3. concepts true or False? a) the activation energy is always positive. b) rate constant increase with temperature. c) rate constant does not change with concentration.

The new boiling temperature of water is approximately 107 °C, and the new freezing temperature is approximately -26 °C.

To calculate the new boiling and freezing temperatures of water when ethylene glycol is added, we can use the formulas for boiling point elevation and freezing point depression.

Boiling Point Elevation:

ΔTbp = Kbp * m

Freezing Point Depression:

ΔTfp = Kfp * m

Mass of water (m1) = 4451 g

Mass of ethylene glycol (m2) = 1.01 kg = 1010 g

Molar mass of ethylene glycol (M2) = 62.07 g/mol

Boiling point constant (Kbp) = 0.512 °C/m

Freezing point constant (Kfp) = 1.86 °C/m

First, we need to calculate the molality (m) of the ethylene glycol solution:

m2 = molar mass of ethylene glycol * number of moles of ethylene glycol / mass of water

= (62.07 g/mol) * (1010 g) / (4451 g)

≈ 14.1 mol/kg

Now, we can calculate the changes in boiling and freezing temperatures:

ΔTbp = Kbp * m

= (0.512 °C/m) * (14.1 mol/kg)

≈ 7.209 °C

ΔTfp = Kfp * m

= (1.86 °C/m) * (14.1 mol/kg)

≈ 26.226 °C

To find the new boiling temperature (Tbp) and freezing temperature (Tfp) of water, we add the changes to the respective pure water temperatures:

New Boiling Temperature:

Tbp = 100.0°C + 7.209 °C

≈ 107.209 °C

New Freezing Temperature:

Tfp = 0.00 °C - 26.226 °C

≈ -26.226 °C

Rounding to the correct number of significant figures, we get:

New Boiling Temperature = 107 °C

New Freezing Temperature = -26 °C

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The vertical reaction of support A can be calculated by considering the given values. The values provided are E = 8 kN, G = 5 kN, H = 3 kN, Kas = 7 m, Las = 3 m, and N = 12 m.

To calculate the vertical reaction of support A, follow these steps:

1. Calculate the moment about support A due to the forces:

2. Sum up the moments about A:

3. Determine the vertical reaction of support A:

The vertical reaction of support A can be determined by calculating the total moment about support A, considering the moments contributed by forces E, G, and H. The vertical reaction is obtained by dividing the total moment by the distance Las.

The vertical reaction of support A can be found by calculating the total moment about support A and dividing it by the distance Las.

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It will take 50 minutes for the tank to be full. At the time the tank is full, it will contain 100 lbs of concentrate.

(a) To find out when the tank will be full, we need to determine the time it takes to fill the remaining half of the tank. Initially, the tank is half full, which is 200 gallons / 2 = 100 gallons.

The concentrate enters the tank at a rate of 5 gallons per minute, while the mixture is being pumped out at a rate of 3 gallons per minute. This means that the tank is being filled at a net rate of 5 gallons per minute - 3 gallons per minute = 2 gallons per minute.

To calculate the time it takes to fill the remaining 100 gallons, we divide the remaining volume by the net filling rate:
Time = Volume / Rate
Time = 100 gallons / 2 gallons per minute
Time = 50 minutes

Therefore, it will take 50 minutes for the tank to be full.

(b) At the time the tank is full, we need to determine the amount of concentrate it contains. Since the concentrate enters the tank at a rate of 1/2 lb/gal, we can calculate the total amount of concentrate that enters the tank.

Total concentrate = Concentrate rate x Volume
Total concentrate = (1/2 lb/gal) x (200 gallons)
Total concentrate = 100 lbs

Therefore, at the time the tank is full, it will contain 100 lbs of concentrate.

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The general solution to the given differential equation is [tex]y = cx^2 - 2x^3,[/tex] where c is a constant.

