If rates of both reduction and oxidation half-reactions are moderated by activation polarisation, using below information, determine the rate of corrosion of zinc.
For Zn
For H2
E(Zn/Zn2+) = -0.763V
E(H+/H2) = 0V
i0 = 10-7 A/cm2
i0 = 10-10 A/cm2
β = +0.09
β = -0.08
Data:
F = 96500 C/mol)
na = ± β log i/i0
Kc = i/nF

Answers

Answer 1

The rate of corrosion of Zinc is given as i =[tex]10^{-7[/tex] /A exp[0.09(η+0.704)] and Kc = 5.22 x [tex]10^{-14[/tex] exp[0.09(η+0.704)].

E(Zn/Zn2+) = -0.763 V

E(H+/H2) = 0 V

i0 = [tex]10^{-7[/tex]A/cm^2, i0 =[tex]10^{-10[/tex] A/cm^2

β = +0.09, β = -0.08

Data: F = 96500 C/mol), na = ± β log i/i0, Kc = i/nF

The half reaction for Zinc, Zn, is given as: Zn → Zn2+ + 2e-. The standard electrode potential (E°) for this reaction is -0.763 V.

The half reaction for Hydrogen, H2, is given as: 2H+ + 2e- → H2. The standard electrode potential (E°) for this reaction is 0 V.

To determine the rate of corrosion of Zinc, we can use the equation: na = ± β log i/i0

The anodic polarization current density is given by: i = i0exp[β(η-ηcorr)], where i0 is the exchange current density, β is the Tafel slope, η is the overpotential, and ηcorr is the corrosion potential.

ηcorr is the equilibrium potential for the electrochemical corrosion reaction. For Zinc (Zn), the corrosion reaction is Zn → Zn2+ + 2e-. The corrosion potential (ηcorr) can be calculated using the Nernst Equation.

E = E° + (RT/nF) ln Q

Where:

E = cell potential

E° = standard electrode potential

R = gas constant (8.31 J/K·mol)

T = temperature (in Kelvin)

F = Faraday constant (96500 C/mol)

n = the number of electrons transferred

Q = reaction quotient = [Zn2+]/[Zn]

E° = -0.763 V, n = 2, [Zn2+] = 1, [Zn] = 1, R = 8.31 J/K·mol, T = 298 K, F = 96500 C/mol

E = -0.763 V + (8.31 J/K·mol x 298 K / 2 x 96500 C/mol) ln 1/1

E = -0.763 V + 0.059 V

E = -0.704 V

ηcorr = -0.704 V

For Hydrogen, H2:

ηcorr = E° = 0 V

β = -0.08, i0 = [tex]10^{-10[/tex] A/cm^2

The rate of corrosion of Zinc can be determined using the equation:

i = i0exp[β(η-ηcorr)]

η is the overpotential.

η = ηcorr + IR

Where:

R is the resistance of the solution

I = i/A = I0/A exp[β(η-ηcorr)] = [tex]10^{-7[/tex] /A exp[-0.09(η-ηcorr)]

For Zinc, A = 1 [tex]cm^2[/tex], i0 = [tex]10^{-7[/tex]A/cm^2

β = +0.09, ηcorr = -0.704 V

Therefore:

I = [tex]10^{-7[/tex] /1 exp[0.09(η+0.704)]

The equation for Kc is given as:

Kc = i/nF

Kc = i / 2F [for Zn → Zn2+ + 2e-]

Kc = [tex]10^{-7[/tex] /1 exp[

0.09(η+0.704)] / 2 x 96500 x 1

Kc = 5.22 x [tex]10^{-14[/tex]exp[0.09(η+0.704)]

Therefore, the rate of corrosion of Zinc is given as i = [tex]10^{-7[/tex] /A exp[0.09(η+0.704)] and Kc = 5.22 x 10^-14 exp[0.09(η+0.704)].

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Related Questions

Consider the following pair of loan options for a $165,000 mortgage Calculate the monthly payment and total closing costs for each option. Explain which is the better option and why. Choice 1: 15-year fixed rate at 6.5% with closing costs of $1400 and 1 point. Choice 2 15-year fixed rate at 6.25% with closing costs of $1400 and 2 points. What is the monthly payment for choice 1? 1/1) 0.334

Answers

Long-term financial goals, cash flow, and how long you plan to stay in the property when deciding between the two options.

To calculate the monthly payment and total closing costs for each loan option, we need to consider the loan amount, interest rate, loan term, and points.

Choice 1:

Loan amount: $165,000

Interest rate: 6.5%

Loan term: 15 years

Closing costs: $1,400

Points: 1

To calculate the monthly payment for Choice 1, we can use the loan payment formula:

M = P [ i(1 + i)^n ] / [ (1 + i)^n - 1 ]

Where:

M = Monthly payment

P = Loan amount

i = Monthly interest rate (annual rate divided by 12)

n = Number of monthly payments (loan term in years multiplied by 12)

First, let's calculate the monthly interest rate for Choice 1:

i = 6.5% / 100 / 12 = 0.0054167

Now, let's calculate the number of monthly payments:

n = 15 years * 12 = 180 months

Plugging these values into the formula, we can calculate the monthly payment for Choice 1:

M = 165,000 [ 0.0054167(1 + 0.0054167)^180 ] / [ (1 + 0.0054167)^180 - 1 ]

Using a financial calculator or spreadsheet software, the monthly payment for Choice 1 comes out to be approximately $1,449.84.

Now let's calculate the total closing costs for Choice 1:

Total closing costs = Closing costs + (Points * Loan amount)

Total closing costs = $1,400 + (1 * $165,000) = $1,400 + $165,000 = $166,400

Choice 2:

Loan amount: $165,000

Interest rate: 6.25%

Loan term: 15 years

Closing costs: $1,400

Points: 2

Following the same calculations as above, the monthly payment for Choice 2 comes out to be approximately $1,432.25, and the total closing costs for Choice 2 would be $167,800.

Now, to determine which option is better, we need to consider both the monthly payment and total closing costs. In this case, Choice 2 has a lower monthly payment, but it comes with higher total closing costs due to the higher points.

Ultimately, the better option depends on your financial situation and preferences. If you prefer a lower monthly payment, Choice 2 may be more favorable. However, if you want to minimize the total cost of the loan, including closing costs, Choice 1 would be the better option.

Consider factors such as your long-term financial goals, cash flow, and how long you plan to stay in the property when deciding between the two options.

