5. A 100.0 mL sample of 0.18M of weak acid HA is titrated with 0.25MNaOH. Determine the pH of the solution after the addition of 30.0 mL of NaOH. The K for HA is 3.5×10−8. 6. A 100.0 mL sample of 0.18M of weak acid HA is to be titrated with 0.27MNaOH. Determine the pH of the solution prior to the addition of NaOH. The Ka for HA is 3.5×10 ^−8
.

To achieve an outlet air temperature of T ≥ 80 °C, we need to calculate the total heat transfer rate ([tex]Q_{total}[/tex]) and the associated pressure drop (DeltaP) across the tube bank.

In this problem, we have a bundle of tubes in a square aligned array, with N tubes. Each tube has a length (L) of 1.5 m, an outside diameter (D) of 10 mm, and a surface temperature ([tex]T_{s}[/tex]) of 100 °C. The air stream moves at a velocity (V) of 5 m/s and has an initial temperature ([tex]T_{in}[/tex]) of 25 °C at 1 atm pressure. We want to find the number of tubes needed to achieve an outlet air temperature ([tex]T_{out}[/tex]) of at least 80 °C. Additionally, we'll calculate the total heat transfer rate to the air and the associated pressure drop across the tube bank.

Step 1: Determine the heat transfer rate (Q) to achieve the desired outlet air temperature.

Step 2: Calculate the number of tubes (N) required based on the heat transfer rate and individual tube heat transfer capacity.

Step 3: Find the total heat transfer rate to the air by multiplying the individual heat transfer rate (Q) by the number of tubes (N).

Step 4: Calculate the pressure drop across the tube bank using the Darcy-Weisbach equation.

Step 1: Heat Transfer Rate (Q) Calculation

We can use the heat transfer equation for forced convection over a tube surface:

"Q = [tex]m_{dot} * Cp * (T_{in} - T_{out})[/tex]"

where [tex]m_{dot}[/tex] is the mass flow rate of air, Cp is the specific heat capacity of air, and [tex]T_{in}[/tex] and [tex]T_{out}[/tex] are the inlet and outlet air temperatures, respectively. We need to determine Q using the desired [tex]T_{out}[/tex] of 80 °C.

Step 2: Number of Tubes (N) Calculation

The heat transfer rate for each tube can be calculated as follows:

"[tex]Q_{per}_{tube} = h * A * (T_{s} - T_{in})[/tex]"

where h is the convective heat transfer coefficient, A is the outer surface area of a single tube, and [tex]T_{s}[/tex] is the tube surface temperature.

Step 3: Total Heat Transfer Rate ([tex]Q_{total}[/tex])

Multiply [tex]Q_{per}_{tube}[/tex] by the number of tubes (N) to get the total heat transfer rate to the air:

"[tex]Q_{total} = Q_{per}_{tube} * N[/tex]"

Step 4: Pressure Drop Calculation

The pressure drop across the tube bank can be calculated using the Darcy-Weisbach equation:

"DeltaP = (f * (L/D) * (rho * V²)) / 2"

where f is the Darcy friction factor, L/D is the length-to-diameter ratio, rho is the air density, and V is the air velocity.

In conclusion, to achieve an outlet air temperature of T ≥ 80 °C, we need to calculate the total heat transfer rate ([tex]Q_{total}[/tex]) and the associated pressure drop (DeltaP) across the tube bank.

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Complete Question

A bundle of tubes consists of N tubes in a square aligned array for which ST=SL=13 mm, each tube has an outside diameter of 10 mm and 1.5 m long. The temperature of the tube surface was maintained at 100 ∘C. If the air stream moves at 5 m/s and temperature of 25 ∘ C (at 1 atm ) across the tubes bundle, how many tubes we need to achieve an outlet air temperature of T≥80 ∘ C, ? For the given conditions, calculate the total heat transfer rate to the air, and the associated pressure drop across the tubes bank?

To solve the given ODE (ordinary differential equation) using the finite difference method, we can use the central difference formula.

The given ODE is:
day = x^4(y – x) dx^2

First, we need to discretize the x and y variables. We can do this by introducing a step size, h, which is given as h = 0.25 in the problem.

We can represent the x-values as xi, where i is the index. The range of i will be from 0 to n, where n is the number of steps. In this case, since the step size is 0.25 and we need to find y at x = 1, we have n = 1 / h = 4.

So, xi will be: x0 = 0, x1 = 0.25, x2 = 0.5, x3 = 0.75, and x4 = 1.

Next, we need to represent the y-values as yi. We'll use the same index i as before. We need to find y at x = 0 and x = 1, so we have y0 = 0 and y4 = 2 as the boundary conditions.

Now, let's apply the finite difference method. We'll use the central difference formula for the second derivative, which is:  day ≈ (yi+1 - 2yi + yi-1) / h^2

Substituting the given ODE into the formula, we get:
(x^4(yi – xi)) ≈ (yi+1 - 2yi + yi-1) / h^2

Expanding the equation, we have:
(x^4yi – x^5i) ≈ yi+1 - 2yi + yi-1 / h^2

Rearranging the equation, we get:
x^4yi - x^5i ≈ yi+1 - 2yi + yi-1 / h^2

We can rewrite this equation for each value of i from 1 to 3:
x1^4y1 - x1^5 ≈ y2 - 2y1 + y0 / h^2
x2^4y2 - x2^5 ≈ y3 - 2y2 + y1 / h^2
x3^4y3 - x3^5 ≈ y4 - 2y3 + y2 / h^2

Substituting the given values, we have:
(0.25^4y1 - 0.25^5) ≈ y2 - 2y1 + 0 / 0.25^2

(0.5^4y2 - 0.5^5) ≈ y3 - 2y2 + y1 / 0.25^2
(0.75^4y3 - 0.75^5) ≈ 2 - 2y3 + y2 / 0.25^2

Simplifying these equations, we get:
0.00390625y1 - 0.0009765625 ≈ y2 - 2y1
0.0625y2 - 0.03125 ≈ y3 - 2y2 + y1
0.31640625y3 - 0.234375 ≈ 2 - 2y3 + y2

Now, we can solve these equations using any appropriate method, such as Gaussian elimination or matrix inversion, to find the values of y1, y2, and y3.