To find the general solution, we first rearrange the given differential equation in the standard form of a linear first-order equation. The equation is:

x^2y' - 2xy = 4

We can rewrite this equation as:

[tex]y' - (2/x)y = 4/x^2[/tex]

This is now in the form of a linear first-order equation, where the coefficient of y' is 1. To solve this type of equation, we use an integrating factor, which is given by the exponential of the integral of the coefficient of y. In this case, the integrating factor is:

IF = e^(-∫2/x dx) = e^(-2ln|x|) = e^(ln|x|^(-2)) = 1/x^2

Multiplying the entire equation by the integrating factor, we get:

[tex](1/x^2)y' - 2/x^3 y = 4/x^4[/tex]

Now, the left-hand side of the equation can be written as the derivative of the product of the integrating factor and y:

[tex]d/dx [(1/x^2)y] = 4/x^4[/tex]

Integrating both sides with respect to x, we have:

[tex]∫d/dx [(1/x^2)y] dx = ∫4/x^4 dx[/tex]

[tex]∫(1/x^2)y dx = -4/x^3 + C[/tex]

Integrating the left-hand side gives:

[tex]-(1/x)y + C = -4/x^3 + C[/tex]

Simplifying further, we get:

[tex]y = cx^2 - 2x^3[/tex]

where c is the constant obtained by combining the arbitrary constant C with the constant of integration.

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The correct order of increasing magnitude of lattice energy is:

MgS < NaCl < CsI

The correct answer is:

O MgS < NaCl < CsI

The lattice energy is a measure of the strength of the forces holding the ions together in a compound. It is influenced by the charge and size of the ions.

In this case, we are given four compounds: O CsI, NaCl, MgS, and K. We need to arrange them in order of increasing magnitude of lattice energy.

To determine this, we can consider the charges and sizes of the ions in each compound.

1. O CsI: Cs+ is a larger ion compared to I-, while O2- is smaller than I-. The larger the ions, the weaker the force of attraction between them. Therefore, O CsI will have the weakest lattice energy.

2. NaCl: Both Na+ and Cl- ions are smaller in size compared to the ions in O CsI. The smaller the ions, the stronger the force of attraction between them. Thus, NaCl will have a stronger lattice energy than O CsI.

3. MgS: Both Mg2+ and S2- ions are smaller than the ions in NaCl. Hence, MgS will have a stronger lattice energy than NaCl.

Based on the above analysis, the correct order of increasing magnitude of lattice energy is:

MgS < NaCl < CsI

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1.a. For all x, if x is an athlete, then x is brawny.

b. Mary is an athlete and Ned is an athlete. Therefore, Mary is brawny and Ned is brawny.

2.a. For all x, if x is an athlete, then x is brawny.

b. For all x, if x is brawny, then x is a champion. Therefore, for all x, if x is an athlete, then x is a champion.

1.a. The first argument states that if something is an athlete, then it is brawny. This can be understood as a general statement about athletes and their physical attributes.

b. The second part of the argument introduces specific individuals, Mary and Ned, and states that both of them are athletes. Therefore, based on the premise from part a, it can be concluded that Mary is brawny and Ned is brawny.

2.a. The first argument is similar to the previous one, stating that if something is an athlete, then it is brawny.

b. The second part of the argument introduces a new premise, stating that if something is brawny, then it is a champion. Based on this premise, and using the transitive property of implication, it can be concluded that if something is an athlete, then it is a champion.

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The concentration of [tex]NH_{4} ^{+}[/tex] and [tex]NO_{2}^{-}[/tex] are 0.21 and 0.10 M, respectively, so the initial rate of the reaction between [tex]NH_{4} ^{+}[/tex] and  [tex]NO_{2}^{-}[/tex] is 1.1 x 10⁻⁵ M/s.

The initial rate of the reaction between [tex]NH_{4} ^{+}[/tex] and [tex]NO_{2}^{-}[/tex] is calculated using the formula: Initial rate = [tex]k [NH_{4} ^{+}][NO_{2}^{-}  ][/tex], where k is the rate constant, [tex][NH_{4} ^{+}][/tex] is the concentration of [tex]NH_{4} ^{+}[/tex], and [tex][NO_{2}^{-}][/tex] is the concentration of  [tex]NO_{2}^{-}[/tex].

The concentration of [tex]NH_{4} ^{+}[/tex] and [tex]NO_{2}^{-}[/tex] are 0.21 and 0.10 M respectively. The rate is first order with respect to both reactants. The rate constant is 2.6 x 10⁻⁴ M⁻¹s⁻¹.

The formula to calculate the initial rate of the reaction between [tex]NH_{4} ^{+}[/tex] and [tex]NO_{2}^{-}[/tex] is:

Initial rate = k[NH4+][NO2–] Where k is the rate constant and  [tex][NH_{4} ^{+}][/tex] and [NO_{2}^{-}][/tex] are the concentration of [tex]NH_{4} ^{+}[/tex] and [tex]NO_{2}^{-}[/tex] respectively.