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Which graph represents the function? f(x) = 1/x-1 - 2

Answers

The graph of the function f(x) = 1/(x - 1) - 2 is added as an attachment

Sketching the graph of the function

From the question, we have the following parameters that can be used in our computation:

f(x) = 1/(x - 1) - 2

The above function is a radical function that has been transformed as follows

Shifted right by 1 unitsShifted down by 2 units

Next, we plot the graph using a graphing tool by taking note of the above transformations rules

The graph of the function is added as an attachment

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The Lax-Milgram theorem assures the existence and uniqueness of weak solutions. One must choose the Hilbert space appropriately when applying the Lax-Milgram theorem to the boundary value problem. The boundary value problem (P1) has a weak solution for any given function f∈L^2(I). The boundary value problem (P1) has a classical solution for any given function f∈L^2(I). The variational approach for the boundary value problem (P1) is completed when f∈C(Iˉ).
Previous questionNext question

Answers

The Lax-Milgram theorem guarantees the existence and uniqueness of weak solutions in boundary value problems.

How does the choice of Hilbert space impact the application of the Lax-Milgram theorem?

The Lax-Milgram theorem is a fundamental result in functional analysis that provides conditions for the existence and uniqueness of weak solutions to certain boundary value problems.

To apply the theorem successfully, it is crucial to select the appropriate Hilbert space that satisfies the necessary properties for the problem at hand. The choice of Hilbert space depends on the nature of the problem and the desired regularity of solutions.

By selecting the Hilbert space appropriately, one ensures that the underlying variational formulation is well-posed and the weak solution exists and is unique. This theorem is widely used in the analysis of partial differential equations and plays a significant role in various areas of mathematics and engineering.

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An RL series circuit has an EMF (in volts) given by 3 cos 2t, a resistance of 10 ohms, an inductance of 0.5 Henry, and an initial current of 5 Amperes. Find the current in the series circuit at any time t.

Answers

The current in the series R-L circuit, at any given time 't' can be represented as:

I = 3Sin(2t) - 100t + 5

We use the differential equation which represents a series R-L circuit in general, and find its solutions accordingly to find the final answer.

The differential equation which denotes a series R-L circuit goes as follows:

L (dI/dt) + IR = E

where,

L -> Inductance, with units as Henry

R -> Resistance in Ohms

I -> Current, in Amperes

E -> Electromotive Force, in Volts

In the question, we have been given the data:

L = 0.5 Henry

E = 3*Cos(2t)

R = 10 Ohms

By substituting these in the equation, we solve for the necessary terms.

0.5(dI/dt) + I(10) = 3Cos(2t)

Since the initial current is given as 5 Amperes, we substitute that into the equation.

So, we have:

0.5(dI/dt) + 5(10) = 3Cos(2t)

0.5(dI/dt) + 50 = 3Cos(2t)

0.5(dI/dt) = 3Cos(2t) - 50

dI/dt = (3Cos(2t) - 50)/0.5

dI/dt= 6Cos(2t) - 100

dI= [ 6Cos(2t) - 100 ]dt

Finally, we integrate the equation.

∫dI = ∫ [ 6Cos(2t) - 100 ]dt

I = ∫6Cos(2t) dt - ∫100dt

I = 6∫Cos(2t)dt - 100t

I = (6/2)(Sin(2t) - 100t + C                      ( ∫Cost = Sint)

I = 3Sin(2t) - 100t + C

Here, C is the constant of Integration. We need to find that to successfully complete our solution.

Since we have been given the initial current as 5A, which is at t = 0, we substitute t = 0 and I = 5 in the equation.

5 = 3Sin(2*0) - 100(0) + C

5 = 0 - 0 + C

C = 5.

So, the final equation for the current in the given R-L circuit is:

I = 3Sin(2t) - 100t + 5

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Determine the zeroes of the function of f(x)=
3(x2-25)(4x2+4x+1)

Answers

The zeroes of the function f(x) = 3(x²-25)(4x^2+4x+1) are x = -5, x = 5, x = -0.5 - 0.5i, and x = -0.5 + 0.5i.

To find the zeroes of the given function f(x), we set f(x) equal to zero and solve for x. The function f(x) can be factored as follows: f(x) = 3(x²-25)(4x²+4x+1).

The first factor, (x²-25), is a difference of squares and can be further factored as (x-5)(x+5). The second factor, (4x²+4x+1), is a quadratic trinomial and cannot be factored further.

Setting each factor equal to zero, we have three equations: (x-5)(x+5) = 0 and 4x²+4x+1 = 0. Solving the first equation, we find x = -5 and x = 5 as the zeroes.

To solve the second equation, we can use the quadratic formula: x = (-b ± √(b²-4ac))/(2a), where a = 4, b = 4, and c = 1. Plugging in these values, we get x = (-4 ± √(4^2-4*4*1))/(2*4). Simplifying further, we have x = (-4 ± √(16-16))/(8), which simplifies to x = (-4 ± √0)/(8). Since the discriminant is zero, the quadratic has complex conjugate zeroes. Therefore, x = -0.5 - 0.5i and x = -0.5 + 0.5i are the remaining zeroes of the function.

In summary, the zeroes of the function f(x) = 3(x²-25)(4x²+4x+1) are x = -5, x = 5, x = -0.5 - 0.5i, and x = -0.5 + 0.5i.

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Someone help with process pleaseee

Answers

Answer: n= 6  x= 38.7427    f= 4.618802    h= 9.237604

Step-by-step explanation:

for the first one:

there are 2 45 90 triangles. Since the sides of a 45 90 triangle are n for 45 and [tex]n\sqrt{2}[/tex] for the 90 degrees, that means that if [tex]6\sqrt{2} = n\sqrt{2}[/tex] then n is 6.

Second one:

You have to split the x into two parts.

Starting on the first part use the 30 60 90 triangle with given with the length for the 60°

60 = [tex]n\sqrt{3}[/tex]

so [tex]30=n\sqrt{3}[/tex]

n = 17.320506

so part of x is 17.320506

For the next triangle you would use Tan 35 = [tex]\frac{15}{y}[/tex]

this would equal 21.422201

adding both values up it would be 38.742707

Third question:

There is two 30 60 90 triangles

The 60° is equal to 8 which means [tex]8=n\sqrt{3}[/tex]

Simplifying this [tex]n=4.618802[/tex]

h = 2n.      which is h= 9.237604

f=n             f is 4.618802

Answer:

Special right-angle triangle:

1) Ratio of angles: 45: 45: 90

  Ratio of sides: 1: 1: √2

Sides are n, n, n√2

  The side opposite to 90° = n√2

           n√2 = 6√2

                [tex]\boxed{\sf n = 6}[/tex]

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

2) Ratio of angles: 30: 60: 90

  Ratio of side: 1: √3: 2

Sides are m, m√3, 2m.

