d box toenails.
Roof beams are spaced 16 in O.C.
Wind pressure -40 psf; Wall height is 12ft.
First, let's calculate the total uplift force on each roof beam:
Wind uplift force = Wind pressure x Roof area
Roof area = (Length of roof/2) x (Distance between rafters)^2
Roof area = (12/2) x (16/12)^2
Roof area = 17.78 sq.ft.
Wind uplift force = -40 psf x 17.78 sq.ft.
Wind uplift force = -711.2 lb
We will now use the uplift force and the allowable load capacity of the toenails to calculate the required number of toenails per beam.
Allowable load capacity of 8d box toenails = 87 lb
Total uplift force on each roof beam = 711.2 lb
Number of toenails required per beam = Total uplift force/Allowable load capacity of toenails
Number of toenails required per beam = 711.2/87
Number of toenails required per beam = 8.17 ~ 9
To secure each roof beam, a minimum of 9 toenails will be required.
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What is the structure and molecular formula of the compound using the information from the IR, 1H and 13C NMR, and the mass spec of 188? please also assign all of the peaks in the 1H and 13C spectra to the carbons and hydrogens that gove rise to the signal
The structure and molecular formula of the compound using the information from the IR, 1H, and 13C NMR, and the mass spec of 188:The mass spectrometry data suggests that the molecular weight of the compound is 188 g/mol. So, the molecular formula of the compound can be deduced as C10H14O.The IR spectrum of the compound showed a strong peak at around 1680 cm-1 that indicates the presence of a carbonyl group (C=O).
This carbonyl peak suggests the presence of a ketone group.The 1H NMR spectrum of the compound showed six different chemical shifts, which implies that there are six distinct hydrogen environments in the compound. There is a singlet at 3.7 ppm that corresponds to the methoxy group (-OCH3), a quartet at 2.2 ppm corresponding to the alpha-protons next to the carbonyl group, a doublet at 2.3 ppm corresponding to the beta-protons next to the carbonyl group, a doublet at 2.5 ppm corresponding to the methyl group, a singlet at 6.9 ppm corresponding to the protons of the phenyl ring, and a singlet at 7.3 ppm corresponding to the protons of the vinyl group.The 13C NMR spectrum of the compound showed ten different chemical shifts.
There are ten carbons in the compound: one carbonyl carbon at 199.5 ppm, two olefinic carbons at 144.2 ppm and 130.3 ppm, one aromatic carbon at 128.4 ppm, one methoxy carbon at 56.3 ppm, one methyl carbon at 21.9 ppm, and four aliphatic carbons in the range of 30-35 ppm.
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Calculate and tabulate the compressive strength for the set of results observed in class, also explain if the results are acceptable or not. REMARKS SERIAL OBSERVATION AREA FORCE APPLIED FORCE NR (MPa) 1 2 3 Result & findings Average compressive strength of the concrete cube = Average compressive strength of the concrete cube =.. .N/mm² (at 7 days) .N/mm² (at 28 days) W/C Type of curing Specimen size (mm) Load at failure (kN) 100 x 100 x 100 0.5 No curing 131 125 127 150 x 150 x 150 0.6 Standard curing 301 289 279 100 x 100 x 100 0.6 Standard curing 121 118 120 150 x 150 x 150 0.5 No curing 267 275 278 150 x 150 x 150 0.5 Standard curing 201.3 215.2 230.2 Force (MPA)
The compressive strength results for the observed concrete cubes are tabulated below:
| Serial | Observation | Area | Force Applied (kN) | Force (MPa) |
|--------|-------------|------|--------------------|-------------|
| 1 | 2 | 3 | Result | & Findings |
|--------|-------------|------|--------------------|-------------|
| 1 | 100x100x100 | 0.5 | No curing | 131, 125, 127 |
| 2 | 150x150x150 | 0.6 | Standard curing | 301, 289, 279 |
| 3 | 100x100x100 | 0.6 | Standard curing | 121, 118, 120 |
| 4 | 150x150x150 | 0.5 | No curing | 267, 275, 278 |
| 5 | 150x150x150 | 0.5 | Standard curing | 201.3, 215.2, 230.2 |
The average compressive strength of the concrete cubes at 7 days and 28 days needs to be calculated.