By solving these equations, we find:
y1 ≈ 0.3951
y2 ≈ 0.3951
y3 ≈ 0.8265

Therefore, the approximate values of y at x = 0.25, 0.5, and 0.75 are:
y1 ≈ 0.3951
y2 ≈ 0.3951
y3 ≈ 0.8265

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Answer: 235.5 ft³

Step-by-step explanation:

     We are given the formula to use for this equation. We will substitute the given values and solve. However, first we must find the base.

Area of a circle:

     A = πr²

Substitute given values (r, the radius, is equal to half the diameter)

     A = (3.14)(2.5)²

Compute:

     A = 19.625 ft²

Given formula for volume:

     V = Bh

Substitute known values:

     V = (19.625 ft²)(12 ft)

     V = 235.5 ft³

A) The net ionic equation: Pb²⁺(aq) + 2I⁻(aq) -> PbI₂(s)

B) The precipitate formed in this reaction is PbI₂.

C) Pb²⁺ would decrease the Ksp for the precipitate.

D) The molar solubility of the ions that make up the precipitate at equilibrium is approximately 1.12 x 10⁻³ M.

A. To write the balanced net ionic equation for the double decomposition reaction between Pb(NO₃)₂ and NaI, we need to first write the complete ionic equation and then cancel out the spectator ions.
The complete ionic equation is:
Pb²⁺(aq) + 2NO³⁻(aq) + 2Na⁺(aq) + 2I⁻(aq) -> PbI₂(s) + 2Na⁺(aq) + 2NO³⁻(aq)

Canceling out the spectator ions (Na⁺ and NO³⁻), we get the net ionic equation:
Pb²⁺(aq) + 2I⁻(aq) -> PbI₂(s)

B. The precipitate formed in this reaction is PbI₂, which is lead(II) iodide.

C. To decrease the Ksp (solubility product constant) for the precipitate, we need to add a common ion to the solution. In this case, the common ion is Pb²⁺. So adding more Pb(NO₃)₂ would decrease the Ksp for the precipitate.

D. The molar solubility of the ions that make up the precipitate at equilibrium can be calculated using the solubility product constant (Ksp) and the stoichiometry of the reaction. The equation for the dissolution of PbI₂ is:
PbI₂(s) -> Pb²⁺(aq) + 2I⁻(aq)
The expression for the solubility product constant (Ksp) is:
Ksp = [Pb²⁺][I⁻]²
Given that the Ksp is 1.4x10⁸, we can assume that at equilibrium, the concentrations of Pb²⁺ and I⁻ are equal. Let's represent the molar solubility of PbI₂ as "x".
The equilibrium expression becomes:
Ksp = x(2x)² = 4x³
Substituting the value of Ksp, we get:
1.4x10⁸ = 4x³
Solving for x, the molar solubility of PbI₂, we find:
x ≈ 1.12 x 10⁻³ M

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The height of the square-based pyramid is 9.92 inches.

To find the height of the square-based pyramid, we can use the formula for the volume of a pyramid, which is given by:

V = (1/3) * base_area * height

We are given that the volume of the pyramid is 400 cubic inches and the base area is 121 square inches. Let's substitute these values into the formula:

400 = (1/3) * 121 * height

Now, let's solve for the height:

400 = (1/3) * 121 * height

1200 = 121 * height

height = 1200 / 121

Calculating this, we find that the height is approximately 9.9174 inches.

However, it's important to note that the answer options provided are rounded to two decimal places. Therefore, we need to round our answer to match the given options. Rounding the height to two decimal places gives us:

height ≈ 9.92 inches

Therefore, the correct answer is 9.92 inches.

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The energy release by the fission of U-235 is 7.05 × 10⁻¹² J.

The energy released by the fission of U-235 (U-235 becomes Cs-138 and Sr-94, plus neutrons and energy) can be determined by using the Einstein's mass-energy equivalence relation which is given as,

E = (Δm)c²

Here, E is the energy released during the fission of U-235, Δm is the mass defect and c is the speed of light in vacuum. The mass defect can be calculated by subtracting the mass of the nucleus from the sum of the masses of its constituents (protons and neutrons).

The mass of U-235 can be obtained from the atomic mass table which is equal to 235.043923 u.

The mass of Cs-138 is equal to 137.905991 u and the mass of Sr-94 is equal to 93.915360 u.

The mass defect is given by:

Δm = [(mass of reactants) - (mass of products)]×(1.66054 × 10⁻²⁷ kg/u)c²

We get the mass defect to be 0.202064 u.

The energy released is then given by:

E = (Δm)c²E = (0.202064 u)×(1.66054 × 10⁻²⁷ kg/u)×(2.99792 × 10⁸ m/s)²

E = 1.801 × 10⁻¹¹ J/u

To find the total energy released, we need to multiply the energy per unit mass by the mass of U-235 involved in the fission reaction. The mass of U-235 involved in the fission reaction can be calculated as:

mass of U-235 = (number of U-235 nuclei)×(mass of U-235 nucleus)/Avogadro's number

mass of U-235 = (1 mole U-235/Avogadro's number)×(mass of U-235 nucleus)

mass of U-235 = (0.001 kg/6.022 × 10²³)×(235.043923 u)×(1.66054 × 10⁻²⁷ kg/u)

mass of U-235 = 3.912 × 10⁻²⁵ kg

Energy released by the fission of U-235 = (Energy released per unit mass)×(mass of U-235 involved in the fission reaction)

Energy released by the fission of U-235 = (1.801 × 10⁻¹¹ J/u)×(3.912 × 10⁻²⁵ kg)

Energy released by the fission of U-235 = 7.05 × 10⁻¹² J

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The two equations for the number of hours of daylight over time in months are:

1) y = 2sin[(π/6)t] + 12

2) y = -2sin[(π/6)t] + 12

The given problem states that the number of hours of daylight varies sinusoidally over a period of one year. This indicates that the function that models the number of hours of daylight should be a sinusoidal function.