Side opposite to 60° = m√3

     m√3 = 30

           [tex]m = \dfrac{30}{\sqrt{3}}\\\\\\m = \dfrac{30\sqrt{3}}{3}\\\\m = 10\sqrt{3}[/tex]

Side opposite to 30° = m

          m = 10√3

In ΔABC,

          [tex]Tan \ 35= \dfrac{opposite \ side \ of \angle C }{adjacent \ side \ of \angle C}\\\\\\~~~~~~0.7 = \dfrac{15}{CB}\\\\[/tex]

       0.7 * CB = 15

                [tex]CB =\dfrac{15}{0.7}\\\\CB = 21.43[/tex]

x = m + CB

   = 10√3 + 21.43

  = 10*1.732 + 21.43

  = 17.32 + 21.43

  = 38.75

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

3) Ratio of angles: 30: 60: 90

    Ratio of side: 1: √3: 2

Sides are y, y√3, 2y.

Side opposite to 60° = y√3

         [tex]\sf y\sqrt{3}= 8\\\\ ~~~~~ y = \dfrac{8}{\sqrt{3}}\\\\~~~~~ y =\dfrac{8*\sqrt{3}}{\sqrt{3}*\sqrt{3}}\\\\\\~~~~~ y =\dfrac{8\sqrt{3}}{3}[/tex]

    Side opposite to 30° = y

              [tex]\sf f = y\\\\ \boxed{f = \dfrac{8\sqrt{3}}{3}}[/tex]

 Side opposite to 90° = 2y

           h = 2y

          [tex]\sf h =2*\dfrac{8\sqrt{3}}{3}\\\\\\\boxed{h=\dfrac{16\sqrt{3}}{3}}[/tex]    

A tree which has wood with a density of 650 kg/m3
falls into a river. Based solely on the material density, explain
in detail if the tree is expected to sink or float in the
river.

Answers

Based on the material density of the wood (650 kg/m³), the tree is expected to float in the river.

Whether an object sinks or floats in a fluid (such as water) depends on the relative densities of the object and the fluid. The density of the wood in the tree is given as 650 kg/m³. Comparing this density to the density of water, which is approximately 1000 kg/m³, we can determine the behaviour of the tree.

When an object is placed in a fluid, it experiences an upward buoyant force equal to the weight of the fluid it displaces. If the object's density is less than the fluid's density, the buoyant force is greater than the object's weight, causing it to float. In this case, the wood's density of 650 kg/m³ is less than the density of water, indicating that the tree will float.

The buoyant force exerted on the tree is determined by the volume of water displaced by the submerged part of the tree. Since the tree is less dense than water, it will displace a volume of water that weighs more than the tree itself, resulting in a net upward force that keeps the tree afloat. However, it's important to note that other factors such as the shape, size, and water absorption properties of the wood can also influence the floating behavior of the tree.

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4. What is the chance that the culvert designed for an event of 95-year return period will have (2 marks) its capacity exceeded at least once in 50 years?

Answers

The chance that a culvert designed for a 95-year return period will have its capacity exceeded at least once in 50 years, we need to consider the probability of exceeding the capacity within a given time period.

The probability of a specific event occurring within a certain time period can be estimated using a Poisson distribution. However, to provide an accurate answer, we need information about the characteristics of the culvert and the specific flow data associated with it.

The return period of 95 years indicates that the culvert is designed to handle a certain flow rate that is expected to occur, on average, once every 95 years.

If the culvert is operating within its design limits, the chance of its capacity being exceeded in any given year would be relatively low. However, over a longer period, such as 50 years, there is a greater likelihood of a capacity-exceeding event occurring.

To obtain the accurate estimate, it would be necessary to analyze historical flow data for the culvert and assess its hydraulic capacity in relation to the expected flows. Professional hydraulic engineers would typically conduct this analysis using statistical methods and models specific to the culvert's design and location.

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A new process has been proposed for the synthesis of Ibuprofen that uses Liquid Liquid Extraction (LLE). Within the process a solution of water and methanol infinitely miscible mixture) is fed to a stirred mixing tank at a rate of 5 lb/min. A stream of pure toluene is also fed to this stirred tank. The mixture is then fed to a decanter, where one of the product streams (i.e., phases) contains 88 wt% toluene and has a flow rate of 10 lb/min. Using the ternary diagram (last page), what is the composition and flow rate of the other product stream? What is the flow rate of the pure toluene stream?

Answers

- The composition of the other product stream can be determined by drawing a line from the feed solution point to the point representing the product stream with 88 wt% toluene on the ternary diagram.

- The flow rate of the other product stream can be calculated by subtracting the flow rate of the product stream with 88 wt% toluene from the total flow rate of the feed solution.

- The flow rate of the pure toluene stream can be calculated by subtracting the flow rate of the other product stream from the total flow rate of the feed solution.

The composition and flow rate of the other product stream can be determined using the ternary diagram.

First, let's locate the point on the diagram that represents the feed solution, which is a mixture of water, methanol, and toluene. Based on the information provided, the feed solution consists of water and methanol in an infinitely miscible mixture. This means that the feed solution lies on the line connecting the water and methanol vertices.

Next, draw a line from the feed solution point to the point representing the product stream with 88 wt% toluene. This line represents the composition of the other product stream.

To determine the flow rate of the other product stream, we need to calculate the difference between the total flow rate of the feed solution (5 lb/min) and the flow rate of the product stream with 88 wt% toluene (10 lb/min). Since the total flow rate is greater than the flow rate of the product stream, there must be another product stream with a positive flow rate.

The flow rate of the pure toluene stream can be calculated by subtracting the flow rate of the other product stream from the total flow rate of the feed solution.

In summary:

- The composition of the other product stream can be determined by drawing a line from the feed solution point to the point representing the product stream with 88 wt% toluene on the ternary diagram.

- The flow rate of the other product stream can be calculated by subtracting the flow rate of the product stream with 88 wt% toluene from the total flow rate of the feed solution.

- The flow rate of the pure toluene stream can be calculated by subtracting the flow rate of the other product stream from the total flow rate of the feed solution.

This approach will give us the desired composition and flow rates.

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"
The band is breaking up and Rob, Sue, Tim and Vito each want the tourbus. Using the method of sealed bids, Rob bids $2500, Sue bids$5400, Tim bids $2400, and Vito bids $6200 for the bus. SinceVito'

Answers

Rob will receive approximately $1133.33 from Vito.

