Calculate the pH at the equivalence point for titrating 0.200 M solution of benzoic acid with 0.060 M NaOH. Ka for benzoic acid is 6.3 x10^-5

Answers

Answer 1

Answer:

[tex]pH=8.43[/tex]

Explanation:

Hello there!

In this case, since the reaction between benzoic acid and sodium hydroxide is carried out in a 1:1 mole ratio, it is possible to calculate the moles of sodium benzoate salt that are produced due to the neutralization as show below:

[tex]n_{salt}=0.2mol/L*1L=0.2mol[/tex]

We can assume that the volume of benzoic acid is 1 L and therefore the used volume of NaOH is:

[tex]V_{NaOH}=\frac{0.200M*1L}{0.060M}=3.33L[/tex]

Which means that the total final volume is 4.33 L and the concentration of the resulting basic salt is:

[tex][salt]=\frac{0.2mol}{4.33L}=0.046M[/tex]

Next, since the salt is C6H5COONa, we can see it is ionized in Na+ cations and C6H5COO- anions, but just the latter is able to react with the water in the solution in order to undergo the following reaction:

[tex]C_6H_5COO^-+H_2O\rightleftharpoons C_6H_5COOH+OH^-[/tex]

Whose equilibrium expression, it terms of Kb, due to the release of OH- ions, is:

[tex]Kb=\frac{[C6H5COOH][OH^-]}{[C6H5COO^-]}[/tex]

And can be written in terms of x, Kw and Ka:

[tex]\frac{Kw}{Ka} =\frac{x*x}{0.046M-x} \\\\\frac{1x10^{-14}}{6.3x10^{-5}}=1.59x10^{-10}= \frac{x^2}{0.046M-x}[/tex]

And because Kb<<<<<1 we can neglect the x on the bottom to get:

[tex]1.59x10^{-10}= \frac{x^2}{0.046M}[/tex]

Whereas x is computed as follows:

[tex]x=\sqrt{1.59x10^{-10}*{0.046M} =2.7x10^{-6}M[/tex]

Which is actually equal to the concentration of OH- ions so that we can calculate the pOH prior to the pH:

[tex]pOH=-log(2.7x10^{-6})=5.57[/tex]

And therefore the pH as shown below:

[tex]pH=14-5.57\\\\pH=8.43[/tex]

Which makes sense since this sodium benzoate is a basic salt.

Regards!


Related Questions

URGENT ! PLEASE ANSWER QUICKLY

Calculate the volume of a NaCl solution that would contain 5.0 g of NaCl and have a molarity of 4.8 M.

Calculate the pH for a solution with a 4.6 x 10-9 M hydronium concentration.

Answers

Answer:If we dissolve NaF in water, we get the following equilibrium:

text{F}^-(aq)+text{H}_2text{O}(l) rightleftarrows text{HF}(aq)+text{OH}^-(aq)

The pH of the resulting solution can be determined if the  K_b of the fluoride ion is known.

20.0 g of sodium fluoride is dissolve in enough water to make 500.0 mL of solution. Calculate the pH of the solution. The  K_b of the fluoride ion is 1.4 × 10 −11 .

Step 1: List the known values and plan the problem.

Known

mass NaF = 20.0 g

molar mass NaF = 41.99 g/mol

volume solution = 0.500 L

K_b of F – = 1.4 × 10 −11

Unknown

pH of solution = ?

The molarity of the F − solution can be calculated from the mass, molar mass, and solution volume. Since NaF completely dissociates, the molarity of the NaF is equal to the molarity of the F − ion. An ICE Table (below) can be used to calculate the concentration of OH − produced and then the pH of the solution.

Explanation:

Answer:

not sure if this is 100% correct but this is what i got first question: molarity=mol/L 5g*1mol/58.44g=5/58.44 =0.085558mol 4.8m=0.085558/L L=0.0178

jiujuan avatar

second question: pH = - log [H3O+] pH= -log [4.6*10^-9] = 8.33724216

Explanation:

i need help with this pls

Answers

I know it’s E and A

Explanation: did you count it’s exactly 28, also the electrons are not visible.

Ps: I’m in 5th grade, what grade is this, if my suggestion was correct then holy crackers.