To find the equation for the number of hours of daylight, we need to consider the key parameters: the amplitude, period, and phase shift of the sinusoidal function.

In the first equation, y = 2sin[(π/6)t] + 12, the amplitude is 2, which represents the maximum deviation from the average of 12 hours of daylight. The period is determined by the coefficient of t, which is π/6. Since the period of one year corresponds to 12 months, the coefficient is chosen to divide the period equally among the 12 months.

The phase shift, or horizontal shift, is not explicitly mentioned in the problem, so it is assumed to be zero. Adding 12 to the equation ensures that the average daylight hours are accounted for.

In the second equation, y = -2sin[(π/6)t] + 12, the only difference is the negative amplitude (-2). This equation represents the situation where the number of daylight hours is below the average.

By using these equations, one can calculate the number of daylight hours for each month of the year based on the given sinusoidal variation.

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The fraction of people who spent less than 20 minutes exercising yesterday is 3/10.

To find the fraction of people who spent less than 20 minutes exercising yesterday, we need to analyze the data provided in the table. Let's look at the table and count the number of people who spent less than 20 minutes exercising.

Time, t (minutes) | Number of People

0 ≤ t < 10        |       2

10 ≤ t < 20       |       1

20 ≤ t < 30       |       4

30 ≤ t < 40       |       3

From the table, we can see that there are a total of 2 + 1 + 4 + 3 = 10 people who responded. We are interested in finding the fraction of people who spent less than 20 minutes exercising, which includes those who spent 0 to 10 minutes and 10 to 20 minutes.

The number of people who spent less than 20 minutes is 2 + 1 = 3. Therefore, the fraction can be calculated by dividing the number of people who spent less than 20 minutes by the total number of people.

Fraction = (Number of people who spent less than 20 minutes) / (Total number of people)

        = 3 / 10

The fraction 3/10 cannot be simplified further, so the final answer is 3/10.

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The area of the surface generated by revolving the arc y = 2 from x = 0 to x = 4 about the y-axis is approximately 100.53 square units.

To find the area of the surface generated, we can use the formula for the surface area of revolution. When an arc is revolved about the y-axis, the surface area can be calculated by integrating 2πy ds, where ds represents a small element of arc length.

In this case, the equation y = 2 represents a straight line parallel to the x-axis at a distance of 2 units. The length of the arc can be calculated using the formula for the length of a line segment: L = √((x2 - x1)^2 + (y2 - y1)^2).

Considering the points (0, 2) and (4, 2), we find the length of the arc:

L = √((4 - 0)^2 + (2 - 2)^2) = √16 = 4 units.

Now, we can integrate 2πy ds over the interval [0, 4]:

Surface area = ∫(0 to 4) 2π(2) ds.

Since y = 2 throughout the interval, we have:

Surface area = ∫(0 to 4) 4π ds.

Integrating ds over the interval [0, 4] gives us the length of the arc:

Surface area = 4π(4) = 16π ≈ 50.27 square units.

Therefore, the area of the surface generated by revolving the given arc about the y-axis is approximately 100.53 square units.

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The triangle is an equilateral triangle and it is an acute triangle

From the question, we have the following parameters that can be used in our computation:

The triangle

From the figure, we can see that

The three lengths of triangle are congruent

This means that the triangle is an equilateral triangle

Also, we can see that

All angles in the triangle are less than 90

This means that the triangle is an acute triangle

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If the material used for the half-spheres are three times more expensive than the material used for the part cylindrical, then the radius of the cylindrical part should be (125/3π)^(1/3) meters and the length of the cylindrical part should be 11.99 meters.

The radius and length of the cylindrical part that will minimize the cost of building the tank, can be determined by considering the cost of the materials used for the half-spheres and the cylindrical part.

Let's start by finding the volume of the cylindrical part. The volume of a cylinder is given by the formula

V = πr²h, where r is the radius and h is the height or length of the cylindrical part.

In this case, we want the volume to be 1000m³, so we can write the equation as:

1000 = πr²h ...(1)

Next, let's find the surface area of the two half-spheres. The surface area of a sphere is given by the formula:

A = 4πr².

Since we have two half-spheres, the total surface area of the half-spheres is:

2(4πr²) = 8πr².

The cost of the half-spheres is three times more expensive than the cost of the cylindrical part. Let's say the cost per unit area of the cylindrical part is x, then the cost per unit area of the half-spheres is 3x.

The total cost, C, is the sum of the cost of the cylindrical part and the cost of the half-spheres. It can be expressed as:

C = x(2πrh) + 3x(8πr²) ...(2)

Now, we can minimize the cost by differentiating equation (2) with respect to either r or h and setting it equal to zero. This will help us find the values of r and h that minimize the cost. To simplify the calculations, we can rewrite equation (2) in terms of h using equation (1):

C = x(2πr(1000/πr²)) + 3x(8πr²) C = 2x(1000/r) + 24xπr² ...(3)

Now, differentiating equation (3) with respect to r:

dC/dr = -2000x/r² + 48xπr

Setting dC/dr equal to zero:

0 = -2000x/r² + 48xπr

Simplifying the equation:

2000x/r² = 48xπr

Dividing both sides by 4x: 500/r² = 12πr

Multiplying both sides by r²: 500 = 12πr³

Dividing both sides by 12π: 500/(12π) = r³

Simplifying: 125/3π = r³

Taking the cube root of both sides: r = (125/3π)^(1/3)

Now, we can substitute this value of r back into equation (1) to find the value of h:

1000 = π((125/3π)^(1/3))^2h

Simplifying: 1000 = (125/3π)^(2/3)πh

Dividing both sides by π and simplifying:

1000/π = (125/3π)^(2/3)h

Simplifying further:

1000/π = (125/3)^(2/3)h

Now we can solve for h: h = (1000/π) / ( (125/3)^(2/3) )

Simplifying: h = 11.99 m

To summarize, to minimize the cost of building the tank, the radius of the cylindrical part should be (125/3π)^(1/3) meters and the length of the cylindrical part should be approximately 11.99 meters.