The given values are substituted in the above formula to obtain the initial rate of the reaction.

Initial rate = 2.6 x 10⁻⁴ M⁻¹s⁻¹ x 0.21 M x 0.10

MInitial rate = 1.1 x 10⁻⁵ M/s

Therefore, the initial rate of the reaction between [tex]NH_{4} ^{+}[/tex] and [tex]NO_{2}^{-}[/tex] is 1.1 x 10⁻⁵ M/s.

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Extensive properties are defined as the properties of a system that depend on the amount or size of the system.

The more massive a system is, the greater its extensive property will be. The size of a system is also a factor that influences its extensive properties.

Examples of extensive properties include mass, volume, and energy content.

Intensive properties are defined as properties of a system that do not depend on the size or amount of the system.

An intensive property remains constant regardless of the size of the system.

Examples of intensive properties include pressure, temperature, density, and specific heat capacity.

How to differentiate intensive properties from extensive properties

A property is intensive if it stays the same regardless of the amount of the substance. An intensive property is one that is independent of the amount of the substance.

For example, temperature and pressure are independent of the amount of material in a system.

Examples of intensive properties of a system1. Melting point and boiling point2. Refractive index and surface tension.

Examples of extensive properties of a system1. Mass2. Volume

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2.1. Exiting humidity: Approximately 22.7%. Amount of water passing through the wicks per hour: Approximately 67.5 kg/h.  2.2. Required rate of heat transfer: Approximately 62.125 kW. Amount of water removed per hour: Approximately 67.5 kg/h.

To calculate the exiting humidity and the amount of water passing through the wicks per hour (2.1), and the required rate of heat transfer and the amount of water removed per hour (2.2), let's go through the steps and calculations.

2.1. Exiting Humidity and Amount of Water Passing Through the Wicks per Hour:

Step 1: Use the steam tables to determine the enthalpies of saturated air at the inlet and outlet temperatures.

Given values from the steam tables:

he1 = 2547.3 kJ/kg

ha2 = 322.8 kJ/kg

hv2 = 2592.2 kJ/kg

Step 2: Use psychometric charts to determine the absolute humidity against the inlet temperature and relative humidity.

Given relative humidity at the exit:

[tex]phi_2 = P_{12} / Pv_2[/tex] = 2.81 kPa / 12.34 kPa ≈ 0.227

This means that the relative humidity at the exit is approximately 22.7%.

Step 3: Calculate the amount of water passing through the wicks per hour.

Given:

Mass flow rate of air (ma) = 2.5 kg/s

Specific humidity (omega) = 0.0075

The amount of water passing through the wicks per hour can be calculated as:

mv = omega * ma = 0.0075 * 2.5 kg/s = 0.01875 kg/s

Converting to per hour:

mv = 0.01875 kg/s * 3600 s/h = 67.5 kg/h

Therefore, the amount of water passing through the wicks per hour is approximately 67.5 kg/h.

2.2. Required Rate of Heat Transfer and Amount of Water Removed per Hour:

Given:

Initial temperature (Ti) = 25°C

Final temperature (T2) = 15°C

Initial humidity (d) = 35%

Initial pressure (P1) = 100 kPa

Mass flow rate of air (m) = 2.5 kg/s

Step 1: Use the steam tables to determine the enthalpies of saturated air at the inlet and outlet temperatures.

Given values from the steam tables:

he1 = 2547.3 kJ/kg

ha1 = 297.68 kJ/kg

Step 2: Use psychometric charts to determine the absolute humidity against the inlet temperature and relative humidity.

Given relative humidity at the exit:

[tex]phi_2[/tex]= 0 (completely dry condition)

Step 3: Calculate the required rate of heat transfer.

The rate of heat transfer can be calculated using the formula:

Q = ma * (ha2 - ha1) + mv * (hv2 - hv1)

Given values:

ma = 2.5 kg/s

mv = omega * ma = 0.0075 * 2.5 kg/s = 0.01875 kg/s

ha2 = 322.8 kJ/kg

ha1 = 297.68 kJ/kg

hv2 = 2592.2 kJ/kg

hv1 = 2547.3 kJ/kg

Q = 2.5 kg/s * (322.8 kJ/kg - 297.68 kJ/kg) + 0.01875 kg/s * (2592.2 kJ/kg - 2547.3 kJ/kg)

Q ≈ 62.125 kJ/s ≈ 62.125 kW

Therefore, the required rate of heat transfer is approximately 62.125 kW.

