Answer:
∠
O
−
C
−
C
l
≅
120
∘
The central carbon is
s
p
2
−
hybridized........
Explanation:
And thus
∠
C
l
−
C
−
C
l
and
∠
O
−
C
−
C
l
≅
are
120
∘
to a first approximation.
Why this value? We look to
VSEPR theory
. There are 3 regions of electron density around the central carbon, and the most stable geometry is a trigonal plane. While there is a
carbonyl
group, i.e. a
C
=
O
bond, the
π
bond is conceived to lie above and below this trigonal plane.
The
carbonyl oxygen
is likewise conceived to be
s
p
2
-hybridized
, however, here, there are 2 lone pairs on the oxygen centre.
The approximate chlorine-carbon-chlorine bond angle in C2Cl4 is 120°.
The bond angle is defined as the angle between ant two bonds emanating from a common atom.
The compound C2Cl4 is tetrachloroethene. The carbon atoms are sp2 hybridized in this molecule.
Recall that the bond angle of an sp2 hybridized carbon atom is 120°. Therefore the chlorine-carbon-chlorine bond angle in C2Cl4 is 120°.
From the perspective of the VSEPR theory, the geometry of each carbon atom in C2Cl4 is trigonal planar which implies a bond angle of 120°.
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Calculate the pH of a solution containing a caffeine concentration of 455 mg/L . Express your answer to one decimal place.
Answer:
Explanation:
Caffeine is a weak base with pKb = 10.4
Kb = 10⁻¹⁰°⁴ = 3.98 x 10⁻¹¹
molecular weight of caffeine = 194.2
455 x 10⁻³ g / L = 455 x 10⁻³ / 194.2 moles / L
concentration of given solution a = 2.343 x 10⁻³ M
Let the caffeine be represented by B .
B + H₂O = BH + OH⁻
a - x x x
x² / ( a - x ) = Kb
x² / ( a - x ) = 3.98 x 10⁻¹¹
x is far less than a so a -x is almost equal to a
x² = 3.98 x 10⁻¹¹ x 2.343 x 10⁻³ = 9.32 x 10⁻¹⁴
x = 3.05 x 10⁻⁷
[ OH⁻ ] = 3.05 x 10⁻⁷
pOH = - log ( 3.05 x 10⁻⁷ )
= 7 - log 3.05
= 7 - 0.484 = 6.5
pH = 14 - 6.5 = 7.5
The pH of 455 mg/L of caffeine is 7.5
Using the formula;
Mass concentration = molar concentration × molar mass
Molar mass of caffeine = 194 g/mol
Mass concentration of caffeine = 455 mg/L
Molar concentration = Mass concentration/molar mass
Molar concentration = 455 × 10^-3g/L/194 g/mol
= 0.00235 M
Let Caffeine by depicted by the general formula BH
We can now set up the ICE table as follows;
:B + H2O ⇄ BH + OH^-
I 0.00235 0 0
C - x +x +x
E 0.00235 - x x x
Note that water is present in large excess
Again; pKb of caffeine =10.4
Kb = Antilog[-pKb]
Kb = Antilog [-10.4]
Kb = 3.98 × 10^-11
Kb = [BH] [OH^-]/[:B]
3.98 × 10^-11 = [x] [x]/[ 0.00235 - x ]
3.98 × 10^-11 [ 0.00235 - x ] = [x] [x]
9.4 × 10^-14 - 3.98 × 10^-11x = x^2
x^2 + 3.98 × 10^-11x - 9.4 × 10^-14 = 0
x = 3.1 × 10^-7 M
Recall [BH] = [OH^-] = 3.1 × 10^-7 M
Now;
pOH = - log [OH^-]
pOH = log [3.1 × 10^-7 M]
pOH = 6.5
But;
pH + pOH = 14
pH = 14 - pOH
pH = 14 - 6.5
pH = 7.5
The pH of 455 mg/L of caffeine is 7.5
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Missing parts
Caffeine (C8H10N4O2) is a weak base with a pKb of 10.4. Calculate the pH of a solution containing a caffeine concentration of 455 mg/L.
The amount of force that is exerted on a balloon by the gas inside the balloon is.