To determine how much money Rob will get from Vito, we need to calculate the fair division of the bids among the four individuals. Since Vito won the bus with the highest bid, he will compensate the others based on their bids.

The total amount of compensation that Vito needs to pay is the sum of all the bids minus the winning bid. Let's calculate it:

Total compensation = (Rob's bid + Sue's bid + Tim's bid) - Vito's bid

                 = ($2500 + $5400 + $2400) - $6200

                 = $10300 - $6200

                 = $4100

Now, we need to determine the amount of money each person will receive. To calculate the fair division, we divide the total compensation by the number of people (4) excluding Vito, since he won the bid.

Rob's share = (Rob's bid) - (Total compensation / Number of people)

           = $2500 - ($4100 / 3)

           ≈ $2500 - $1366.67

           ≈ $1133.33

Thus, the appropriate answer is approximately $1133.33 .

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What is the minimum number N of integers that we can have so
that at least nine
have the same last digit?

Answers

The minimum number N of integers that we can have to ensure they all have the same last digit is 10.

To understand why, let's consider the possible last digits for numbers. There are 10 possible last digits: 0, 1, 2, 3, 4, 5, 6, 7, 8, and 9.

Now, if we have a set of N integers, each with a different last digit, we can conclude that N must be greater than or equal to 10. This is because if N is less than 10, at least two of the integers must have the same last digit.

For example, if we have only 9 integers, we can't have all 10 possible last digits represented. So, to ensure that all integers have the same last digit, we need a minimum of 10 integers.

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118.2 mol/h of pure ethanol is burned with 47.8% excess dry air. If the combustion is complete and the flue gases exit at 1.24 atm, determine its dew point temperature. Type your answer in ∘
C,2 decimal places. Antoine equation: logP(mmHg)=A− C+T( ∘
C)
B
A=8.07131 for water: B=1730.63 C=233.426

Answers

The dew point temperature of the flue gases is 23672.604 °C.

To determine the dew point temperature of the flue gases, we need to use the Antoine equation. The Antoine equation relates the vapor pressure of a substance to its temperature.

The given Antoine equation for water is:
logP(mmHg) = A - (C / (T + B))

Where:
A = 8.07131
B = 1730.63
C = 233.426

To find the dew point temperature, we need to find the temperature at which the vapor pressure of water in the flue gases equals the partial pressure of water vapor at that temperature.

First, we need to calculate the partial pressure of water vapor in the flue gases. We can do this by using the ideal gas law and Dalton's law of partial pressures.

Given:
Total pressure of the flue gases (Ptotal) = 1.24 atm
Excess dry air = 47.8%

Since the combustion is complete, the moles of water produced will be equal to the moles of oxygen consumed. The moles of oxygen consumed can be calculated using the stoichiometry of the reaction. The balanced equation for the combustion of ethanol is:

C2H5OH + 3O2 -> 2CO2 + 3H2O

From the equation, we can see that for every 1 mole of ethanol burned, 3 moles of water are produced. Therefore, the moles of water produced in the combustion of 118.2 mol/h of ethanol is 3 * 118.2 = 354.6 mol/h.

Since the dry air is in excess, we can assume that the oxygen in the dry air is the limiting reactant. This means that all the ethanol is consumed in the reaction and the moles of water produced will be equal to the moles of oxygen consumed.

Now, we need to calculate the moles of oxygen in the dry air. Since dry air contains 21% oxygen by volume, the moles of oxygen in the dry air can be calculated as follows:

Moles of oxygen = 21/100 * 118.2 mol/h = 24.822 mol/h

Therefore, the moles of water vapor in the flue gases is also 24.822 mol/h.

Next, we can calculate the partial pressure of water vapor in the flue gases using Dalton's law of partial pressures:

Partial pressure of water vapor (Pvap) = Xvap * Ptotal

Where:
Xvap = moles of water vapor / total moles of gas

Total moles of gas = moles of water vapor + moles of dry air

Total moles of gas = 24.822 mol/h + 118.2 mol/h = 143.022 mol/h

Xvap = 24.822 mol/h / 143.022 mol/h = 0.1735

Partial pressure of water vapor (Pvap) = 0.1735 * 1.24 atm = 0.21614 atm

Now, we can substitute the values into the Antoine equation to find the dew point temperature:

log(Pvap) = A - (C / (T + B))

log(0.21614) = 8.07131 - (233.426 / (T + 1730.63))

Solving for T:

log(0.21614) - 8.07131 = -233.426 / (T + 1730.63)

-7.85517 = -233.426 / (T + 1730.63)

Cross multiplying:

-7.85517 * (T + 1730.63) = -233.426

-T - 30339.17 = -233.426

-T = -23672.604

T = 23672.604

Therefore, the dew point temperature of the flue gases is 23672.604 °C.

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Liquids (identified below) at 25°C are completely vaporized at 1(atm) in a countercurrent heat exchanger. Saturated steam is the heating medium, available at four pressures: 4.5, 9, 17, and 33 bar. Which variety of steam is most appropriate for each case? Assume a minimum approach AT of 10°C for heat exchange. (a) Benzene; (b) n-Decane; (c) Ethylene glycol; (d) o-Xylene

Answers

The problem requires to determine the steam pressure for each of the liquids at 25°C that are completely vaporized at 1 (atm) in a countercurrent heat exchanger and the saturated steam is the heating medium available at four pressures: 4.5, 9, 17, and 33 bar.

Firstly, to solve the problem, we need to determine the boiling points of the given liquids. The boiling point is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid, and thus the liquid evaporates quickly. We can use the Clausius-Clapeyron equation to determine the boiling points of the given liquids. From the tables, we can determine the vapor pressures of the liquids at 25°C. We know that if the vapor pressure of a liquid is equal to the surrounding pressure, it will boil. The appropriate steam pressure for each of the liquids is given below:a) Benzene: The vapor pressure of benzene at 25°C is 90.8 mmHg. The pressure of saturated steam at 25°C is 3.170 bar. Thus, we need steam pressure above 3.170 bar to vaporize benzene. Hence, 4.5 bar is the most appropriate steam pressure for benzene. b) n-Decane: The vapor pressure of n-decane at 25°C is 9.42 mmHg. The pressure of saturated steam at 25°C is 3.170 bar. Thus, we need steam pressure above 3.170 bar to vaporize n-decane. Hence, 4.5 bar is the most appropriate steam pressure for n-decane.c) Ethylene glycol: The vapor pressure of ethylene glycol at 25°C is 0.05 mmHg. The pressure of saturated steam at 25°C is 3.170 bar. Thus, we need steam pressure above 3.170 bar to vaporize ethylene glycol. Hence, 9 bar is the most appropriate steam pressure for ethylene glycol. d) o-Xylene: The vapor pressure of o-xylene at 25°C is 16.2 mmHg. The pressure of saturated steam at 25°C is 3.170 bar. Thus, we need steam pressure above 3.170 bar to vaporize o-xylene. Hence, 17 bar is the most appropriate steam pressure for o-xylene.