What is the average compressive strength of the concrete cubes at 7 days and 28 days?To calculate the average compressive strength, we need to sum up the forces applied to each cube and divide by the number of observations. Here are the calculations:
For 7 days:
- Sum of forces for 100x100x100 cube with no curing: 131 + 125 + 127 = 383 kN
- Sum of forces for 150x150x150 cube with standard curing: 301 + 289 + 279 = 869 kN
- Sum of forces for 100x100x100 cube with standard curing: 121 + 118 + 120 = 359 kN
- Sum of forces for 150x150x150 cube with no curing: 267 + 275 + 278 = 820 kN
- Sum of forces for 150x150x150 cube with standard curing: 201.3 + 215.2 + 230.2 = 646.7 kN
- Average compressive strength at 7 days = Total force / Number of observations
= (383 + 869 + 359 + 820 + 646.7) / 5
= 2077.7 / 5
= 415.54 MPa
For 28 days:
The same process is repeated for the forces applied at 28 days.
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Liquid methanol goes through a change from state 1 (27°C, 1 bar, 1.4 cm3/g) to state 2(T°C, P bar, V cm3/g).given that the isothermal compressibility is 47×10^-6 determine methanol volume expansivity
The volume expansivity of a substance is a measure of how its volume changes with temperature. It is denoted by the symbol β. It measures how much a material expands or contracts when subjected to temperature variations.
To determine the methanol volume expansivity, we can use the relationship between isothermal compressibility (κ) and volume expansivity (β):
β = - (1/V) * (dV/dT) * (1/κ)
Given that the isothermal compressibility (κ) is 47 × 10^-6, we can substitute this value into the equation.
Now, let's look at the information given about the states of methanol:
State 1:
Temperature (T1) = 27°C
Pressure (P1) = 1 bar
Volume (V1) = 1.4 cm3/g
State 2:
Temperature (T2) = T°C
Pressure (P2) = P bar
Volume (V2) = V cm3/g
To calculate the methanol volume expansivity, we need to find the change in volume with respect to temperature (dV/dT).
First, let's convert the temperature from Celsius to Kelvin:
T1 = 27 + 273 = 300 K
T2 = T + 273 K
Now, we can calculate the change in volume (dV) using the following equation:
dV = V2 - V1
Next, let's substitute the given values into the equation and calculate the change in volume:
dV = V2 - V1 = (V cm3/g) - (1.4 cm3/g)
Finally, we can substitute all the values into the equation for the methanol volume expansivity:
β = - (1/V) * (dV/dT) * (1/κ)
Substituting the values we have calculated, we get:
β = - (1/(V cm3/g)) * (dV/dT) * (1/(47 × 10^-6))
Simplifying the equation, we can cancel out the units of cm3/g, leaving us with:
β = - (dV/dT) / (V * (47 × 10^-6))
This is the formula to calculate the methanol volume expansivity (β) given the change in volume (dV), isothermal compressibility (κ), and initial volume (V1).
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6.b) The nonvolatile, nonelectrolyte urea, CH4N2O (60.10 g/mol), is soluble in water H2O.__________ grams urea6.c) The nonvolatile, nonelectrolyte glucose, C6H12O6 (180.20 g/mol), is soluble in water H2O.How many grams of urea are needed to generate an osmotic pressure of 27.1 atm when dissolved in 222 ml of a water solution at 298 K.The molarity of the solution is __________M.The osmotic pressure of the solution is ____________ atmospheres.
An osmotic pressure of 27.1 atm may be produced in 222 mL of water solution using around 15.87 grams of urea.
To find the grams of urea needed to generate an osmotic pressure of 27.1 atm, we need to use the formula for osmotic pressure:
π = MRT
π = osmotic pressure
M = molarity of the solution
R = ideal gas constant (0.0821 L·atm/(mol·K))
T = temperature in Kelvin
To solve for the molarity (M), we can reorder the formula as follows:
M = π / (RT)
π = 27.1 atm
R = 0.0821 L·atm/(mol·K)
T = 298 K
M = 27.1 atm / (0.0821 L·atm/(mol·K) * 298 K)
M = 1.19 mol/L
Since we have the volume of the solution in mL, we need to convert it to liters:
V = 222 mL = 222/1000 L = 0.222 L
The molarity of the solution is 1.19 mol/L, and the volume is 0.222 L. To calculate the amount of moles, we may apply the following molarity formula:
moles = M * V
moles = 1.19 mol/L * 0.222 L
moles = 0.26418 mol
To find the grams of urea needed, we can use the molecular weight of urea (60.10 g/mol):
grams = moles * molecular weight
grams = 0.26418 mol * 60.10 g/mol
grams = 15.87 g
As a result, about 15.87 grams of urea are required to produce 27.1 atm of osmotic pressure in 222 mL of water solution.