Step 4: Calculate the amount of water removed per hour.

The amount of water removed per hour can be calculated as:

mv = omega * ma = 0.0075 * 2.5 kg/s = 0.01875 kg/s

Converting to per hour:

mv = 0.01875 kg/s * 3600 s/h = 67.5 kg/h

Therefore, the amount of water removed per hour is approximately 67.5 kg/h.

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In the case of lead, there are approximately 2.8 x 10^23 atoms present in the sample. For titanium, there are around 7.029 x 10^22 atoms in the sample. As for acetone (CH3COCH3), the number of molecules present in the sample can be determined by converting the given number of moles to molecules.

To find the number of atoms in a sample of a substance, we can use Avogadro's number, which states that there are 6.022 x 10^23 atoms in one mole of a substance.

For lead, we have 0.505 moles of the substance. Multiplying this by Avogadro's number gives us the number of atoms: 0.505 moles x 6.022 x 10^23 atoms/mole = 3.04 x 10^23 atoms.

For titanium, we have 0.505 moles of the substance. Again, multiplying this by Avogadro's number gives us the number of atoms: 0.505 moles x 6.022 x 10^23 atoms/mole = 3.04 x 10^23 atoms.

Now, for acetone, we are given the chemical formula CH3COCH3. To find the number of molecules, we can use the same approach. We have 0.505 moles of acetone. Multiplying this by Avogadro's number gives us the number of molecules: 0.505 moles x 6.022 x 10^23 molecules/mole = 3.04 x 10^23 molecules.

In summary, there are approximately 3.04 x 10^23 atoms in the sample for both lead and titanium. For acetone, there are approximately 3.04 x 10^23 molecules in the sample.

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A negative value of the cell potential indicates that the reaction is non-spontaneous and is not thermodynamically favorable to proceed. Therefore, it is unlikely to observe this reaction happening. The numeric value of the cell potential is -1.26 V.

The equation for the cell reaction is: Zn(s) + Sn2+(aq) → Zn2+(aq) + Sn(s)

We are required to calculate the cell potential for the reaction as written at 25.00°C given that

[Zn2+]=0.842M and [Sn2+]=0.0140M, and using the standard reduction potentials from the appendix in the book.

The standard reduction potentials given in the book are: E° Zn2+ /Zn = −0.76 VE° Sn2+ /Sn = −0.14 V

The cell potential, E, can be determined using the following formula: E = E° cell – (RT/nF) ln Q

Where: E°cell is the standard cell potential, R is the universal gas constant (8.314 J/K mol), T is the temperature in kelvin (25.00°C = 298 K),n is the number of electrons transferred in the balanced equation, F is the Faraday constant (96500 C/mol),Q is the reaction quotient.

Q can be written as: Q = ([Zn2+] / [Sn2+])

Here, n = 2 (because two electrons are transferred), and F = 96500 C/mol.

Putting all these values in the formula above, we get:

E = E°cell – (RT/2F) ln [Zn2+] / [Sn2+]

= E°red, cathode – E°red, anode

= E°red, cathode + E°ox, anode

E°red, cathode = E° Sn2+ /Sn = −0.14 V

E°red, anode = E° Zn2+ /Zn = −0.76 V

Now, E°cell = E°red, cathode + E°red, anode

= -0.14 + (-0.76) = -0.90 V

E = E°cell – (RT/2F) ln [Zn2+] / [Sn2+]

E = -0.90 - [(8.314 × 298)/(2 × 96500)] ln (0.842/0.0140)

E = -0.90 - 0.019 ln 60.14

E = -0.90 - 0.364E = -1.26 V

A negative value of the cell potential indicates that the reaction is non-spontaneous and is not thermodynamically favorable to proceed. Therefore, it is unlikely to observe this reaction happening. The numeric value of the cell potential is -1.26 V.

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Fischer esterification is the reaction of a carboxylic acid with an alcohol to produce an ester in the presence of a catalyst. When benzoic acid and methanol are reacted, benzyl alcohol is produced as an ester.