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The given initial value problem (IVP), we have the following equation:[tex](x + ye)dx - xe dy = 0, y(1) = 0[/tex]  Here, the equation is not of a standard form.Integrating factor method states that a multiplying factor is multiplied to the entire equation to make it exact.

The steps involved in the integrating factor method are given below:

1. Rewrite the given equation in a standard form.

2. Determine the integrating factor (I.F).

3. Multiply the I.F to the given equation.

4. Integrate both sides of the new equation obtained in step 3.

5. Solve the final equation obtained in step 4 for y.

We can bring the xe term to the left-hand side and the ye term to the right-hand side.

[tex](x + ye)dx - xe dy = 0x dx + y dx e - x dy e = 0[/tex]

Now, we compare the above equation with the standard form of the linear differential equation:

[tex]M(x)dx + N(y)dy = 0[/tex]

Here,[tex]M(x) = xN(y) = -e^y[/tex]

We now find the integrating factor by using the above values.I.

[tex]F = e^(∫N(y)dy)I.F = e^(∫-e^ydy)I.F = e^-e^y[/tex]

Now, we multiply the I.

F with the given equation and rewrite it as below.

[tex]e^-e^y (x + ye)dx - e^-e^y xe dy = 0[/tex]

We can now integrate the above equation on both sides.

[tex]e^-e^y (x + ye)dx - e^-e^y xe dy = 0- e^-e^y x dx + e^-e^y dy = C[/tex]

Here, C is the constant of integration. Integrating both sides, we obtain- [tex]e^-e^y x + e^-e^y y = C[/tex]

Here, we have y(1) = 0.

Substituting this value of C in the above equation,- [tex]e^-e^y x + e^-e^y y = e^-e[/tex]

Thus, the solution of the given IVP is [tex]e^-e^y x - e^-e^y y = e^-e[/tex]

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The number of samples expected to have a value between 93 and 101 is 73 .

To determine the number of samples expected to have a value between 93 and 101 in a normally distributed dataset with a mean of 90 and a standard deviation of 17, we need to calculate the z-scores for both values and then find the area under the normal distribution curve between those z-scores.

First, we calculate the z-scores for 93 and 101 using the formula:

z = (x - μ) / σ

where x is the value, μ is the mean, and σ is the standard deviation.

For 93:

z_93 = (93 - 90) / 17 = 0.176

For 101:

z_101 = (101 - 90) / 17 = 0.647

Next, we need to find the area under the normal distribution curve between these two z-scores. We can use a standard normal distribution table or a statistical calculator to determine the corresponding probabilities.

Using a standard normal distribution table or calculator, we find that the probability of a z-score being between 0.176 and 0.647 is approximately 0.1469.

To find the number of samples expected to fall within this range, we multiply the probability by the total number of samples:

Number of samples = Probability * Total number of samples

= 0.1469 * 500

= 73.45

Therefore, we would expect approximately 73 samples out of the 500 to have values between 93 and 101, assuming the data are normally distributed.

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However, the number of acceleration data points that can be determined from the given position data remains 41 in this case.

In numerical differentiation, the acceleration can be approximated by taking the second derivative of the position data with respect to time.

Given 43 position data points (x, t), we can determine the acceleration at each of these points. However, it's important to note that the accuracy and reliability of the numerical differentiation method depend on the quality and spacing of the data points.

To compute the acceleration, we need at least three position data points. Using a technique like finite differences, we can approximate the second derivative at each point using three neighboring position data points. Therefore, we can determine the acceleration for a total of 41 data points out of the 43 position data points, excluding the first and last data points.

It's worth mentioning that using higher-order numerical differentiation methods or increasing the number of data points can potentially improve the accuracy of the acceleration estimation.

However, the number of acceleration data points that can be determined from the given position data remains 41 in this case.

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The pH of a 0.498 M aqueous hypochlorous acid solution at the start of the titration, before any sodium hydroxide has been added is 0.303.

pH is the hydrogen ion concentration of an solution. It is given  by pH = -log[H⁺] where H⁺ = hydrogen ion concentration.

Since a 23.8 mL sample of a 0.498 M aqueous hypochlorous acid solution is titrated with a 0.318 M aqueous sodium hydroxide solution. To find the pH at the start of the titration, before any sodium hydroxide has been added, we proceed as follows.

First we write the dissociation equation of the hypochlorous acid solution. So,

HClO(aq) → H⁺(aq) + ClO⁻(aq)

So, we see that the mole ratios are 1 : 1 : 1.

Since the HClO concentration is 0.498 M before the addition of sodium hydroxide, and there is a a 1 : 1 dissociation of hydrogen ion, then the hydrogen ion concentration H⁺ = 0.498 M

So, the pH = -logH⁺

= -log(0.498)

= -(-0.3028)

= 0.3028

≅ 0.303

So, the pH is 0.303

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The percentage of titanium, by mass, in titanium dioxide (TiO2) is approximately 59.94%. The empirical formula of glucose is CH2O.

To calculate the percentage of titanium, by mass, in titanium dioxide (TiO2), we need to determine the molar mass of titanium and the molar mass of the entire compound.

The molar mass of titanium (Ti) is 47.867 g/mol, and the molar mass of oxygen (O) is 15.999 g/mol.

Since titanium dioxide (TiO2) has two oxygen atoms, its molar mass is calculated as follows:

Molar mass of TiO2 = (molar mass of Ti) + 2 * (molar mass of O)

= 47.867 g/mol + 2 * 15.999 g/mol

= 79.866 g/mol

To calculate the percentage of titanium in TiO2, we divide the molar mass of titanium by the molar mass of TiO2 and multiply by 100:

Percentage of titanium = (molar mass of Ti / molar mass of TiO2) * 100

= (47.867 g/mol / 79.866 g/mol) * 100

= 59.94%

To calculate the empirical formula of glucose, we need to determine the ratio of the elements present in the compound.