The division of Earth’s history into smaller units makes up the ____.

Answers

Answer:

geologic time scale

hope this helps

have a good day :)

Explanation:

How many calories of heat were added to 167.9 g of water to raise its temperature from 25oC to 55oC?

Answers

Answer:

Q = 5036.9 calories

Explanation:

Given that,

Mass, m = 167.9 g

The temperature raises from 25°C to 55°C.

The specific heat of water,c = 4.184 J/g °C

We need to find the heat added to water. We know that,

[tex]Q=mc\Delta T\\\\=167.9 \times 4.184\times (55-25)\\\\=21074.8\ J[/tex]

or

Q = 5036.9 calories

So, 5036.9 calories of heat is added.

What is the mole ratio of magnesium carbonate to magnesium oxide? MgCO3 →MgO+CO2
a)3:2 b) 1:3 c) 1:1 d) 1:2 e) 2:3

Answers

I think the answer is D

Answer:

d)1:2

Explanation:

Compare How does the horse's average speed from 60 s to 120 s compare to its average speed from 120 s to 180 s?

Answers

Answer:

Explanation:

To compare the average speed, we would need some parameters which you clearly didn't state in your question. However, permit me to manufacture some from thin air.

The formula for average speed is given as

Speed = distance / time

From the question, we have the time, but not the distance moved by the horse. Now, assuming the horse moves a distance of 60 meters, then we can say,

Speed = 60 / 60

Where the difference between the two time, t = 120 - 60 = 180 - 120 = 60

So, from my hypothesized example, the average speed of the horse is 1 m/s

The atomic model that describes an atom as a spherical object containing a certain number of electrons trapped in a mass of positive charge is often called the ___________ model.
help

Answers

Stop sending links like honestly
The raisin bread model founded by JJ Thompson

a gas measured a volume 100 mL under pressure of 740 mmHg. What would the volume be under a pressure of 780 mmHg with constant temperature

Answers

Answer:

94.87 mL

Explanation:

The new volume can be found by using the formula for Boyle's law which is

[tex]P_1V_1 = P_2V_2[/tex]

Since we're finding the new volume

[tex]V_2 = \frac{P_1V_1}{P_2} \\[/tex]

We have

[tex]V_2 = \frac{100 \times 740}{780} = \frac{74000}{780} \\ = 94.8717...[/tex]

We have the final answer as

94.87 mL

Hope this helps you

Which of these is not a characteristic of sponges?

lack a backbone

lack a brain

stationary

have a nervous system

Answers

have a nervous system is the answer!










Have a nervous system


(b) Potassium and sodium are kept in dark reagent bottles filled with paraffin oil.
Explain why.​

Answers

Answer:

these metals are stored in kerosene because kerosene contains no water and protects these metals from being exposed to any moisture in the air that would cause these metals to react, potentially violently.

in which type of condition is a conditions is a landslide most likely to occur

Answers

Answer:

B. In a wet, hilly area

Explanation:

We know that for a landslide to happen, there has to be a down hill slope so it can fall.

This eliminates answers C, D and E.

So we are left with A and B

Now we can look at this in a real life scenario. If you have ever walking on wet ground, you will know that is weaker than dry ground. Knowing this, we know the answer will have to be answer B.

What of reaction is Zn + H2S =ZnS + H2

Answers

It’s a single replacement because it has an element + a compound on the left side that form a new compound + a new element

What is the total volume of water that you have if you calculated that it
weighs 180g?

Answers

180g weights 0.4 pounds Divides it and you get 450 pounds

How does a nuclear power plant create electricity?*

A: A nuclear reaction burns fuel

B: A nuclear reaction caused water to flow, which is then what creates electricity

C: A nuclear reaction creates heat which is applied to water to create steam

D: A nuclear reaction creates an electrical current

Answers

Answer:

C

Explanation:

Answer:

hi jajsbbsjsmsksjsksksjsjdkkdkdndndnxjsjsksksksjsksmsnznnsnsnznsjsjshsjjajannananabababababajajajajajabananabbananajanabajajakmaka

The following graph shows a decay chain. Which part of the decay will take the most time? the decay of U-238 to Th-234, the decay of Th-234 to Ra-226, the decay of Ra-226 to Po-214, the decay of Po-214 to Pb-206

Answers

A- the decay of U-238 to Th-234

right on edge 2021

Answer:

A) the decay of U-238 to Th-234

:)

Explanation:

pls help help help!
i give 20 points
pls​

Answers

Answer:

His name is Harold

Explanation:

* Describe the structure and behavior of the inner Earth

Answers

Answer:

The interior of the Earth, like that of the other terrestrial planets, is chemically divided into layers. The Earth has an outer silicate solid crust, a highly viscous mantle, a liquid outer core that is much less viscous than the mantle, and a solid inner core.