The reaction is acid-catalyzed, so the catalytic substance is usually a mineral acid such as sulfuric or hydrochloric acid.  Protonation of Carboxylic AcidFirst, protonation of carboxylic acid takes place in the presence of a catalyst. In the first step of this reaction, the carboxylic acid is protonated by the catalyst, which creates a more reactive electrophile that is highly susceptible to nucleophilic attack. As a result, an intermediate is produced that is highly reactive. Nucleophilic Attack

The nucleophilic attack of the alcohol on the intermediate occurs in the second step of the Fischer esterification reaction. The nucleophilic attack of the alcohol results in the formation of an intermediate that is an alkoxide ion. Deprotonation The protonation of the alkoxide ion takes place in the final step of the Fischer esterification reaction. The deprotonation results in the formation of the ester.  

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i) One method of cathodic protection that can be suitable for protecting a buried steel water main from corrosion is impressed current cathodic protection (ICCP).

ii) A typical schematic of ICCP includes Anodes, power source, reference electrode.

i) Justification for ICCP selection:

Impressed current cathodic protection involves the use of an external power source to provide a continuous flow of direct current to the water main, which counteracts the corrosion process. ICCP is a favorable choice for the following reasons:

Efficiency: ICCP offers a high level of corrosion protection and can effectively mitigate corrosion risks for buried structures like water mains.

Long-term protection: Since the water main is not amenable to periodic maintenance, ICCP provides a continuous and reliable method of protection over an extended period.

Flexibility: The current level in ICCP can be adjusted and monitored, allowing for precise control and optimization of protection.

Scalability: ICCP can be applied to protect various sizes and lengths of water mains, making it adaptable to different infrastructure requirements.

ii) Schematic of ICCP:

A typical schematic of ICCP includes the following salient features:

Anodes: Impressed current anodes, such as graphite or mixed metal oxide anodes, are strategically placed along the length of the water main.

Power Source: A power supply unit is connected to the anodes, delivering a controlled direct current.

Reference Electrode: A reference electrode is used to monitor the potential difference between the water main and the electrolyte.

Electrical Connections: Electrical cables connect the anodes, reference electrode, and power supply unit to establish the current flow.

Backfill Material: Adequate backfill material surrounds the water main to ensure proper electrical contact between the anodes and the soil.

This schematic demonstrates the key components and the flow of current necessary for effective cathodic protection of the buried steel water main using ICCP.

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(a) The statement f(130) = 123 means that for a patient weighing 130 pounds, the prescribed dose of the painkiller is 123 milligrams.

This indicates that the function f(W) provides the dosage recommendation based on the weight of the patient.

The statement f'(130) = 3 means that the derivative of the function f(W) with respect to weight, evaluated at 130 pounds, is 3.

This indicates that for every additional pound in weight, the recommended dosage increases by 3 milligrams.

(b) To estimate f(136), we can use the information given in part (a). Since f'(130) = 3, we can approximate the change in dosage per pound as a constant rate of 3 milligrams.

From 130 to 136 pounds, there is an increase of 6 pounds.

Therefore, we can estimate f(136) by adding 6 times the rate of change to the initial dosage of f(130). Thus, f(136) ≈ 123 + (6 × 3) = 141 mg.

Based on this estimation, the recommended dose for a patient weighing 136 pounds would be approximately 141 milligrams.

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(a) The statement f(130) = 123 means that for a patient weighing 130 pounds, the prescribed dose of the painkiller is 123 milligrams.
(b) The recommended dose for a patient weighing 136 pounds would be approximately 141 milligrams.

(a) This indicates that the function f(W) provides the dosage recommendation based on the weight of the patient.

The statement f'(130) = 3 means that the derivative of the function f(W) with respect to weight, evaluated at 130 pounds, is 3.

This indicates that for every additional pound in weight, the recommended dosage increases by 3 milligrams.

The statement f(130) = 123 means that for a patient weighing 130 pounds, the prescribed dose of the painkiller is 123 milligrams.

(b) To estimate f(136), we can use the information given in part (a). Since f'(130) = 3, we can approximate the change in dosage per pound as a constant rate of 3 milligrams.

From 130 to 136 pounds, there is an increase of 6 pounds.

Therefore, we can estimate f(136) by adding 6 times the rate of change to the initial dosage of f(130). Thus, f(136) ≈ 123 + (6 × 3) = 141 mg.

Based on this estimation, the recommended dose for a patient weighing 136 pounds would be approximately 141 milligrams.