O A) temperature
OB) prlessure
O C) volume
O D) heat
Answer:
pressure
Explanation:
pressure is the amount of force exerted on an area. when you blow up the balloon you're filling it with gas particles. the gas particles move freely within the balloon and may collide with one another exerting pressure on the inside of the balloon.
The pressure of the gas is the amount of force that is exerted on a balloon by the gas inside the balloon. Therefore, option B is correct.
What is pressure?Pressure can be described as the force applied perpendicular to the surface of a body per unit area. Pressure can be defined as a standard mechanical quantity and is derived from a unit of force divided by a unit of area.
The SI unit of measurement of pressure, the pascal (Pa) or Newton per square meter (N/m²). Pressure can be defined as the amount of force exerted perpendicular to the surface per unit area.
Mathematically, the pressure exerted by force can be calculated as:
[tex]{\displaystyle p={\frac {F}{A}}}[/tex]
where, p is the pressure, F is the magnitude of the normal force, and A is the area of the surface.
Therefore, the amount of force that is exerted on the balloon by the gas inside the balloon is equal to pressure.
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What is the density of a block of gold that occupies 1000 ml and has a mass of 3.5 kg? Show your work
Answer:
We are given:
mass of the block = 3500 grams
volume of the block = 1000 mL
Finding the density:
Density = mass of the object (in grams) / volume of the object (in mL)
Density = 3500 / 1000
Density = 3.5 g / mL
What was the atomic theory about?
A. The properties of the nucleus
B. The existence of isotopes
C. The structure of the atom
D. The existence of electrons
Answer:
The structure of the atom
convert 575.1 mmHg to atm
Answer:
= .7567105263
Explanation:
1 atm = 760 mmHg
575.1 mmHg (1 atm/760mmHg) = .7567105263 atm
How many moles are in 141.16 grams of F?
Use two digits past the decimal for all values
Answer: 2681.81
Explanation:
HELPP
describe what potassium would do to be more stable
Answer:
Explanation:
Its a elemental potassium is soft ,white in colour and has one more electron than argon,an element that we know is extremely stable ... Potassium extra electron is easily lost to form the much more stable cation, K+
Solid calcium chlorate decomposes to form solid calcium chloride and oxygen gas.
Write the balanced chemical equation for the reaction described. Phases are optional.
equation:
Answer:
Ca(ClO₃)₂(s) → CaCl₂(s) + 3O₂(g)
Explanation:
Chemical equation:
Ca(ClO₃)₂(s) → CaCl₂(s) + O₂(g)
Balance chemical equation:
Ca(ClO₃)₂(s) → CaCl₂(s) + 3O₂(g)
Step 1:
Ca(ClO₃)₂(s) → CaCl₂(s) + O₂(g)
Left hand side Right hand side
Ca = 1 Ca = 1
Cl = 2 Cl = 2
O = 6 O = 2
Step 2:
Ca(ClO₃)₂(s) → CaCl₂(s) + 3O₂(g)
Left hand side Right hand side
Ca = 1 Ca = 1
Cl = 2 Cl = 2
O = 6 O = 6
Please help!!
This is a big part of my grade -----
Will make you brainliest******
Explanation:
U need to draw the graph first and make a line at 17 pennies, where the line of 17 pennies and your graph meet is the mass of it(at y axis)
Determine the value of the equilibrium constant (report your answer to three significant figures) for the following reaction if an equilibrium mixture contains 0.010 mol of solid PbBr2, and is 0.0100 M in Pb2+ ions and 0.0250 M in Br1- ions. Use the notation 4.31e-5 to indicate a number such as 4.31 x 10-5.
Answer:
6.25e-6 is the value of the equilibrium constant
Explanation:
we have this equation
[tex]PbBr(s) ----- Pb^{2+}(aq) + 2Br(aq)[/tex]
When at a state of equilibrium,
we have the concentration of Pb^2+ to be 0.01
we have the concentration of Br^- to be 0.025
the equilibrium constant concentration of both pure solids and liquid s are said to be equal to 1
[PbBR2] = 1
such tht
Keq = [Pb^2+] x [Br-]^2
we already know the values of these from the above.
0.01x0.025^2
= 0.01 x 0.000625
= 0.00000625
= 6.25 x 10^-6
= 6.25e^-6
Which number represetns a coefficient?