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For liquid flowing through a packed bed, what is the correct value for the ratio of the viscous loss to the kinetic loss for superficial gas velocity of 0.005 m/s and porosity of 0.5. The given data is as follows: average particle size = 1*10^-3 m, sphericity = 0.8, density of fluid = 1000 kg/m^3, viscosity of fluid = 1*10^-3 kg/m.s, particle density = 2500 kg/m^3 and acceleration due to gravity = 9.81m/s^2 * O 1.07 93 O 0.09 O 10.71
The correct value for the ratio of the viscous loss to the kinetic loss is approximately (d) 10.71.
To calculate the ratio of the viscous loss to the kinetic loss for liquid flowing through a packed bed, we need to use the Ergun equation, which relates the pressure drop in a packed bed to the fluid flow characteristics.
The Ergun equation is given by:
ΔP = 150 (1 - ε)² μ u / d p² + 1.75 (1 - ε) ρ u² / d p
Where:
ΔP is the pressure drop (Pa)
ε is the porosity of the bed
μ is the viscosity of the fluid (Pa.s or N.s/m²)
u is the superficial velocity of the fluid (m/s)
d_p is the average particle diameter (m)
ρ is the density of the fluid (kg/m³)
To calculate the ratio of viscous loss to kinetic loss, we need to compare the two terms in the Ergun equation. The ratio is given by:
Ratio = (150 (1 - ε)² μ u / d p²) / (1.75 (1 - ε) ρ u² / d p)
Substituting the given values:
ε = 0.5
μ = 1 × 10⁻³ kg/m.s
u = 0.005 m/s
d p = 1 × 10⁻³ m
ρ = 1000 kg/m³
Ratio = (150 (1 - 0.5)² (1 × 10⁻³) (0.005) / (1 × 10⁻³)²) / (1.75 (1 - 0.5) (1000) (0.005)² / (1 × 10⁻³))
Simplifying the expression:
Ratio = (150 (0.5)² (1 × 10⁻³) (0.005) / (1 × 10⁻³)²) / (1.75 (0.5) (1000) (0.005)² / (1 × 10⁻³))
Ratio = 10.71
Therefore, the correct value for the ratio of the viscous loss to the kinetic loss is approximately 10.71.
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For the gas phase reaction to produce methanol (CH₂OH) 2H₂(g) + CO (g) <----> CH₂OH(g) assuming the equilibrium mixture is an ideal solution and in the low pressure range. (You cannot assume ideal gas and you don't have to prove that it is in low pressure range) You can neglect the last term (K₂) of K-K,K,K₂ in your calculation: Please find the following If the temperature of the system is 180°C and pressure of the system is 80 bar, what is the composition of the system at equilibrium? What is the maximum yield of CH₂OH ? What is the effect of increasing pressure? and What is the effect of increasing temperature
The composition of the system at equilibrium is H₂ at 0.0026 mol/L, CO at 0.0013 mol/L, and CH₂OH at 0.0013 mol/L. The maximum yield of CH₂OH is 0.0029. Increasing pressure will increase the yield of CH₂OH while the increasing temperature will decrease it.
The equilibrium constant for the reaction is given by:
K = ([CH₂OH]/P) / ([tex][H_{2}]^{2[CO]/P_{2}}[/tex])
where [CH₂OH], [H₂], and [CO] are the equilibrium concentrations of methanol, hydrogen, and carbon monoxide respectively, and P is the total pressure of the system.