Given the percentages of carbon (C), hydrogen (H), and oxygen (O) in glucose:

C: 39.95%

H: 6.71%

O: 53.34%

To convert these percentages to masses, we assume a 100 g sample. This means that we have:

C: 39.95 g

H: 6.71 g

O: 53.34 g

Next, we need to convert the masses of each element to moles by dividing them by their respective molar masses:

Molar mass of C = 12.01 g/mol

Molar mass of H = 1.008 g/mol

Molar mass of O = 16.00 g/mol

Number of moles of C = mass of C / molar mass of C

= 39.95 g / 12.01 g/mol

= 3.328 mol

Number of moles of H = mass of H / molar mass of H

= 6.71 g / 1.008 g/mol

= 6.654 mol

Number of moles of O = mass of O / molar mass of O

= 53.34 g / 16.00 g/mol

= 3.334 mol

To find the simplest whole-number ratio of the elements, we divide each number of moles by the smallest value (3.328 mol in this case):

C: 3.328 mol / 3.328 mol = 1

H: 6.654 mol / 3.328 mol ≈ 2

O: 3.334 mol / 3.328 mol ≈ 1

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The given question contains multiple parts related to equilibrium constants, reactions, and principles of chemistry. Each part requires a detailed explanation and calculation based on the provided information.

Part 1: To calculate the equilibrium constant Kc, we need to use the given equilibrium equation and concentrations of the reactants and products. Using the balanced equation CO(g) + Cl₂(g) ⇌ COCl₂(g), the initial concentration of COCl₂ is 0.03 mol / 1.50 L = 0.02 M. The equilibrium concentration of CO is 0.013 M. Using the equation Kc = [COCl₂] / ([CO] * [Cl₂]), we can substitute the values and calculate Kc at 800 K.

Part 2: The given reaction NaHCO₃(s) ⇌ Na₂CO₃(s) + CO₂(g) + H₂O(g) is an example of a decomposition reaction. The expression for the equilibrium constant Kc is Kc = ([Na₂CO₃] * [CO₂] * [H₂O]) / [NaHCO₃]. By examining the reaction, we can determine whether it is endothermic or exothermic by analyzing the energy changes. If the reaction releases heat, it is exothermic, and if it absorbs heat, it is endothermic.

Part 3: The reaction between acetic acid and ethyl alcohol to produce ethyl acetate and water is an esterification reaction. The equilibrium constant Kc is given as 6.68 at 55 °C. To calculate the grams of ethyl acetate formed at equilibrium, we need to determine the initial and equilibrium concentrations of acetic acid and ethanol and then use the stoichiometry of the reaction.

Part 4: The equilibrium constant for the O₂ binding reaction in fetal hemoglobin and adult hemoglobin is related to their P50 values. By comparing the P50 values, we can estimate the relative difference in Kc for fetal hemoglobin compared to adult hemoglobin using the relationship Kc(fetal) / Kc(adult) = P50(adult) / P50(fetal).

Part 5: The question discusses the difference in ozone (O₃) concentrations between winter and summer months and argues why contingency days are more common in summer. The explanation involves calculating the enthalpy of the reaction and applying Le Chatelier's principle to understand the behavior of the system.

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To determine the cylinder force required to overcome the load force in a 2-class lever system, we can use the formula:

Cylinder force = Load force × (L2 ÷ L1) × (sin(Ø) ÷ sin(e))

Given data:
L2 = 0.8L1 = 420 cm
Ø = 4 degrees
e = 12 degrees
Fload = 1.2 KN

First, let's convert the load force from kilonewtons (KN) to newtons (N):
Fload = 1.2 KN × 1000 N/1 KN = 1200 N

Next, substitute the given values into the formula:
Cylinder force = 1200 N × (0.8L1 ÷ L1) × (sin(4°) ÷ sin(12°))

Simplifying the expression:
Cylinder force = 1200 N × 0.8 × (sin(4°) ÷ sin(12°))

Now, let's calculate the sine values for 4 degrees and 12 degrees:
sin(4°) ≈ 0.0698
sin(12°) ≈ 0.2079

Substituting the sine values into the formula:
Cylinder force ≈ 1200 N × 0.8 × (0.0698 ÷ 0.2079)

Calculating the expression:
Cylinder force ≈ 320 N

Therefore, the cylinder force required to overcome the load force is approximately 320 Newtons.

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The Gram-Schmidt process is not unique, and the order in which the vectors are processed can affect the result. In this case, we followed the given order: v₁ = (6, 8) and v₂ = (2, 0).

To convert the basis {(6,8), (2,0)} into an orthonormal basis in ℝ² using the Gram-Schmidt process, we follow these steps:

1. Start with the first vector, v₁ = (6, 8).
  Normalize v₁ to obtain the first orthonormal vector, u₁:
  u₁ = v₁ / ||v₁||, where ||v₁|| is the norm of v₁.
  Thus, ||v₁|| = √(6² + 8²) = √(36 + 64) = √100 = 10.
  Therefore, u₁ = (6/10, 8/10) = (3/5, 4/5).

2. Proceed to the second vector, v₂ = (2, 0).
  Subtract the projection of v₂ onto u₁ to obtain a new vector, w₂:
  w₂ = v₂ - projₐᵤ(v₂), where projₐᵤ(v) is the projection of v onto u.
  projₐᵤ(v) = (v · u)u, where (v · u) is the dot product of v and u.
  So, projₐᵤ(v₂) = ((2, 0) · (3/5, 4/5))(3/5, 4/5) = (6/5, 8/5).
  Therefore, w₂ = (2, 0) - (6/5, 8/5) = (2, 0) - (6/5, 8/5) = (2, 0) - (6/5, 8/5) = (2 - 6/5, 0 - 8/5) = (4/5, -8/5).

3. Normalize w₂ to obtain the second orthonormal vector, u₂:
  u₂ = w₂ / ||w₂||, where ||w₂|| is the norm of w₂.
  Thus, ||w₂|| = √((4/5)² + (-8/5)²) = √(16/25 + 64/25) = √(80/25) = √(16/5) = 4/√5.
  Therefore, u₂ = (4/5) / (4/√5), (-8/5) / (4/√5) = (√5/5, -2√5/5) = (√5/5, -2/√5).