2
3
4
7
What is the process of cell eating called
Answer:
Phagocytosis
Explanation:
How does temperature affect the copper (II) chloride equilibrium? Is the forward reaction (color changing from blue to green) endothermic or exothermic? Justify your choice with experimental evidence i.e color changes in the video for Part B.
Answer:
See explanation
Explanation:
A popular experiment that describes the effect of heat on the position of equilibrum is the change of colour when copper II chloride is heated.
As the solution is heated, it's colour changes from blue to green, this implies the the colour change (blue to green) is an endothermic process (equilibrum position shifts to the right with increase in temperature)
The equilibrum is represented by the equation;
[Cu(H2O)6]^2+(aq) + 4Cl^-(aq)<------>[CuCl4]^2-(aq) + 6H2O(l) ∆H=positive
The equilibrium mixture undergoing cooling or heating have colour changes. The temperature affects the colour of the products formed and the forward reaction is endothermic.
What are the equilibrium and the forward reactions?In the reaction copper (II) chloride or [tex]\rm CuCl_{4}[/tex] is the main species. The heat or the temperature affects the colour formation of copper (II) chloride as the equilibrium change affects the colouration of the product.
The heating of the solution affects the colour change from blue to the green of the reactant to products and the forward reaction shifts the equilibrium towards the right when the temperature is increased and is an endothermic reaction.
The reaction at the equilibrium can be shown as,
[tex]\rm [Cu(H_{2}O)_{6}]^{2+} (aq) + 4Cl^{-} (aq) \Leftrightarrow [CuCl_{4}]^{2-}(aq) + 6H_{2}O(l), \Delta H=positive[/tex]
Therefore, temperature changes the colouration and the forward reaction is an endothermic reaction.
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Which of the following is NOT a strong electrolyte?
:
Answers:
Na2SO4
KI
CaCl2
LiOH
C6H1206
Answer:
C6H1206
Explanation:
C6H12O6 is a monomer of carbohydrates also known as glucose, so it is not an electrolyte at all.
What is the percent error for the experiment if the actual density is
2.49g/mL but the experimental value is 1.47 g/mL?
Answer:
The answer is 40.96%Explanation:
The percentage error of a certain measurement can be found by using the formula
[tex]P(\%) = \frac{error}{actual \: \: number} \times 100\% \\ [/tex]
From the question
actual density = 2.49g/mL
error = 2.49 - 1.47 = 1.02
We have
[tex]p(\%) = \frac{1.02}{2.49} \times 100 \\ = 40.96385542...[/tex]
We have the final answer as
40.96 %Hope this helps you
When a helium balloon rises in the air, it expands. If the volume of the balloon doubles, what happens to the density of the helium inside it?
a.The density decreases by half
b.The density doubles
c.The density triples
d.The density stays the same
How do the test variables (independent variables) and outcome variables (dependent variables) in an experiment compare? A. The test variables (independent variables) and outcome variables (dependent variables) are the same things. B. The test variable (independent variable) controls the outcome variable (dependent variable). C. The test variable (independent variable) and outcome variable (dependent variable) have no affect on each other. D. The outcome variable (dependent variable) controls the test variable (independent variable).
Answer:
I'm on the exact same queston
Answer:
The test variable (independent variable) controls the outcome variable (dependent variable)
Explanation:
its right on study island
When 435 J of heat is added to 3.4 g of olive oil that's at 21 Deg C, it's
temperature increases to 85 Deg C. Calculate the specific heat of Olive oil? Show work
Answer:
k Nishant
Explanation:
i don't know sorry but u can search in google
How many atoms are in 10 g of He
Answer:
6.7
⋅
10
23
atoms of H
Explanation:
A student reacts 5.0 g of sodium with 10.0 g of chlorine and collect 5.24 g of sodium chloride. What is the percent yield of this combination reaction
Answer: The percent yield of this combination reaction is 41.3 %
Explanation : Given,
Mass of [tex]Na[/tex] = 5.0 g
Mass of [tex]Cl_2[/tex] = 10.0 g
Molar mass of [tex]Na[/tex] = 23 g/mol
Molar mass of [tex]Cl_2[/tex] = 71 g/mol
First we have to calculate the moles of [tex]Na[/tex] and [tex]Cl_2[/tex].