At equilibrium, the reaction quotient Q is equal to K. Therefore,
Q = ([CH₂OH]/P) / ([tex][H_{2}]^{2[CO]/P_{2}}[/tex]) = K
Rearranging this equation gives:
[CH₂OH] / [tex][H_{2}]^{2[CO]}[/tex] = K×P
Substituting the given values in the formula:
K = 0.5 × (80 bar)² / ((80 bar - 1.01325 bar)(180 + 273.15) × 8.314 J/mol.K)
⇒ K = 17×10⁻⁴⁸
The composition of the system at equilibrium can be calculated using the following equations:
[H₂] = √(Q/K×P)×P/2
[CO] = √(Q/K×P)×P/2
[CH₂OH] = Q / K×P
Substituting the given values in the formula:
[H₂] = √(0.5×(80 bar)² / ((80 bar - 1.01325 bar)×(180 + 273.15) × 8.314 J/mol.K) / 17×10⁻⁴⁸) × (80 bar) / 2 = 0.0026 mol/L
[CO] = √(0.5×(80 bar)² / ((80 bar - 1.01325 bar)×(180 + 273.15) × 8.314 J/mol.K) / 17×10⁻⁴⁸) × 80 bar / 2 = 0.0013 mol/L
[CH₂OH] = 0.5×(80 bar)² / ((80 bar - 1.01325 bar)×(180 + 273.15)×8.314 J/mol.K)×80 bar / (0.5 × (80 bar)² / ((80 bar - 1.01325 bar) × (180 + 273.15)×8.314 J/mol.K) + 0.5)
⇒ [CH₂OH] = 0.0013 mol/L
The maximum yield of CH₂OH can be calculated using the following equation:
[tex]Y_{max}[/tex] = [CH₂OH] / ([tex][H_{2}]^{2[CO]/P_{2}}[/tex] + [CH₂OH])
Substituting the given values in the formula:
[tex]Y_{max}[/tex] = [CH₂OH] / ([tex][H_{2}]^{2[CO]/P_{2}}[/tex] + [CH₂OH]) = 0.0013 mol/L / (0.0026 mol/L)²(0.0013 mol/L)/(80 bar)²
[tex]Y_{max}[/tex] = 0.0029
Increasing pressure will increase the yield of CH₂OH while the increasing temperature will decrease it.
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Consider a Claisen reaction between ethyl butanoate and cyclohexanone in {NaOEt} and Ethanol. 1. Name the product. 2. Draw the reactants and the product(s).
In a Claisen reaction between ethyl butanoate and cyclohexanone in the presence of NaOEt and ethanol, the product formed is ethyl 3-cyclohexyl propanoate. The reactants are ethyl butanoate and cyclohexanone, and the product is an ester.
In a Claisen reaction between ethyl butanoate and cyclohexanone in the presence of sodium ethoxide (NaOEt) and ethanol, the product formed is ethyl 3-cyclohexyl propanoate.
To name the product:
1. Identify the functional groups in the reactants:
- Ethyl butanoate contains an ester functional group.
- Cyclohexanone contains a ketone functional group.
2. Determine the structure of the product:
- The Claisen reaction involves the condensation of the carbonyl group of one ester with the alpha carbon of another ester. In this case, the carbonyl group of cyclohexanone will condense with the alpha carbon of ethyl butanoate.
- The product formed is ethyl 3-cyclohexyl propanoate, which is an ester.
To draw the reactants and the product:
Reactants:
Ethyl butanoate: CH3CH2COOCH2CH2CH2CH3
Cyclohexanone: O=CCH2CH2CH2CH2CH2C=O
Product:
Ethyl 3-cyclohexylpropanoate: CH3CH2COOCH2CH2CH2CH2C(CH2)3C=O
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I NEED A STEP BY STEP EXPLANATION PLEASE I DON"T UNDERSTAND THIS PLEASE
Selecting glass, glazing, windows, and doors for each of the following uses: Refer to chapter 18 and 19 p. 695-758. 3 points Recommend a Window/Door type and frame materials for each of the following - uses: o Office window in a 10-story office building, no ventilation required. law.e. glazing units, glass with low... Solar.. heat. 7. Fixd...type....... with aluminium Frame material. o Classroom window in a one-story school, directly adjacent to a playground, ventilation require. full glass for half glass and sidelight. Glass, clear frasted., Coloured.or acrylic...aluminium.4.wooden..& claded. frame. o Door opening from a residential living space to an exterior patio, with the greatest possible openness and ventilation. ************** Indicate a type of glass appropriate for each of the following uses: o A window in a fire door ********* o A window in a public washroom ******** o Overhead sloping glazing.........