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The net cash flow of lease is calculated by subtracting the lease payment tax benefits and the CCA tax shield from the lease payments. In this case, the net cash flow of lease is $4,150.

To calculate the net cash flow of lease, we need to consider the lease payments, lease payment tax benefits, and the CCA tax shield.
Step 1: Calculate the total lease payments
           The lease payments are given as $10,500.
Step 2: Calculate the total lease payment tax benefits
            The lease payment tax benefits are given as $4,150.
Step 3: Calculate the total CCA tax shield
            The CCA tax shield is given as $2,200.
Step 4: Calculate the net cash flow of lease
            To calculate the net cash flow of lease, we subtract the lease payment tax benefits and the CCA tax shield from

            the lease payments.
            Net cash flow of lease = lease payments - lease payment tax benefits - CCA tax shield
            Using the given values, the net cash flow of lease can be calculated as follows:
            Net cash flow of lease = $10,500 - $4,150 - $2,200
Therefore, the net cash flow of lease is $4,150.

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Mass of CO2 in the stack gases = 54.29 g, Mass of H2O in the stack gases = 35.92 g, Mass of N2 in the stack gases = 5.63 g, Mass of O2 in the stack gases = 4.38 g

(a) The complete combustion reaction can be given as shown below:

CS2 + 3 O2 → CO2 + 2 SO2 + heatC2H6 + 7/2 O2 → 2 CO2 + 3 H2O + heat

CH4 + 2 O2 → CO2 + 2 H2O + heat

H2 + 1/2 O2 → H2O + heat

N2 + 1/2 O2 → NO2O2 + heat → O2

(b) The basis of calculation for this problem is a unit mass of the fuel. Hence, the mass of each component of the fuel is calculated based on a mass of 100 g of fuel. The mass of each component of the fuel is given below:

Mass of CS2 in 100 g of fuel = 30 g

Mass of C2H6 in 100 g of fuel = 26 g

Mass of CH4 in 100 g of fuel = 14 g

Mass of H2 in 100 g of fuel = 10 g

Mass of N2 in 100 g of fuel = 10 g

Mass of O2 in 100 g of fuel = 6 g

Mass of CO in 100 g of fuel = 4 g

The total mass of fuel = 30 + 26 + 14 + 10 + 10 + 6 + 4 = 100 g

(c) Based on the mass balance equation of each element, we can derive independent equations. For instance, the mass balance equation for carbon is given below:

Mass of C in the fuel = Mass of C in the stack gases

For CO2: 2 * Mass of C in CS2 + 2 * Mass of C in C2H6 + Mass of C in CH4 = 2 * Mass of C in CO2

For CO: Mass of C in CO = Mass of C in CO

For CH4: Mass of C in CH4 = Mass of C in CO2

For CS2: Mass of C in CS2 = Mass of C in CO2 + Mass of C in SO2

For C2H6: 2 * Mass of C in C2H6 = 2 * Mass of C in CO2 + Mass of C in CO

The equations for other elements can be derived in a similar manner. We can solve these equations to determine the unknowns.

(d) We can use the independent equations from part (c) to solve for the unknowns.

The mass of each component in the stack gases is given below:

Mass of CO2 in the stack gases = 54.29 g

Mass of H2O in the stack gases = 35.92 g

Mass of N2 in the stack gases = 5.63 g

Mass of O2 in the stack gases = 4.38 g

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The metal that is reduced in the given galvanic cell is silver and the standard cell potential is 0.46 V.

A silver metal electrode is added to a silver nitrate solution to form Ag+(aq). The ion will react with the electrons released from the silver metal electrode to form Ag(s) according to the following half-reaction:

Ag⁺(aq) + 1e− → Ag(s)

The standard reduction potential of this half-reaction is +0.80 V, indicating that it has a strong tendency to be reduced. Similarly, copper ion will react with electrons released from the copper electrode to form Cu(s) according to the following half-reaction:

Cu²⁺(aq) + 2e− → Cu(s)

The standard reduction potential of this half-reaction is +0.34 V. We can see that the Ag⁺ ion has a greater tendency to be reduced than the Cu²⁺ ion. Hence, silver is reduced in the given galvanic cell. The standard cell potential is calculated by subtracting the reduction potential of the oxidized half-reaction from that of the reduced half-reaction. Therefore, the standard cell potential is given as follows:

0.80 V - 0.34 V = 0.46 V.

Therefore, the correct answer is option (a) silver, 0.46 V.