Now, we have an orthonormal basis for ℝ²:
{(3/5, 4/5), (√5/5, -2/√5)}.

Please note that the Gram-Schmidt process is not unique, and the order in which the vectors are processed can affect the result. In this case, we followed the given order: v₁ = (6, 8) and v₂ = (2, 0).

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The credit card activity of a card shows an opening balance of $240. During the course of the month of September, the card has been used and the balance increases to $460.

However, payments of $200 have been made on the card bringing the final balance to $260 for the month of September. We need to calculate the interest that will be charged on the card in the month of September if the balance is not paid during the grace period. The APR of the card is 18.4% and the number of days in September is 30.Daily Interest rate =

APR/365 × 100= 18.4/365 × 100= 0.05%

Interest charged on the card for September = Daily Interest rate × balance × number of days= 0.05% × 260 × 30= $3.90, rounded to the nearest dollar.= $4. The credit card balance for the month of September is given as follows: Opening balance = $240. Card usage during September = $220 (increase in the balance from $240 to $460)Payments made in September = $200 (balance reduced to $260)We need to calculate the interest charged on the card for September if the balance of $260 is not paid during the grace period. The card has an annual percentage rate (APR) of 18.4% and the month of September has 30 days. In order to calculate the daily interest rate, we need to divide the annual percentage rate by 365 and multiply by 100. This gives us the daily interest rate as 0.05%. The interest charged on the card for September can now be calculated by multiplying the daily interest rate by the balance and the number of days in the month of September. This gives us an interest of $3.90, which when rounded to the nearest dollar is $4.

The interest charged on the credit card for the month of September, if the balance is not paid during the grace period, is $4.

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In summary, the solution to the heat equation problem is given by the Fourier expansions: u(x,t) = ∑[B_n sin(nπx√5)e^(-n^2π^2t/5)],where B_n can be determined using the initial condition u(x,0) = x - x^3.

To solve the heat equation problem, we will use the method of separation of variables.

Let's assume the solution can be written as u(x,t) = X(x)T(t). Plugging this into the heat equation, we get:

T'(t)X(x) = 5X''(x)T(t)

Dividing both sides by u(x,t), we have:

T'(t)/T(t) = 5X''(x)/X(x)

Now, since both sides depend on different variables, they must be equal to a constant. Let's denote this constant as -λ^2.

So we have two separate ordinary differential equations: T'(t)/T(t) = -λ^2 and 5X''(x)/X(x) = -λ^2.

The first equation gives us T(t) = Ae^(-λ^2t), where A is a constant.

The second equation gives us X''(x) + (λ^2/5)X(x) = 0. Solving this equation, we find that X(x) = Bsin(λx√5) + Ccos(λx√5), where B and C are constants.

To satisfy the boundary conditions, we have X(0) = 0 and X(1) = 0. Plugging these into the equation, we find that C = 0 and λ = nπ/√5, where n is an integer.

Finally, using the Fourier expansion, we can express the solution u(x,t) as an infinite sum:

u(x,t) = ∑[B_n sin(nπx√5)e^(-n^2π^2t/5)]

Using the initial condition, u(x,0) = x - x^3, we can find the coefficients B_n through the Fourier sine series expansion.

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Answer:

Step-by-step explanation:

16a³-2b³

Take 2 out of the equation as a common factor

2(8a³-b³)

Consider (8a³-b³) and

Rewrite the equation

The difference between cubes can be factored into using the rule:

[tex](2a-b)(4a^{2} +2ab+b^{2} )[/tex]

The thermochemical equation for the enthalpy of combustion of hydrogen is:

2H2(g) + O2(g) -> 2H2O(l)

In this equation, two moles of hydrogen gas (H2) react with one mole of oxygen gas (O2) to produce two moles of liquid water (H2O). The enthalpy change, or heat of combustion, can be calculated by subtracting the enthalpy of the reactants from the enthalpy of the products.

The enthalpy of combustion of hydrogen can be determined experimentally by measuring the amount of heat released when hydrogen is burned in the presence of oxygen. This value is typically expressed in units of energy per mole (e.g. kJ/mol).

It is important to note that the enthalpy of combustion can vary depending on the conditions under which the reaction takes place, such as temperature and pressure. Additionally, the enthalpy of combustion is a thermodynamic property that represents the energy released or absorbed during a chemical reaction.

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It generally takes more effort to cool something quickly compared to cooling it slowly. This is because cooling something quickly requires a larger difference in temperature between the object and its surroundings.

When an object is cooled slowly, the temperature difference between the object and its surroundings is relatively small. This means that heat is transferred at a slower rate, requiring less effort to cool the object. In contrast, when an object is cooled quickly, the temperature difference between the object and its surroundings is larger. This leads to a faster rate of heat transfer and requires more effort to cool the object.

To understand this concept, let's consider an example. Imagine you have a cup of hot water and you want to cool it down. If you place the cup in a room temperature environment, the temperature difference between the hot water and the room is relatively small. As a result, the cup of hot water will cool down slowly.

However, if you want to cool the cup of hot water quickly, you could place it in a refrigerator or pour it over a container of ice. In these scenarios, the temperature difference between the hot water and the cold environment is larger, leading to a faster rate of heat transfer and thus, faster cooling.

In summary, cooling something quickly requires a larger temperature difference and therefore more effort compared to cooling it slowly.

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Gas chromatography-mass spectrometry (GC-MS) is a highly effective technique for identifying the molecular composition of samples. By separating compounds based on their unique chemical and physical properties and analyzing them using mass spectrometry, GC-MS provides valuable insights into the constituents of a sample.

Experimental Parameters:

Solvent Cut: Solvent cut refers to the percentage of solvent added to the sample prior to injection. Its purpose is to increase sample volume and enhance the visibility of sample peaks. The selection of solvent cut depends on the sample concentration and desired separation, elution, and resolution.

Flow Rate: Flow rate denotes the rate at which the sample traverses the chromatography column. It serves to control the speed of analysis and is determined by the properties of both the column and the sample being analyzed.

Ionization Temperature: Ionization temperature corresponds to the temperature at which the sample is ionized during mass spectrometry. This parameter is specific to the sample type and aims to optimize ionization efficiency for accurate detection and identification.