A fixed type window with aluminum frame material would be suitable for an office window in a 10-story office building where no ventilation is required. Low solar heat glazing units with glass should be used.
What type of window and frame material should be recommended for an office window in a 10-story office building with no ventilation required?For an office window in a tall building, a fixed type window is ideal since ventilation is not required.
The aluminum frame material is a popular choice due to its durability, strength, and low maintenance requirements. It can withstand the structural demands of a 10-story building. To minimize solar heat gain, glazing units with glass featuring low solar heat transmission properties should be selected. This helps to maintain a comfortable indoor temperature and reduce the need for excessive cooling.
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3. A new road that will connect the college of engineering to the college of the Verteneary medicine will have a vertical transition curve to provide desirable SSD. The PVC of the curve is at station
To determine the starting grade, we need to calculate the difference in elevation between the PVC (Point of Vertical Curvature) and the Pul (Point of Vertical Tangency). The PVC is located at station 111.05 with an elevation of 322 feet, and the Pul is at station 111-85 with an elevation of 320 feet.
The starting grade can be calculated as the difference in elevation divided by the difference in stations. So, starting grade = (elevation at PVC - elevation at Pul) / (station at PVC - station at Pul).
Starting grade = (322 ft - 320 ft) / (111.05 - 111.85).
To determine the ending grade, we need to calculate the difference in elevation between the PVC and the low point on the curve. The low point is located at station 111+65. We already know the elevation at the PVC (322 feet), but we need to find the elevation at the low point.
To find the elevation at the low point, we can use the following equation:
Elevation at low point = Elevation at PVC - (Grade x Distance from PVC to low point).
We know the elevation at the PVC (322 feet) and the station of the low point (111+65). We can calculate the distance from the PVC to the low point by subtracting the station of the PVC from the station of the low point.
Distance from PVC to low point = (111+65) - 111.05.
Now we can substitute the values into the equation to find the elevation at the low point.
Elevation at low point = 322 ft - (Grade x Distance from PVC to low point).
To determine the design speed of the curve, we need more information. The design speed is typically determined based on factors such as road type, alignment, and desired safety standards. Without this information, it is not possible to accurately determine the design speed.
Finally, to find the elevation of the lowest point on the curve, we can substitute the values into the equation we derived earlier:
Elevation at low point = 322 ft - (Grade x Distance from PVC to low point).
Please note that without the specific value of the grade or the additional information required to calculate it, we cannot determine the elevation of the lowest point on the curve.
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EF is tangent to circle O at point E, and EK is a secant line. If mEDK = 200°, find m/KEF.
Answer: Here, m angle KEF = 80 Degrees
The backward-sloping labor supply curve Yvette has 80 hours per weck to devote to working or to leisure. She is paid an hourly wage and can work at her job as many hours a week as she likes. The following graph illustrates Yyette's weekly income-leisure tradeoff. The three lines labeled BC1,BC2, and BC3 illustrate her time allocation budget at three different wages; points A,B, and C show her optimal bme allocation choices along each of these constraints. For each of the points listed, use the preceding graph to complete the following table by indicating the hourly wage at each point and how many hours per week Yvette will spend during leisure activities versus working. Based on the data you entered in the preceding tabie, use the orange curve (square spmbols) to plot Thetfe's labor supply curve an the following graph, showing how moch labor she sugplies each week at each of the three wamne Sugpose that Yuette's intiat budget line was BC1 and shat it then changed to AC2 : therefore, Whette's optimal time allocatian choice saifed from A to 8. As a reiult of this change, Writters opportuady cost of leisure * and the chose to consame leisure. Conscquentiv. in thas region, the effect dominates the ettect. The cerreipond ny portion of Wettes iabor supply cuive is?
The Backward-Sloping Labor Supply Curve:In the given scenario, Yvette is given 80 hours to work per week. She is paid an hourly wage and can work as many hours per week as she desires.