There are 1 1/2 times the amount of
we need on the planet today

Answers

Is there answer choices?

what can you infer about aspirin’s ester group?



A. It provides aspirin’s pain-killing ability.



B. It makes the compound more digestible.



C. It reduces fevers.




It's B

Answers

Answer:

Option B, aspirin’s ester group provides greater digestibility to aspirin

Explanation:

Aspirin ester group has three parts

carboxylic acid functional group (R-COOH) ester functional group (R-O-CO-R') aromatic group (benzene ring)

Aspirin is a weak acid and hence it cannot dissolve in water readily. The reaction of Aspirin ester group with water is as follows -

aspirin

(acetylsalicylic acid) + water → salicylic acid + acetic acid

(ethanoic acid)

Aspirin passes through the stomach and remains unchanged until it reaches the intestine where it hydrolyses ester to form the active compound.

why is hydrogen a nonmetal,usually placed with group 1 elements in the periodic table even though it does not show a metallic property like the alkalietals?​

Answers

Hydrogen is a nonmetal and is placed above group in the periodic table because it has ns1 electron configuration like the alkali metals. However, it varies greatly from the alkali metals as it forms cations (H+) more reluctantly than the other alkali metals.Aug 15, 2020
Electronic Configuration: 1s
At Room Temperature: Colorless & Odorless Diatomic Gas
Atomic Weight: 1.0079

Periodic table has been divided into three, one is metal, second is non metal and third metalloid. Therefore,  hydrogen is considered as non metal.

What is metal?

Metals are those elements which is hard, conduct electricity, ductile, lustrous and malleable.

Lets take property

1.Since metals have free electrons that's why they can conduct electricity

2. Since atoms in metals are very closely packed in a definite crystal so Aluminium is solid. It is not brittle that is it can not be broken down easily

3. It does not react with water.

4.It is denser than water hence it sink in water.

Since hydrogen has only 1 electron in its outermost shell, to complete its duet and gain stability, hydrogen has to gain 1 electron just like halogen. So, on this basis hydrogen is considered as non metal.

Therefore,  hydrogen is considered as non metal.

Learn more about the metals, here:

https://brainly.com/question/27859211

#SPJ2

*At 25 °C, gas in a rigid cylinder with a movable piston has a volume of 145 mL and a pressure of 125 atm. Then, the gas is compressed to a volume of 80mL What is the new pressure of the gas if the temperature is at 30°C?

Answers

Answer:

Pressure will increase by the direct ratio of the volume change. Therefore, since volume changes from 145 to 80, pressure will go up by the ratio change 145÷80 times the original pressure 125 kPa. Sure, you can use the more complicated gas law equation PV = nRT but we are only varying volume so the question boils down to the change in one simple variable.

Putting them together we have: 145÷80 x 125 = 226.5625 or just 226 kPa since the accuracy of the figures and the equation are not great.

what are protons, what is their charge, and where they located?

Answers

Protons are subatomic particles, their electric charge is positive, and they are located in the nucleus of the atom.

In describing weather completely, it is important to include, among other aspects, air pressure, precipitation, and humidity. Which of the following statements is false?


Wind is the movement of air that results from differences in air pressure.

Precipitation is a form of water that falls to Earth’s surface from the clouds.

Air typically moves from areas of lower pressure to areas of higher pressure.

When the temperature of the air cools to the dew point, the air is saturated, and water droplets will form.

Answers

Answer:

The false statement is - Air typically moves from areas of lower pressure to areas of higher pressure.