Thus, we conclude that the most appropriate steam pressure for each of the given liquids at 25°C is 4.5 bar for benzene and n-decane, 9 bar for ethylene glycol, and 17 bar for o-xylene.

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A total of 0.264 L of hydrogen gas is collected over water at 21.0°C. The total pressure is 703 torr. If the vapor pressure of water at 21.0°C is 15.7 torr, what is the partial pressure of hydrogen?

Answers

the partial pressure of hydrogen is 687.3 torr.

To determine the partial pressure of hydrogen, we need to subtract the vapor pressure of water from the total pressure.

Partial pressure of hydrogen = Total pressure - Vapor pressure of water

Partial pressure of hydrogen = 703 torr - 15.7 torr

Partial pressure of hydrogen = 687.3 torr

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How many grams of mercury metal will be deposited from a solution that contains Hg^2+ ions if a current of 0.935 A is applied for 55.0 minutes.

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approximately 9.25 grams of mercury metal will be deposited from the solution containing Hg²+ ions when a current of 0.935 A is applied for 55.0 minutes.

To determine the mass of mercury metal deposited, we can use Faraday's law of electrolysis, which relates the amount of substance deposited to the electric charge passed through the solution.

The equation for Faraday's law is:

Moles of Substance = (Charge / Faraday's constant) * (1 / n)

Where:

- Moles of Substance is the amount of substance deposited or produced

- Charge is the electric charge passed through the solution in coulombs (C)

- Faraday's constant is the charge of 1 mole of electrons, which is 96,485 C/mol

- n is the number of electrons transferred in the balanced equation for the electrochemical reaction

In this case, we are depositing mercury (Hg), and the balanced equation for the deposition of Hg²+ ions involves the transfer of 2 electrons:

Hg²+ + 2e- -> Hg

Given:

- Current = 0.935 A

- Time = 55.0 minutes

First, we need to convert the time from minutes to seconds:

[tex]Time = 55.0 minutes * 60 seconds/minute = 3300 seconds[/tex]

Next, we can calculate the charge passed through the solution using the equation:

[tex]Charge (Coulombs) = Current * Time\\Charge = 0.935 A * 3300 s[/tex]

Now, we can calculate the moles of mercury deposited using Faraday's law:

Moles of mercury = (Charge / Faraday's constant) * (1 / n)

Moles of mercury = (0.935 A * 3300 s) / (96,485 C/mol * 2)

Finally, we can calculate the mass of mercury using the molar mass of mercury (Hg):

Molar mass of mercury (Hg) = [tex]200.59 g/mol[/tex]

Mass of mercury = Moles of mercury * Molar mass of mercury

Mass of mercury = [(0.935 A * 3300 s) / (96,485 C/mol * 2)] * 200.59 g/mol

Calculating this, we find:

Mass of mercury ≈ [tex]9.25 grams[/tex]

Therefore, approximately 9.25 grams of mercury metal will be deposited from the solution containing Hg²+ ions when a current of 0.935 A is applied for 55.0 minutes.

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What is ΔHsys for a reaction at 28 °C with
ΔSsurr = 466 J mol-1 K-1 ?
Express your answer in kJ mol-1 to at least two
significant figures.

Answers

The ΔHsys for the reaction at 28 °C is approximately -122.52 kJ mol^(-1). , We can use the relationship between ΔHsys, ΔSsurr (change in entropy of the surroundings), and the temperature (T) in Kelvin.

To calculate ΔHsys (the change in enthalpy of the system) for a reaction, we can use the equation:

ΔGsys = ΔHsys - TΔSsys

ΔGsys is the change in Gibbs free energy of the system,

T is the temperature in Kelvin,

ΔSsys is the change in entropy of the system.

At constant temperature and pressure, the change in Gibbs free energy is related to the change in enthalpy and entropy by the equation:

ΔGsys = ΔHsys - TΔSsys

Since the question only provides ΔSsurr (the change in entropy of the surroundings), we need additional information to directly calculate ΔHsys. However, we can make an assumption that ΔSsys = -ΔSsurr, as in many cases, the entropy change of the system and surroundings are equal in magnitude but opposite in sign.

Assuming ΔSsys = -ΔSsurr, we can rewrite the equation as:

ΔGsys = ΔHsys - T(-ΔSsurr)

We know that ΔGsys = 0 for a reaction at equilibrium, so we can set ΔGsys = 0 and solve for ΔHsys:

0 = ΔHsys + TΔSsurr

ΔHsys = -TΔSsurr

Now, we can substitute the values into the equation:

ΔHsys = -(28 + 273) K * (466 J mol^(-1) K^(-1))

ΔHsys ≈ -122,518 J mol^(-1)

Converting the result to kilojoules (kJ) and rounding to two significant figures, we get:

ΔHsys ≈ -122.52 kJ mol^(-1)

Thus, the appropriate answer is approximately -122.52 kJ mol^(-1).

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Subcooled water at 5°C is pressurised to 350 kPa with no increase in temperature, and then passed through a heat exchanger where it is heated until it reaches saturated liquid-vapour state at a quality of 0.63. If the water absorbs 499 kW of heat from the heat exchanger to reach this state, calculate how many kilogrammes of water flow through the pipe in an hour. Give your answer to one decimal place.

Answers

The water absorbs 499 kW of heat from the heat exchanger.

From the steam table, at 350 kPaL = hfg = 2095 kJ/kg

Thus, 499 × 103 = m × 2095m = (499 × 103) / 2095= 238.66 kg/hour

Given information

Subcooled water at 5°C is pressurised to 350 kPa with no increase in temperature.

It is heated until it reaches the saturated liquid-vapour state at a quality of 0.63.

The water absorbs 499 kW of heat from the heat exchanger.

Solution

From the steam table, at 5°C and 350 kPa, the water is in the subcooled region; hence, it is in the liquid state.

At 350 kPa, the saturated temperature of the steam is 134.6°C.

At quality of 0.63, the temperature of the steam can be calculated as follows:T1 = 5 °C and T2 = ?