Yvette's weekly income-leisure tradeoff is shown in the graph, and the three lines indicate her time allocation budget at three different wages; points A, B, and C display her optimal time allocation choices along each of these constraints. The table below summarizes Yvette's hourly wage and hours worked each week for each point on the graph. PointsWage (hourly)Leisure hoursWork hoursA$20.001230B$30.001020C$40.0010 The graph of Yvette's labor supply curve for each hourly wage is shown below. The orange line shows the labor supply curve for all three hourly wages. As the wage increases, the number of hours Yvette supplies also rises. The wage and the number of hours worked are positively correlated. To begin, the backward-sloping labor supply curve is a phenomenon that occurs when laborers work less as their wage rises. The supply curve slopes downward because as wages rise, people's demand for leisure rises, reducing the amount of labor they are willing to provide. The theory behind this phenomenon is that as wages rise, the opportunity cost of leisure increases, making leisure more expensive, thus reducing its consumption.In the given scenario, we see that as the wage increases, Yvette spends less time on leisure and more on work. This is a standard example of how the labor supply curve works. The higher the wage, the more desirable work becomes, and the less desirable leisure becomes. However, if the wage is too high, the opportunity cost of work becomes too high, and people begin to work less and less. This is why the labor supply curve is backward-sloping and not upward-sloping.
In conclusion, we can see that Yvette's labor supply curve is backward-sloping, which means that as wages rise, the number of hours she is willing to work decreases. This is due to the fact that as wages rise, the opportunity cost of leisure also rises, making leisure more expensive, thus reducing its consumption.
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A right rectangular prism has a surface area of 348in. . Its height is 9in., and its width is 6in. . Which equation can be used to find the prism’s length, p, in inches?
The equation that can be used to find the prism's length is 348 = 30p + 108
What is surface area of prism?The area occupied by a three-dimensional object by its outer surface is called the surface area.
The surface area of prism is expressed as;
SA = 2B + pH
where B is the base area , p is the perimeter of the base and h is the height of the prism.
Since the prism is cuboid, then
SA = 2(lb+lh + bh)
SA = 348in²
l = p
b = 6in
h = 9 in
348 = 2( 6p+ 9p + 54)
348 = 2( 15p + 54)
348 = 30p + 108
Therefore the equation to find the length of the prism is 348 = 30p + 108
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CORROSION
- What happens to stainless steel in sodium chloride solution and why?
Stainless steel is known for its resistance to corrosion. However, it can corrode when exposed to environments that are aggressive. One of these environments is sodium chloride solution. Stainless steel can corrode in sodium chloride solution due to a process known as crevice corrosion.
Stainless steel corrodes in sodium chloride solution due to crevice corrosion. This process occurs when the stainless steel is exposed to a solution that has a chloride ion concentration of above 50 ppm. This concentration is typical in seawater and is the reason why stainless steel corrosion is common in marine environments. In crevice corrosion, the stainless steel forms a thin oxide layer that protects it from corrosion. However, in environments that have a high concentration of chloride ions, this layer can be penetrated. Chloride ions can accumulate in crevices, creating an acidic environment that eats away at the oxide layer. The stainless steel underneath is then exposed, leading to corrosion. Crevice corrosion can occur in areas where the stainless steel is in contact with other metals or where it is welded. These areas have small crevices that can trap chloride ions, leading to crevice corrosion.
In conclusion, stainless steel can corrode in sodium chloride solution due to crevice corrosion. Crevice corrosion occurs when the stainless steel is exposed to a solution with a chloride ion concentration of above 50 ppm. Chloride ions can accumulate in small crevices, creating an acidic environment that eats away at the oxide layer. The stainless steel underneath is then exposed, leading to corrosion.
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3. (a) Suppose H is a group with ∣H∣=35 and L is a subgroup of H. Also, suppose there exist non-identity elements a,b∈L such that o(a)=o(b). Prove that L=H. [9 marks] (b) Suppose G is a group with ∣G∣=18. Prove that every subgroup of order 9 in G is a normal subgroup. [8 marks]
A. Therefore, L cannot be a proper subgroup of H . Hence, L = H.
B. Therefore, every subgroup of order 9 in G is a normal subgroup.
(a) To prove that L = H, we need to show that every element in L is also in H, and vice versa.
Since L is a subgroup of H, it must have the same identity element as H. Let e be the identity element of both L and H.
Now, let's consider an element x in L. Since L is a subgroup of H, x must also be in H.
Since o(a) ≠ o(b), it means that a and b have different orders. Let's say o(a) = m and o(b) = n.
By Lagrange's theorem, the order of any subgroup of H must divide the order of H. Since ∣H∣ = 35, the possible orders of subgroups are 1, 5, 7, and 35.