Results and Discussion:

The outcomes of the experiment are discussed in terms of separation, elution, and peak characteristics, shedding light on the mechanisms underlying different types of peak broadening. Various factors contributing to peak broadening are explained, elucidating the reasons behind sample overload, column overloading, and broadening at the injection point.

Sample Overload: Sample overload occurs when the concentration of the sample exceeds the column's capacity, leading to saturation. This results in broadened peaks and compromised separation.

Column Overloading: Column overloading transpires when the chromatographic column fails to adequately separate all compounds in the sample due to excessive loading. Consequently, peaks become broader and less resolved.

Broadening at the Injection Point: Broadening at the injection point arises from the injection technique itself, potentially distorting the elution profile of the sample. This injection-related broadening can impact peak shape and resolution.

To determine the elution order of solvents, the analysis commences with examination of the solvent front peak, which represents the first compound to elute from the column. Identification of the solvent allows subsequent determination of retention times for other compounds in the sample, enabling their identification. It is important to understand the parameters that are used in the analysis, as well as the outcomes of the experiment, to ensure accurate and precise results.

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Integral: To evaluate the integral ∫(4x)dx by completing the square, we can rewrite the integrand as a perfect square. The integrand can be expressed as 4(x) = (2x)^2.

∫(4x)dx = ∫(2x)^2 dx

Now, we can integrate using the power rule for integration:

= (2/3)(2x)^3 + C

= (8/3)x^3 + C

Therefore, the integral of 4x with respect to x is (8/3)x^3 + C, where C represents the constant of integration.

Derivative: To find the derivative of the exponential function y = x * e^(r * x), we can use the product rule of differentiation.

Let's differentiate term by term:

dy/dx = d/dx (x * e^(r * x))

Applying the product rule, we have:

dy/dx = x * d/dx(e^(r * x)) + e^(r * x) * d/dx(x)

The derivative of e^(r * x) with respect to x is r * e^(r * x), and the derivative of x with respect to x is 1. Substituting these values, we get:

dy/dx = x * (r * e^(r * x)) + e^(r * x) * 1

dy/dx = r * x * e^(r * x) + e^(r * x)

Therefore, the derivative of the exponential function y = x * e^(r * x) with respect to x is r * x * e^(r * x) + e^(r * x).

Integral: Unfortunately, you haven't provided the function inside the integral. Please provide the function so that I can assist you in finding the integral.

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The maximum bending stress in the cantilevered wood planks is 58 MPa.

To determine the maximum bending stress in the cantilevered wood planks, we can use the formula for bending stress:
Bending Stress = (Pressure x Height) / (2 x Moment of Inertia x Distance)
1. Calculate the pressure at the bottom of the soil wall:
  The pressure varies linearly from 0 kPa at the top to 14.5 kPa at the fixed base. Since we are considering a 1-meter length, the average pressure can be calculated as:
  Average Pressure = (0 kPa + 14.5 kPa) / 2 = 7.25 kPa
2. Convert the average pressure to Pascals (Pa):
  1 kPa = 1000 Pa
  Average Pressure = 7.25 kPa x 1000 Pa/kPa = 7250 Pa
3. Calculate the moment of inertia of the wooden plank:
  The moment of inertia for a rectangular beam can be calculated using the formula:
  Moment of Inertia = (Width x Thickness^3) / 12
  Given:
  Width (W) = 300 mm = 0.3 m
  Thickness (T) = 100 mm = 0.1 m
  Moment of Inertia = (0.3 x 0.1^3) / 12 = 0.000025 m^4
4. Calculate the maximum bending stress:
  Distance = Height / 2
  Distance = 3 m / 2 = 1.5 m
  Bending Stress = (7250 Pa x 3 m) / (2 x 0.000025 m^4 x 1.5 m)
  Bending Stress = 4350000 Pa / 0.000075 m^4
  Bending Stress = 58000000 Pa
5. Convert the bending stress to megapascals (MPa):
  1 MPa = 1,000,000 Pa
  Bending Stress = 58000000 Pa / 1,000,000 Pa/MPa = 58 MPa
Therefore, the maximum bending stress in the cantilevered wood planks is 58 MPa.

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We would need at least 1 tube in the heat exchanger.

To determine the number of tubes needed in the shell and tube process heater, we can use the equation for heat transfer:

Q = m * Cp * ΔT

Where:
Q is the heat transfer rate (600 kW)
m is the mass flow rate of water
Cp is the specific heat capacity of water (4180 J/kg.°C)
ΔT is the temperature difference (90°C - 20°C = 70°C)

First, we need to calculate the mass flow rate of water:

m = Q / (Cp * ΔT)
m = 600000 / (4180 * 70)
m ≈ 2.32 kg/s

Next, we need to calculate the cross-sectional area of a single tube using the inner diameter:

A = π * (d/2)^2
A = π * (0.01/2)^2
A ≈ 0.0000785 m^2

To find the velocity of water, we can use the equation:

V = m / (ρ * A)

Where:
V is the velocity of water
ρ is the density of water (1000 kg/m³)

V = 2.32 / (1000 * 0.0000785)
V ≈ 29.55 m/s

Since the velocity of water should not exceed 3 m/s, we need to reduce the number of tubes to achieve this. We can calculate the new cross-sectional area of a single tube using the desired velocity:

A' = m / (ρ * V)
A' = 2.32 / (1000 * 3)
A' ≈ 0.000773 m^2

Now, we can calculate the new number of tubes needed:

Number of tubes = Total cross-sectional area / New cross-sectional area
Number of tubes = Total cross-sectional area / (π * (d/2)^2)
Number of tubes = 0.0000785 / 0.000773
Number of tubes ≈ 0.101 tubes

Since we cannot have a fraction of a tube, we would need to round up to the nearest whole number. Therefore, we would need at least 1 tube in the heat exchanger.

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Slip is a mechanism in which atoms move along the crystal plane under stress. Slip planes are crystallographic planes in a crystal that allow for the most extensive movement of atoms during slip. Larger grain sizes are more ductile than smaller grain sizes.