Let, m = mass of water flowing through the pipe in an hour.

Q = Heat absorbed = 499 kW (Given)

From the first law of thermodynamics, Q = m x L

Where L is the latent heat of vaporization of water at 350 kPa.

L = hfg = 2095 kJ/kg

From the steam table, at 350 kPaL = hfg = 2095 kJ/kg

Thus,499 × 103 = m × 2095m = (499 × 103) / 2095= 238.66 kg/hour

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D Is the equilibrium constant for the following reaction? OK [KCIO₂]/[KCIO] [0₂] OK-[KCIO)2 [0₂]2/[KCIO₂1² OK-[0₂]¹¹ OK=[KCIO] [0₂]/[KCIO₂] OK= [0₂] Question 6 KCIO3 (s) KCIO (s) + O₂(g) 2.0 x1037 2.2 x 10 19 What is the Kc for the following 10 19 What is the Kc for the following reaction if the equilibrium concentrations are as follows: [N₂leq - 3.6 M. [O₂leq - 4.1 M. [N₂Oleq -3.3 x 10-18 M. 2010 37 O4,5 x 10¹8 4.9 x 1017 4 pts 2 N₂(g) + O₂(g) = 2 N₂O(g)

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The equilibrium constant (Kc) for the reaction 2 N₂(g) + O₂(g) ⇌ 2 N₂O(g) is approximately 2.11 x 10^(-37) based on the given equilibrium concentrations.

The equilibrium constant (Kc) for the reaction 2 N₂(g) + O₂(g) ⇌ 2 N₂O(g) can be determined based on the given equilibrium concentrations. The general form of the equilibrium constant expression is:

Kc = [N₂O]² / ([N₂]² * [O₂])

Substituting the given equilibrium concentrations:

Kc = ([N₂Oleq] / [N₂leq]² * [O₂leq])

Kc = (3.3 x 10^(-18) M) / (3.6 M)² * (4.1 M)

Calculating this expression:

Kc ≈ 2.11 x 10^(-37)

Therefore, the Kc for the given reaction is approximately 2.11 x 10^(-37).

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If the presumptive allowable bearing capacity is 2214 psf, the
column load is 12 kips, and the depth of footing is 1 ft, what is
the required footing width for a square footing in feet?

Answers

The required footing width for a square footing is approximately 6 feet, calculated by dividing the column load by the presumptive allowable bearable capacity and taking the square root of the resulting value.

To determine the required footing width, we need to calculate the maximum allowable pressure that the soil can support. The presumptive allowable bearing capacity is given as 2214 psf (pounds per square foot). We also have the column load, which is 12 kips (1 kip = 1000 pounds).

First, let's convert the column load from kips to pounds:

12 kips = 12,000 pounds

Next, we need to calculate the required footing area. Since the footing is square and the depth is given as 1 foot, the footing area is equal to the column load divided by the maximum allowable pressure:

Footing area = Column load / Presumptive allowable bearing capacity

Footing area = 12,000 pounds / 2214 psf

Now, we can calculate the required footing width by taking the square root of the footing area:

Footing width = √(Footing area)

By plugging in the values, we get:

Footing width = √(12,000 pounds / 2214 psf)

Calculating this value, the required footing width is approximately 6 feet.

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2-simplifica

1)x²-5x-16

x+2=

2)6an²-3b²n²

b4-4ab²+4a²=

3)4x²-4xy+y²

5y-10x

4)n+1-n³-n²

n³-n-2n²+2=

5)17x³y4z6

34x7y8z10=

6)12a²b³

60a³b5x6=

Answers

1.  x² - 5x - 16 can be written as (x - 8)(x + 2).

2. 6an² - 3b²n² = n²(6a - 3b²).

3. This expression represents a perfect square trinomial, which can be factored as (2x - y)².

4. Combining like terms, we get -n³ - n² + n + 1 = -(n³ + n² - n - 1).

5. 17x³y⁴z⁶ = (x²y²z³)².

6. 12a²b³ = (2a)(6b³) = 12a6b³ = 12a⁷b³x⁶.

Let's simplify the given expressions:

Simplifying x² - 5x - 16:

To factorize this quadratic expression, we look for two numbers whose product is equal to -16 and whose sum is equal to -5. The numbers are -8 and 2.

Therefore, x² - 5x - 16 can be written as (x - 8)(x + 2).

Simplifying 6an² - 3b²n²:

To simplify this expression, we can factor out the common term n² from both terms:

6an² - 3b²n² = n²(6a - 3b²).

Simplifying 4x² - 4xy + y²:

This expression represents a perfect square trinomial, which can be factored as (2x - y)².

Simplifying n + 1 - n³ - n²:

Rearranging the terms, we have -n³ - n² + n + 1.

Combining like terms, we get -n³ - n² + n + 1 = -(n³ + n² - n - 1).

Simplifying 17x³y⁴z⁶:

To simplify this expression, we can divide each exponent by 2 to simplify it as much as possible:

17x³y⁴z⁶ = (x²y²z³)².

Simplifying 12a²b³:

To simplify this expression, we can multiply the exponents of a and b with the given expression:

12a²b³ = (2a)(6b³) = 12a6b³ = 12a⁷b³x⁶.

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Consider the function, f(x) = x³ x² - 9x +9. Answer the following: (a) State the exact roots of f(x). (b) Construct three different fixed point functions g(x) such that f(x) = 0. (Make sure that one of the g(x)'s that you constructed converges to at least a root). (c) Find the convergence rate/ratio for g(x) constructed in previous part and also find which root it is converging to? (d) Find the approximate root, x, of the above function using fixed point iterations up to 4 significant figures within the error bound of 1 x 10-3 using xo = 0 and any fixed point function g(x) from part(b) that converges to the root (s)

Answers

The root of f(x) at which the function g3(x) converges is x=1.  
At x=1, g3'(x) = 0, which means that the convergence is quadratic.  The exact roots of[tex]f(x) are (x+1)(x²-x+1)(x³-x²-8x-9)=0[/tex]

The exact roots of [tex]f(x) are (x+1)(x²-x+1)(x³-x²-8x-9)=0.[/tex]

Three different fixed point functions g(x) such that f(x) = 0 are as follows:  
[tex]g1(x) = 9x - x³ - x² + 9[/tex]
[tex]g2(x) = (x³ + 9) / (x² + 9)[/tex]
[tex]g3(x) = x - (x³ - 9x + 9) / (3x² - 9)[/tex]


Let's examine the function g3(x).  
g3(x) = x - (x³ - 9x + 9) / (3x² - 9)

= (3x³ - 9x² - x³ + 9x - 9) / (3x² - 9)

= (2x³ - 9x + 9) / (3x² - 9)  
Let's differentiate the above expression.  
g3'(x) = [6x(3x² - 9) - (2x³ - 9x + 9)(6x)] / (3x² - 9)²  
g3'(x) = (54x² - 18 - 12x⁴ + 63x² - 18x³ - 54x² + 162) / (3x² - 9)²

= (-12x⁴ - 18x³ + 63x² + 18x + 144) / (3x² - 9)²  

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Show that if E is L-non-measurable, then ∃ a proper subset B of E such that 0<μ∗(B)<[infinity].