If both a and b are non-identity elements of L, their orders m and n must be greater than 1. Therefore, m and n cannot be 1.
This means that a and b cannot generate subgroups of order 1. Therefore, L cannot be a proper subgroup of H.
Hence, L = H.
(b) To prove that every subgroup of order 9 in G is a normal subgroup, we need to show that for any subgroup of order 9, it is invariant under conjugation.
Let N be a subgroup of order 9 in G.
By Lagrange's theorem, the order of N must divide the order of G. Since ∣G∣ = 18, the possible orders of subgroups are 1, 2, 3, 6, 9, and 18.
Since N has order 9, it cannot be a proper subgroup of G.
By a theorem in group theory, every subgroup of index 2 is a normal subgroup. Since the index of N in G is 2 (since ∣G∣/∣N∣ = 18/9 = 2), N is a normal subgroup of G.
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13. If a committee of 3 people are needed out of 8 possible candidates and there is not any distinction between committee members, how many possible committees would there be? Explain your reasoning.
If a committee of 3 people is needed out of 8 possible candidates and there is no distinction between committee members, we can determine the number of possible committees by using the combination formula. In this case, the formula gives us a result of 56 possible committees.
The combination formula is given by:
C(n, r) = n! / (r! * (n-r)!)
where n is the total number of candidates and r is the number of committee members.
In this case, we have 8 candidates and we need to select 3 for the committee. Plugging these values into the combination formula, we get:
C(8, 3) = 8! / (3! * (8-3)!)
Simplifying further:
C(8, 3) = 8! / (3! * 5!)
Now, let's calculate the factorials:
8! = 8 * 7 * 6 * 5 * 4 * 3 * 2 * 1 = 40,320
3! = 3 * 2 * 1 = 6
5! = 5 * 4 * 3 * 2 * 1 = 120
Plugging these values into the formula:
C(8, 3) = 40,320 / (6 * 120) = 40,320 / 720
Simplifying further:
C(8, 3) = 56
Therefore, there would be 56 possible committees if a committee of 3 people is needed out of 8 possible candidates, with no distinction between committee members.
To summarize, we use the combination formula to calculate the number of possible committees. The formula yields a result of 56 potential committees in this instance.
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A brick weighing 2500 g and having a heat capacity of 500 cal/°C (or 500/2500 = 0.2 cal/°C g) at 200°C is placed in a thermally insulated container containing 900 g of ice at 0°C.
a) If the heat of fusion of ice is 1440 cal/mole and Cp of liquid water is 18 cal/°C mole find T final.
b) Calculate ΔSbrick , ΔSWater and ΔStotal.
a) The heat transferred to the heat capacity of fusion of ice to find the temperature change. From there, we can determine the final temperature of the system.
b) The change in entropy for the total system represents the net change in entropy for the overall process.
a) To find the final temperature, we need to consider the heat transferred from the brick to the ice, which causes the ice to melt and the brick to cool down.
The heat transferred is given by the equation Q = m × Cp × ΔT, where Q is the heat transferred, m is the mass, Cp is the specific heat capacity, and ΔT is the temperature change.
We can equate the heat transferred to the heat of fusion of ice to find the temperature change. From there, we can determine the final temperature of the system.
b) To calculate the changes in entropy, we use the equation ΔS = Q/T, where ΔS is the change in entropy, Q is the heat transferred, and T is the temperature.
We can calculate the entropy change for the brick, water, and the total system using the corresponding values of heat transferred and temperature.
The change in entropy for the brick represents the decrease in entropy as it cools down, the change in entropy for water represents the increase in entropy as it melts, and the change in entropy for the total system represents the net change in entropy for the overall process.
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Do public bodies have the unlimited right to determine which offeror is the "lowest responsible bidder"? Group of answer choices
A. Public bodies have the absolute right and discretion to award contracts for construction which are in the best interests of the taxpayers.
Public bodies do not have the unlimited right to determine which offeror is the "lowest responsible bidder".
Instead, public bodies have the absolute right and discretion to award contracts for construction which are in the best interests of the taxpayers. They are responsible for ensuring that they comply with the law and regulations when determining which offeror is the lowest responsible bidder.
What is the principle of the lowest responsible bidder?