Explanation:

The wind is the air movement that takes place due to pressure differences or the temperature difference of air. Air moves from the higher pressure area to the lower pressure area. The more the difference will be the faster the air will move to a low-pressure area.

Precipitation is a form of water that falls from clouds to earth, it can be rainfall, snow and other forms. Dew is one of the forms that occur when the air cools down to the dew point and form droplets.

Answer:

Air typically moves from areas of lower pressure to areas of higher pressure.

Explanation:

What is the measure of the indicated angle? 37∘ 53∘ 180∘ 127∘

Answers

Answer:

53∘

plz mark me as brainliest.

Using the ideal gas law, what will be the volume occupied by 1.46 moles of helium at
0.982 atmospheres and 13.0°C? (R = 0.0821 L'atm/mol-K)

Answers

Answer:

34.91 L

Explanation:

Ideal gas law -> PV=nRT

convert C to K -> 13+273 = 286

plug numbers in

(.982)V=(1.46)(.0821)(286)

V = 34.91 L

Review the chart of all the domesticated rabbits. The different types of rabbits are listed by their scientific names. If you were a
rabbit breeder, which rabbits could you breed to produce fertile offspring? Explain.
A)
All of the rabbits listed. They are all rabbits.
B)
None of these rabbits. They are all different species.
C)
Any of the cottontail rabbits They are the same species.
D)
Any of the rabbits on the same branch in the chart because that means
they are closely related.

Answers

Answer: None of these rabbits listed. they are all different species

Explanation:

I got it right on usatestprep

When more gas particles are added to the same space, how will the behavior change?

Answers

Answer:

The particles move very fast and collide into one another, causing them to diffuse, or spread out, until they are evenly distributed throughout the volume of the container. When more gas particles enter a container, there is less space for the particles to spread out, and they become compressed.

Explanation:

PLEASE HELP DUE IN 20 MINUTES Find the empirical formula for the following problem. Remember to show your work if you want
to earn credit.
1. One mole of an unknown compound has 36.0 g of carbon and 6.0 g of hydrogen. What
is the empirical formula of the unknown compound? (Hint: You will want to reduce to find
the empirical formula)
Given: Carbon: 36.0 grams
1 mol C = 12.0 g
Hydrogen: 6.0 g
1 mol H = 1.0 g
Unknown: empirical formula
Solve:

Answers

Answer:

CH2

Explanation:

The empirical formula is the simplest formula of a chemical compound. It shows the ratio in which constituent atoms are combined in the compound.

To obtain the empirical formula, we divide the given mass of each element by the relative atomic mass of that element.

C- 36.0 g/12.0 g         H- 6.0g/1.0g

C- 3                             H-6

Divide through by the lowest ratio;

C-3/3                              H- 6/3

C-1                                  H-2

Hence the empirical formula of the compound is

CH2

find the ratio of the initial volume to final volume if the temperature of the gas is changed from 27°C to 127°C at constant pressure.​

Answers

Answer: The ratio of the initial volume to final volume for the given gas is 27 to 127 L at constant pressure.

Explanation:

Given: [tex]T_{1} = 27^{o}C[/tex]

[tex]T_{2} = 127^{o}C[/tex]

According to Charle's law, for an ideal gas pressure is directly proportional to the temperature at constant pressure.

So, formula used to calculate the ratio of the initial volume to final volume is as follows.

[tex]\frac{V_{1}}{T_{1}} = \frac{V_{2}}{T_{2}}[/tex]

Substitute the values into above formula as follows.

[tex]\frac{V_{1}}{T_{1}} = \frac{V_{2}}{T_{2}}\\\frac{V_{1}}{V_{2}} = \frac{T_{1}}{T_{2}}\\\frac{V_{1}}{V_{2}} = \frac{27}{127}[/tex]

Hence, we can conclude that the ratio of the initial volume to final volume for the given gas is 27 to 127 L at constant pressure.

Is oil a reasonable energy source? Why or why not? ​

Answers

Answer:

No, it is not.

Explanation:

Oil is a non-renewable source of energy. ... Burning oil can pollute the air. Much of our oil has to be imported and it is becoming more and more expensive as reserves reduce and imports increase. Producing electricity from crude oil is expensive compared to other fossil fuels such as coal or gas.

*You Can put this in your own words

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