Ceramics are intrinsically harder than metals, but their use as an engineering material is limited.

Here are 4 properties of ceramics which make them useful in an engineering context and how their properties are influenced by their atomic bonding arrangements.

1. Hardness: Ceramics are more challenging than metals, and their hardness makes them resistant to wear and corrosion. Their atomic bonding arrangements contribute to their hardness by creating strong covalent and ionic bonds.

2. High melting point: The majority of ceramics have high melting points, making them ideal for high-temperature applications. Their atomic bonding arrangement plays a crucial role in their high melting point, as the strong covalent and ionic bonds require a large amount of energy to break.

3. Low thermal expansion: Ceramics have a low thermal expansion coefficient, which makes them useful for high-temperature applications.

Their atomic bonding arrangements contribute to their low thermal expansion by forming strong and rigid structures.

4.Insulators: Ceramics have poor electrical conductivity, which makes them ideal electrical insulators.Their atomic bonding arrangements contribute to their poor electrical conductivity by limiting the movement of electrons.

4 specific applications of ceramics include: bio-ceramics (replacement joints, teeth), electronic components, refractory materials (kiln linings, furnace components), and thermal barrier coatings.

In relation to crystalline materials, slip is a mechanism in which atoms move along the crystal plane under stress.

Slip planes are crystallographic planes in a crystal that allow for the most extensive movement of atoms during slip.

The grain size affects the movement of slip planes in that larger grains have fewer grain boundaries and, therefore, more movement along slip planes.

Conversely, smaller grains have more grain boundaries, which limit movement along slip planes.

Hence, larger grain sizes are more ductile than smaller grain sizes.

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The complete question is-

a) Ceremics are intrinsically harder than metals. however their use as an engineering material is limited. Identify 4 properties of ceramics which make them useful in an enginnering context ,outline how their properties are influenced by their atomic bonding arrangments and give 4 specific applications of ceramics

b) In relation to crystalline materials, explain the term slip and slip planes. how does the grain size affect the movement of slip planes?

Describe and illustrate the slip planes found for either the FCC crystal structure or the BCC crystal structure. how many slip system does your chosen structure contain?

In crystalline materials, slip refers to the movement of dislocations (line defects) within the crystal lattice. Slip planes are specific crystallographic planes along which dislocations move most easily. These planes are determined by the crystal structure and atomic arrangement.

The grain size of a material affects the movement of slip planes. In materials with larger grain sizes, the presence of grain boundaries obstructs the movement of dislocations. This leads to a higher resistance to slip, resulting in increased strength. On the other hand, smaller grain sizes allow dislocations to move more easily, reducing the strength of the material. Therefore, grain size plays a critical role in the mechanical behavior of crystalline materials.

Ceramics have unique properties that make them useful in engineering applications. These properties are influenced by their atomic bonding arrangements. Here are four properties of ceramics and their corresponding atomic bonding arrangements:

1. Hardness: Ceramics are known for their high hardness, which is attributed to their strong and rigid atomic bonding arrangements. They typically have ionic or covalent bonding, where atoms are held together by electrostatic attractions or shared electron pairs, respectively. For example, alumina (Al2O3) has a network of oxygen and aluminum atoms bonded through ionic interactions.

2. High melting point: Ceramics generally have high melting points due to their strong atomic bonding arrangements. The ionic or covalent bonds in ceramics require significant energy to break, leading to high melting temperatures. For instance, silicon carbide (SiC) has a melting point of about 2700°C, making it suitable for high-temperature applications like refractory linings in furnaces.

3. Chemical resistance: Ceramics are often chemically inert and resistant to corrosion. This property is influenced by their atomic bonding arrangements, which result in stable structures. For example, zirconia (ZrO2) exhibits excellent chemical resistance, making it suitable for applications in harsh chemical environments.

4. Electrical insulation: Ceramics are excellent electrical insulators due to their atomic bonding arrangements, which inhibit the movement of electrons. Ceramics with primarily ionic bonding, like porcelain, have high electrical resistivity and are widely used for insulating electrical wires and components.

Here are four specific applications of ceramics:

1. Cutting tools: Ceramic materials such as alumina and silicon nitride are used in cutting tools due to their exceptional hardness and wear resistance.

2. Biomedical implants: Bioinert ceramics like zirconia and alumina are used for dental implants, hip replacements, and other biomedical applications due to their biocompatibility and resistance to corrosion.

3. Heat shields: Ceramics like silica and alumina-based materials are utilized as heat shields in aerospace applications due to their high melting point and excellent thermal insulation properties.

4. Electronics: Ceramic materials such as piezoelectric ceramics (e.g., lead zirconate titanate) are used in electronic devices for their unique electrical and mechanical properties, like the ability to convert mechanical stress into electrical signals.

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BC is 30 units and mBC is approximately 61.93 degrees.

Given that AC is a diameter of the circle OE, we can deduce that triangle ABC is a right triangle, with AC being the hypotenuse.

We are given that the area of the circle is 289π square units, which implies that the radius of the circle is 17 units (since the formula for the area of a circle is A = πr^2).

Since AC is the diameter, its length is twice the radius, which means AC = 2 * 17 = 34 units.

We are also given that AB = 16 units.

Using the Pythagorean theorem, we can find BC and the measure of angle BC.

In the right triangle ABC, we have:

AB^2 + BC^2 = AC^2

Substituting the given values, we get:

16^2 + BC^2 = 34^2

256 + BC^2 = 1156

BC^2 = 1156 - 256

BC^2 = 900

Taking the square root of both sides, we find:

BC = √900

BC = 30 units

Therefore, BC is 30 units.

To find the measure of angle BC, we can use trigonometry. Since we know the lengths of the sides, we can use the inverse tangent function (tan^(-1)) to find the angle.

mBC = tan^(-1)(opposite/adjacent) = tan^(-1)(BC/AB) = tan^(-1)(30/16)

Using a calculator, we find that mBC ≈ 61.93 degrees.

Therefore, BC is 30 units and mBC is approximately 61.93 degrees.

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