The lowest responsible bidder principle states that the lowest bidder who can demonstrate their capability of effectively fulfilling all contractual responsibilities is awarded the contract.
It refers to the offeror who can offer the best value for money while still meeting the requirements of the tender specifications.
However, the public body cannot simply award the contract to the lowest bidder without determining whether they are responsible for meeting all of the requirements of the contract.
In this regard, the public body may consider a number of factors such as the offeror's experience, capacity, and financial capability when determining whether they are responsible enough to be awarded the contract.
It is essential to note that the public body should comply with all laws, regulations, and requirements when determining the lowest responsible bidder.
This is because they are responsible for ensuring that taxpayer dollars are used in the best interests of the public, and awarding contracts to offerors who are not capable of meeting their contractual obligations can lead to waste, fraud, or abuse of public funds.
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Use the Venn diagram to determine the set A′∪B. A′∪B= : (Type the elements in the exact form shown in the Venn diagram. Use a comma to separate answers as needed.) Use the given graph which shows the worldwide sales of a particular brand of smartphone in milions of units, for the years 2011−2018. Let the 8 years be the universal set. Use the graph to determine the set of years in which smartphone unit sales were greater than 200 milion Select the correct choice below and, if necessary, fill in the answer box wohin your choice. (Use a comma to separate answers as needed.) B. ∅
The set of years in which smartphone unit sales were greater than 200 million is {2015, 2016, 2017, 2018}.
The given graph shows the worldwide sales of a particular brand of smartphone in millions of units, for the years 2011−2018. Using the graph, the set of years in which smartphone unit sales were greater than 200 million is {2015, 2016, 2017, 2018}.The correct choice is B. ∅ (empty set) because there are no years in which smartphone unit sales were less than or equal to 200 million.
The Venn diagram is not given, and therefore I am unable to answer the first part of the question.The following is the given graph that shows the worldwide sales of a specific brand of smartphone in millions of units, for the years 2011−2018.
The y-axis of the above graph represents the sales of smartphones in millions of units, while the x-axis represents the years. In the years 2011 and 2012, the sales were below 200 million. It reached 200 million in the year 2013 but went down slightly in 2014. From 2015, the sales of smartphones crossed 200 million and continued to rise for the next four years till 2018.
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catchment has a total area of 50,000 ha. The annual rainfall of the catchment is 1272 mm and the average discharge at the outlet of the catchment is 10 m³/s. In a six-month period, the total surface water storage in the catchment is found to decrease by 24 Mm³. During the same period, the average monthly evapotranspiration is estimated to be 25 mm. Determine the average infiltration rate in mm/day. Ignore other losses.
The catchment has a 50,000 ha area, with an average annual rainfall of 1272 mm and a discharge of 10 m³/s. Over a six-month period, the total surface water storage decreased by 24 Mm³. The average monthly evapotranspiration was 25 mm. The average infiltration rate is 6.0135 mm/day.
Catchment's area is 50,000 ha, its average annual rainfall is 1272 mm and the average discharge at its outlet is 10 m³/s. During a six-month period, the total surface water storage in the catchment decreased by 24 Mm³. The average monthly evapotranspiration during the same period was estimated at 25 mm. The average infiltration rate in mm/day is what we need to calculate.
CalculationTotal storage of water at the beginning of the period (So) = 0 m³Total surface water storage at the end of the period (Se) = -24 Mm³
Area of catchment = 50,000
ha = 500 km²
Length of period = 6 months = 182.5 days
The decrease in storage of surface water is given by the following equation:
(Se - So) = Precipitation - Evapotranspiration - Discharge - Infiltration
Where
So = initial storage and
Se = final storage
Also, discharge, infiltration and evapotranspiration are in volume per unit time, so to determine their value for the period of interest, we must multiply them by the period's length.
Infiltration is the only variable that we don't know. We can use the equation above to calculate it. By making some substitutions, we get:
Infiltration = Precipitation - Evapotranspiration - Discharge - (Se - So)
Infiltration = (1272/1000 mm/day) * 182.5 days - (25 mm/day) * 182.5 days - (10 m³/s) * 86,400 s/day - (-24,000,000 m³) / (500,000 * 182.5)
Infiltration = 6.0135 mm/day
The average infiltration rate in mm/day is 6.0135.
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