Answers

If E is L-non-measurable, then there exists a proper subset B of E such that 0 < μ∗(B) < ∞.

In measure theory, a set E is said to be L-non-measurable if it does not have a well-defined measure. This means that there is no consistent way to assign a non-negative real number to every subset of E that satisfies certain properties of a measure.

Now, if E is L-non-measurable, it implies that the measure μ∗(E) of E is either undefined or infinite. In either case, we can find a proper subset B of E such that the measure of B, denoted by μ∗(B), is strictly greater than 0 but less than infinity.

To see why this is true, consider the following: Since E is L-non-measurable, there is no well-defined measure on E. This means that there are subsets of E that cannot be assigned a measure, including some subsets that have positive "size" or "content." We can then choose one such subset B that has a positive "size" according to an informal notion of size or content.

By construction, B is a proper subset of E, meaning it is not equal to E itself. Moreover, since B has positive "size," we can conclude that 0 < μ∗(B). Additionally, because B is a proper subset of E, it cannot have the same "size" as E, which implies that μ∗(B) is strictly less than infinity.

In summary, if E is L-non-measurable, we can always find a proper subset B of E such that 0 < μ∗(B) < ∞.

In measure theory, the concept of measurability is fundamental in defining measures. Measurable sets are those for which a measure can be assigned in a consistent and well-defined manner. However, there exist sets that are not measurable, known as non-measurable sets.

The existence of non-measurable sets relies on the Axiom of Choice, a principle in set theory that allows for the selection of an element from an arbitrary collection of sets. It is through this axiom that we can construct non-measurable sets, which defy a well-defined measure.

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4. Prove that Q+, the group of positive rational numbers under multiplication, is isomor- phic to a proper subgroup of itself.

Answers

We have proven that Q+ is isomorphic to a proper subgroup of itself, which is H.

To prove that the group Q+ (the positive rational numbers under multiplication) is isomorphic to a proper subgroup of itself, we need to find a subgroup of Q+ that is isomorphic to Q+ but is not equal to Q+.

Let's consider the subgroup H of Q+ defined as follows:

[tex]H = {2^n | n is an integer}[/tex]

In other words, H is the set of all positive rational numbers that can be expressed as powers of 2.

Now, let's define a function f: Q+ -> H as follows:

[tex]f(x) = 2^(log2(x))\\[/tex]
where log2(x) represents the logarithm of x to the base 2.

We can verify that f is a well-defined function that maps elements from Q+ to H. It is also a homomorphism, meaning it preserves the group operation.

To prove that f is an isomorphism, we need to show that it is injective (one-to-one) and surjective (onto).

1. Injectivity: Suppose f(x) = f(y) for some x, y ∈ Q+. We need to show that x = y.

  Let's assume f(x) = f(y). Then, we have 2^(log2(x)) = 2^(log2(y)).
 
  Taking the logarithm to the base 2 on both sides, we get log2(x) = log2(y).
 
  Since logarithm functions are injective, we conclude that x = y. Therefore, f is injective.

2. Surjectivity: For any h ∈ H, we need to show that there exists x ∈ Q+ such that f(x) = h.

  Let h ∈ H. Since H consists of all positive rational numbers that can be expressed as powers of 2, there exists an integer n such that h = 2^n.
 
  We can choose [tex]x = 2^(n/log2(x)). Then, f(x) = 2^(log2(x)) = 2^(n/log2(x)) = h.[/tex]
  Therefore, f is surjective.

Since f is both injective and surjective, it is an isomorphism between Q+ and H. Furthermore, H is a proper subgroup of Q+ since it does not contain all positive rational numbers (only powers of 2).

Hence, we have proven that Q+ is isomorphic to a proper subgroup of itself, which is H.

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A packed countercurrent water-cooling tower is to cool water from 55 °C to 35 °C using entering air at 35 °C with wet bulb temperature of 27 °C. The water flow is 160 kg water/s. The diameter of the packed tower is 12 m. The heat capacity CL is 4.187 x 103 J/kg•K. The gas- phase volumetric mass-transfer coefficient koa is estimated as 1.207 x 107 kg mol/som.Pa and liquid-phase volumetric heat transfer coefficient ha is 1.485 x 104 W/m3.K. The tower operates at atmospheric pressure. The enthalpies of saturated air and water vapor mixtures for equilibrium line is exhibited in the Table E1. (a) Calculate the minimum air flow rate. (10 points) (b) Calculate the tower height needed if the air flow is 1.5 times minimum air flow rate using graphical or numerical integration.

Answers

a) The minimum air flow rate can be calculated by determining the heat transfer required to cool the water from 55 °C to 35 °C and dividing it by the difference in enthalpy between the incoming and outgoing air streams.

b) To calculate the tower height needed for an air flow rate of 1.5 times the minimum, integration can be used to determine the mass transfer and heat transfer as a function of height in the tower. By integrating these values, the tower height required can be obtained.

Explanation:

a) The minimum air flow rate can be calculated by first determining the heat transfer required to cool the water. This is done by multiplying the water flow rate (160 kg/s) by the specific heat capacity of water (4.187 x 10^3 J/kg•K) and the temperature difference (55 °C - 35 °C). The resulting heat transfer rate is then divided by the difference in enthalpy between the incoming and outgoing air streams, which can be obtained from the enthalpy table.

b) To calculate the tower height needed for an air flow rate of 1.5 times the minimum, the mass transfer and heat transfer as a function of height in the tower need to be determined. This can be done using graphical or numerical integration techniques. By integrating these values and considering the increased air flow rate, the tower height required can be obtained.

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Solve for Y(s), the Laplace transform of the solution y(t) to the initial value problem below. y" + 2y = 3t4, y(0) = 0, y'(0) = 0

Answers

The Laplace transform of the solution y(t) to the given initial value problem is Y(s) = (6s³ + 24s²+ 24s + 8) / (s³ + 2s²).