[tex]\text{Moles of }Na=\frac{\text{Given mass }Na}{\text{Molar mass }Na}[/tex]
[tex]\text{Moles of }Na=\frac{5.0g}{23g/mol}=0.217mol[/tex]
and,
[tex]\text{Moles of }Cl_2=\frac{\text{Given mass }Cl_2}{\text{Molar mass }Cl_2}[/tex]
[tex]\text{Moles of }Cl_2=\frac{10.0g}{71g/mol}=0.141mol[/tex]
Now we have to calculate the limiting and excess reagent.
The balanced chemical equation will be:
[tex]2Na+Cl_2\rightarrow 2NaCl[/tex]
From the balanced reaction we conclude that
As, 2 mole of [tex]Na[/tex] react with 1 mole of [tex]Cl_2[/tex]
So, 0.217 moles of [tex]Na[/tex] react with [tex]\frac{0.217}{2}=0.108[/tex] moles of [tex]Cl_2[/tex]
From this we conclude that, [tex]Cl_2[/tex] is an excess reagent because the given moles are greater than the required moles and [tex]Na[/tex] is a limiting reagent and it limits the formation of product.
Now we have to calculate the moles of [tex]NaCl[/tex]
From the reaction, we conclude that
As, 2 mole of [tex]Na[/tex] react to give 2 mole of [tex]NaCl[/tex]
So, 0.217 mole of [tex]HCl[/tex] react to give 0.217 mole of [tex]NaCl[/tex]
Now we have to calculate the mass of [tex]NaCl[/tex]
[tex]\text{ Mass of }NaCl=\text{ Moles of }NaCl\times \text{ Molar mass of }NaCl[/tex]
Molar mass of [tex]NaCl[/tex] = 58.5 g/mole
[tex]\text{ Mass of }NaCl=(0.217moles)\times (58.5g/mole)=12.7g[/tex]
Now we have to calculate the percent yield of this reaction.
Percent yield = [tex]\frac{\text{Actual yield}}{\text{Theoretical yield}}\times 100[/tex]
Actual yield = 5.24 g
Theoretical yield = 12.7 g
Percent yield = [tex]\frac{5.24g}{12.7g}\times 100[/tex]
Percent yield = 41.3 %
Therefore, the percent yield of this combination reaction is 41.3 %
What does a dissolved salt look like?
Answer:(trick question) once the salt has dissolve in the water it is no longer visible
Thank you! have an amazing day.
The normal boiling point of benzene is 80.1°C. What is its enthalpy of vaporization if the vapor pressure at 26.1°C is 100 torr?
The heat of vaporization of benzene is required.
The heat of vaporization of benzene is 33009 J/kg.
[tex]T_0[/tex] = Normal boiling point = 80.1+273.15 K
[tex]T_B[/tex] = Boiling point at given pressure = 26.1+273.15 K
[tex]R[/tex] = Gas constant = 8.314 J/mol K
[tex]P[/tex] = Pressure at given [tex]T_B[/tex] = 100 torr
[tex]\Delta H[/tex] = Heat of vaporization
From the Clausius–Clapeyron equation
[tex]\dfrac{1}{T_B}=\dfrac{1}{T_0}-\dfrac{R\ln(\dfrac{P}{P_0})}{\Delta H}\\\Rightarrow \Delta H=\dfrac{R\ln\dfrac{P}{P_0}}{\dfrac{1}{T_0}-\dfrac{1}{T_B}}\\\Rightarrow \Delta H=\dfrac{8.314\times \ln\left(\frac{100}{760}\right)}{\frac{1}{80.1+273.15}-\frac{1}{26.1+273.15}}\\\Rightarrow \Delta H=33008.99\ \text{J/kg}[/tex]
The heat of vaporization of benzene is 33009 J/kg.
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The empirical formula of CBr2 has a molar mass of 515.46 g/mol. What is the molecular formula of this
compound
Answer:
C3Br6
Explanation:
C= (1 X 12.011) = 12.011
Br= (2 X 79.904)= 159.808
159.808+12.011 = 171.819
515.46 divided by 171.819 = 3.00
so you mulitpy CBr2 by 3 which gives you C3Br6
The pKb values for the dibasic base B are pKb1=2.10 and pKb2=7.54. Calculate the pH at each of the points in the titration of 50.0 mL of a 0.60 M B(aq) solution with 0.60 M HCl(aq).