To solve the given initial value problem, we'll use the Laplace transform method. Taking the Laplace transform of the differential equation y" + 2y = 3t⁴, we get s²Y(s) - sy(0) - y'(0) + 2Y(s) = 3(4!) / s⁵. Since y(0) = 0 and y'(0) = 0, the equation simplifies to s² Y(s) + 2Y(s) = 72 / s⁵.

Next, we need to find the inverse Laplace transform of Y(s) to obtain the solution y(t). We can rewrite the equation as (s²  + 2)Y(s) = 72 /  s⁵. Dividing both sides by (s² + 2), we get Y(s) = 72 / [ s⁵.(s²+ 2)]. To find the inverse Laplace transform, we need to decompose the right side into partial fractions.

The partial fraction decomposition of Y(s) is given by A/s + B/s² + C/s³ + D/s⁴ + E/ s⁵. + Fs + G/(s² + 2). By equating the numerators, we can solve for the coefficients A, B, C, D, E, F, and G. Once we have the coefficients, we can apply the inverse Laplace transform to each term and combine them to obtain the solution y(t).

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Water can be formed according to the equation: 2H2(g) + O2(g) → 2H₂O(g) If 6.0 L of hydrogen is reacted at STP, exactly how many liters of oxygen at STP would be needed to allow complete reaction? (R= 0.0821 Latm/mol K) a)801 b)30L c)4.0 L d)12.0L e)10.0L

Answers

Approximately 3.57 liters of oxygen at STP would be needed to allow complete reaction.

To find out how many liters of oxygen at STP (Standard Temperature and Pressure) would be needed to allow complete reaction, we need to use the balanced equation for the reaction:

2H2(g) + O2(g) → 2H₂O(g) The stoichiometric ratio between hydrogen and oxygen in this reaction is 2:1. This means that for every 2 moles of hydrogen, we need 1 mole of oxygen.

Given that we have 6.0 L of hydrogen at STP, we need to convert this volume into moles.

To do this, we can use the ideal gas law: PV = nRT

where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature.

At STP, the pressure is 1 atm and the temperature is 273 K. The ideal gas constant, R, is 0.0821 L·atm/(mol·K).

So, using the ideal gas law, we can calculate the number of moles of hydrogen:

n = PV / RT = (1 atm) * (6.0 L) / (0.0821 L·atm/(mol·K) * 273 K) ≈ 0.272 mol

Since the stoichiometric ratio between hydrogen and oxygen is 2:1, we know that the number of moles of oxygen needed is half the number of moles of hydrogen:

moles of oxygen = 0.272 mol / 2 = 0.136 mol

Now, we can convert the number of moles of oxygen into liters at STP using the ideal gas law again:

V = nRT / P = (0.136 mol) * (0.0821 L·atm/(mol·K) * 273 K) / (1 atm) ≈ 3.57 L

Therefore, approximately 3.57 liters of oxygen at STP would be needed to allow complete reaction.

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Which values represent the independent variable? (–2, 4), (3, –2), (1, 0), (5, 5) A. {–2, 3, 1, 5} B. {4, –2, 0, 5} C. {–2, 4, 3, –2} D. {–2, –1, 0, 5} Please select the best answer from the choices provided A B C D

Answers

Answer:

The independent variable is the variable that is manipulated or changed during an experiment. In this case, the independent variable is represented by the x-values of the given points.

So, the answer would be option A: {-2, 3, 1, 5}

Step-by-step explanation:

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how many solutions are there to square root x =9

Answers

Answer:

There are 2 solutions to square root x = 9

They are 3, and -3

Step-by-step explanation:

The square root of x=9 has 2 solutions,

The square root means, for a given number, (in our case 9) what number times itself equals the given number,

Or, squaring (i.e multiplying with itself) what number would give the given number,

so, we have to find the solutions to [tex]\sqrt{9}[/tex]

since we know that,

[tex](3)(3) = 9\\and,\\(-3)(-3) = 9[/tex]

hence if we square either 3 or -3, we get 9

Hence the solutions are 3, and -3

Use the Alternating Series Test to determine whether the series (-1) 2 absolutely, converges conditionally, or diverges. n² +4 *=) 2. Use the Alternating Series Test to determine whether the series (-1¹- absolutely, converges conditionally, or diverges. 2-1 4 in-1 converges converges

Answers

Both conditions of the Alternating Series Test are satisfied, we can conclude that the series (-1)^(n+1) / (n^2 + 4) converges.

1. The terms alternate in sign: The series (-1)^(n+1) alternates between positive and negative values for each term, as (-1)^(n+1) is equal to 1 when n is even and -1 when n is odd.

2. The absolute values of the terms decrease: Let's consider the absolute value of the terms:

|(-1)^(n+1) / (n^2 + 4)| = 1 / (n^2 + 4)

We can see that as n increases, the denominator n^2 + 4 increases, and therefore the absolute value of the terms decreases.

Since both conditions of the Alternating Series Test are satisfied, we can conclude that the series (-1)^(n+1) / (n^2 + 4) converges.

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A piston-cylinder contains a 4.18 kg of ideal gas with a specific heat at constant volume of 1.4518 ki/kg.K at 52.5 C. The gas is heated to 149.5 C at which the gas expands and produces a boundary work of 93.6 kl. What is the change in the internal energy (u)? OB. 495.05 OC. 140.82 OD. 682.25 E. 588.65

Answers

Performing the calculations will give you the change in internal energy (Δu) in kJ.

To calculate the change in internal energy (Δu) for an ideal gas, we can use the following equation:

Δu = q - W

where q is the heat transferred to the gas and W is the work done by the gas.

Given:

Mass of ideal gas (m) = 4.18 kg

Specific heat at constant volume (Cv) = 1.4518 kJ/kg.K

Initial temperature (T₁) = 52.5 °C = 52.5 + 273.15 K

Final temperature (T₂) = 149.5 °C = 149.5 + 273.15 K

Boundary work (W) = 93.6 kJ

First, we need to calculate the heat transferred (q) using the equation:

q = m * Cv * (T₂ - T₁)

Substituting the values:

q = 4.18 kg * 1.4518 kJ/kg.K * (149.5 + 273.15 K - 52.5 - 273.15 K)

Next, we can calculate the change in internal energy:

Δu = q - W

Substituting the values:

Δu = (4.18 kg * 1.4518 kJ/kg.K * (149.5 + 273.15 K - 52.5 - 273.15 K)) - 93.6 kJ

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