Complete Question
The pKb values for the dibasic base B are pKb1=2.10 and pKb2=7.54. Calculate the pH at each of the points in the titration of 50.0 mL of a 0.60 M B(aq) solution with 0.60 M HCl(aq).
(a) before addition of any HCl (b) after addition of 25.0 mL of HCl
Answer:
a The value is [tex]pH =12.81[/tex]
b [tex]pH = 11.9[/tex]
Explanation:
From the question we are told that
The first pKb value for B is [tex]pK_b_1 = 2.10[/tex]
The second pKb value for B is [tex]pK_b_2 = 7.54[/tex]
The volume is [tex]V = 50.0 mL =[/tex]
The concentration of B is [tex][B] = 0.60 M[/tex]
The concentration of [tex]C_A = 0.60 M[/tex]
Generally the reaction equation showing the first dissociation of B is
[tex]\ce{B_{(aq) } + H_2O _{(l)} <=> BH^+ _{(aq)} + OH^- _{(aq)} }[/tex]
Here the ionic constant for B is mathematically represented as
[tex]K_i = \frac{[BH^+] [OH^-]}{[B]}[/tex]
Let denot the concentration of [BH^+] as z and since [tex][BH^+] = [OH^-][/tex] then [tex][OH^-][/tex] is also z
So [B] = 0.60 - z
Here [tex]K_i[/tex] is ionic constant for the first reaction of a dibasic base B and the value is
[tex]K_i = 7.94 *10^{-3}[/tex]
So
[tex] 7.94 *10^{-3}= \frac{z^2}{ 0.60 - z}[/tex]
=> [tex]z^ 2 + 0.00794 z - 0.00476[/tex]
using quadratic formula to solve this equation
[tex]z = 0.0651[/tex]
Hence the concentration of [tex]OH^{-}[/tex] is [tex][OH^-] =0.0651[/tex]
Generally [tex]pOH = -log [OH^-][/tex]
=> [tex]pOH = -log (0.065)[/tex]
=> [tex]pOH = 1.187 [/tex]
Generally the pH is mathematically represented as
[tex]pH = 14 - 1.187[/tex]
[tex]pH =12.81[/tex]
Generally the volume of [tex]HCl[/tex] at the second dissociation of the base B is [tex] 50 mL [/tex]
The volume of the [tex]HCl[/tex] half way to the first dissociation of the base is 25mL
Now the pOH at half way to the first dissociation of the base is
[tex]pOH = -log(K_i)[/tex]
=> [tex]pOH = -log(0.00794)[/tex]
=> [tex]pOH = 2.100[/tex]
Generally the pH after addition of 25.0 mL of HCl is
[tex]pH = 14 - 2.100[/tex]\
=> [tex]pH = 11.9[/tex]
The first dissociation's equation is as follows:
[tex]B(aq) + H_2O(l) \leftrightharpoons BH^{+} (aq) + OH^{-}(aq) \\\\[/tex]
Constant of base ionization
[tex]\to K_{bl}=\frac{[BH^{+}][OH^{-}]}{[B]}\\\\ \to 7.94\times 10^{-3} = \frac{x\times x}{(0.95- x)} \\\\\to 7.94\times 10^{-3} = \frac{x^2}{(0.95- x)} \\\\\to x^2=7.94\times 10^{-3} (0.95-x) \\\\\to x^2=7.543\times 10^{-3} - 7.94\times 10^{-3} x) \\\\\to x^2=7.543\times 10^{-3} - 7.94\times 10^{-3} x) \\\\\to x = 0.0830\ M\\\\[/tex]
So,
[tex]\to [OH^{-}] = 0.0830\ M\\\\[/tex]
The second dissociation of the base equation is
[tex]BH^{+}\ (aq) + H_20\ (l) \leftrightharpoons BH_2^{2+}\ (aq) + OH^{-}\ (aq) \\\\[/tex]
Constant of base ionization
[tex]\to K_{bl}=\frac{[BH^{+}][OH^{-}]}{[B]}\\\\ \to 3.2 \times 10^{-8} =\frac{y \times (0.0830+y)}{(0.0830- y)}\\\\[/tex]
[tex]\to y= \frac{ 3.2 \times 10^{-8} \times (0.0830- y)}{ (0.0830+y)} \\\\ \to y= \frac{ 3.2 \times 10^{-8} \times (0.0830- y)}{ (0.0830+y)} \\\\ \to y = 3.2\times 10^{-8}[/tex]
So,
[tex]\to [OH^{-}] = 0.0830\ M \\\\\to pOH = 1.08 \\\\\to pH = 14.00 - pOH = 12.92\\\\[/tex]
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An ideal gaseous reaction (which is a hypothetical gaseous reaction that conforms to the laws governing gas behavior) occurs at a constant pressure of 35.0 atm and releases 74.6 kJ of heat. Before the reaction, the volume of the system was 8.20 L . After the reaction, the volume of the system was 2.80 L . Calculate the total internal energy change, ΔE, in kilojoules.
Answer:
ΔU = −55.45 kJ
Explanation:
From first law of thermodynamics in chemistry, we have;
ΔU = Q + W
where;
ΔU is change in internal energy
Q is the net heat transfer
W is the net work done
We are given;
Q = 74.6 kJ
But Q will be negative since heat is released
Thus;
ΔU = -74.6 kJ + W
We are given;
Constant pressure; P = 35 atm = 35 × 101325 = 3546375 N/m²
Volume before reaction; Vi = 8.2 L = 0.0082 m³
Volume after reaction; V_f = 2.8 L = 0.0028 m³
Now,
W = -P(V_f - V_i)
W = - 3546375(0.0028 - 0.0082)
W = 19.15 KJ
Thus;
ΔU = Q + W
ΔU = -74.6 kJ + 19.15 KJ =
ΔU = −55.45 kJ
Determine the molar mass of CaO
A scientist discovers remnants of an organism on a slide under his microscope. He can only identify a few components: a large vacuole, ridged cell wall, and a chloroplast. Was the organism prokaryotic or eukaryotic? How do you know?
Answer:
Eukaryotic (a plant cell)
Explanation:
The presence of a chloroplast indicates that the cell has membrane-bound organelles. This is not a feature of prokaryotic cells - only eukaryotic cells. Therefore, the cell is eukaryotic. The presence of a large vacuole, chloroplast, and rigid cell wall suggests its a plant cell as plant cells are the only eukaryotes with these features.
How is matter divided?
Calculate the theoretical density (in g/cm3) of copper (Cu), given that it has the FCC structure. The atomic weight of Cu is 63.55 g/mol, and its atomic radius R is 0.1278 nm.
Answer:
8.937g/cm³
Explanation:
To answer this question we need to know that, in 1 unit FCC cell you have:
Edge length = √8 * R
Volume = 8√8 * R³
And there are 4 atoms per unit cell
Mass of 4 atoms in g:
4 atom * (1mol / 6.022x10²³atom) * (63.55g / mol) = 4.221x10⁻²²g
Volume in cm³:
0.1278nm * (1x10⁻⁷cm / 1nm) = 1.278x10⁻⁸cm
Volume = 8√8 * (1.278x10⁻⁸cm)³
Volume = 4.723x10⁻²³cm³
And density is:
4.221x10⁻²²g / 4.723x10⁻²³cm³ =
8.937g/cm³A chemist prepares a solution of silver(II) oxide by measuring out 0.0013 of silver(II) oxide into a 100 mL volumetric flask and filling the flask to the mark with water. Calculate the concentration in of the chemist's silver(II) oxide solution. Be sure your answer has the correct number of significant digits.
Answer:
1.3x10⁻⁸ mol/L
Explanation:
0.0013μmol, Calculate concentration in mol/L
To obtain concentration in mol/L we need to convert the μmoles to moles and mL to liters:
Moles silver(II) oxide:
0.0013μmol × (1mol / 1x10⁶μmol) = 1.3x10⁻⁹ moles
Liters solution:
100mL * (1L / 1000mL) = 0.1L
That means concentration in mol/L is:
1.3x10⁻⁹ moles / 0.1L =
1.3x10⁻⁸ mol/L