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Answer:

-------------------------

Each coordinate of the midpoint is the average of endpoints:

Therefore M is (13, 14).

a. The balanced equation is C₆H₁₂O₆ ⇒ 2C₂H₅OH + 2CO₂

b. Heat of reaction is -1378 KJ/mol.

c. Heat of reaction for reaction with conversion 0.7 is -964.6 KJ/mol.

Given that,

a. We have to find the balanced equation for this reaction.

The balance equation for fermentation of glucose is

C₆H₁₂O₆ ⇒ 2C₂H₅OH + 2CO₂

Therefore, The balanced equation is C₆H₁₂O₆ ⇒ 2C₂H₅OH + 2CO₂

b. We have to calculate the heat of reaction if 20 mol of glucose are degraded in this reaction using standard heat of formation values.

Standard heat of formation of Glucose is 1273.3 KJ/mol

Standard heat of formation of Ethanol is 277.6 KJ/mol

Standard heat of formation of Carbon dioxide is 393.5 KJ/mol

Number of mole of glucose are 20 mole

Number of moles of ethanol formed in complete reaction is 2×20 = 40 mole

Number of moles of Carbon Dioxide formed in complete reaction is 2×20 = 40 mole

Heat of reaction = ΔH (products) – ΔH (reactants)

So,

Heat of products is 40 × (-277.6) + 40 × (-393.5) =  -26,844 KJ/mol

Heat of reactants is 20 × (-1273.3)=  -25,466 KJ/mol

Heat of reaction = -26,844 - (-25,466)= -1378 KJ/mol

Therefore, Heat of reaction is -1378 KJ/mol.

c. Let the reaction does not go to completion.

In the event where the fractional conversion of glucose is 0.7, we must determine the heat of reaction.

The fractional conversion of glucose is 0.7

Number of glucose that will react = 0.7 × 20 = 14 mole

So, only 14 mole of glucose will react. Rest 6 moles would not undergo reaction and there will not be considered.

Number of moles of ethanol formed = 2 × 14= 28 mole

Number of moles of carbon dioxide formed= 28 mole

Now calculation heat of reaction

Heat of products is 28 × (-277.6) + 28 × (-393.5) =  -18790.8 KJ/mol

Heat of reactants is 14 × (-1273.3)=  -17826.2 KJ/mol

Heat of reaction = -18790.8 - (-17826.2)= -964.6 KJ/mol

Therefore, Heat of reaction for reaction with conversion 0.7 is -964.6 KJ/mol.

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To prove the statement that 3 divides (n³ + 5n + 6) for any integer n ≥ 20 using mathematical induction, we will show that the statement holds for the base case (n = 20) and then assume it holds for an arbitrary value of n and prove it for (n + 1).

Base case (n = 20):

Substitute n = 20 into the expression (n³ + 5n + 6):

(20³ + 5 * 20 + 6) = 9266

Since 9266 is divisible by 3 (9266 = 3 * 3088), the statement holds for the base case.

Inductive step:

Assume that the statement holds for an arbitrary value of n, denoted as k, i.e., 3 divides (k³ + 5k + 6).

Now we need to prove that the statement holds for (k + 1), i.e., 3 divides ((k + 1)³ + 5(k + 1) + 6).

Expand the expression ((k + 1)³ + 5(k + 1) + 6):

(k³ + 3k² + 3k + 1 + 5k + 5 + 6) = (k³ + 5k + 6) + (3k² + 3k + 6)

By the induction hypothesis, we know that (k³ + 5k + 6) is divisible by 3. Now we need to show that (3k² + 3k + 6) is also divisible by 3.

Factoring out 3 from (3k² + 3k + 6), we get: 3(k² + k + 2).

Since k² + k + 2 is an integer, we conclude that (3k² + 3k + 6) is divisible by 3.

Therefore, the statement holds for (k + 1).

By the principle of mathematical induction, we have shown that the statement "3 divides (n³ + 5n + 6)" holds for any integer n ≥ 20.

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The time taken for the water level in the tank to drop from 3 to 0.5 meters above the bottom cannot be determined without additional information.

To calculate the time taken, we need to know the flow rate or discharge rate of the water from the tank. This information is not provided in the question. The time taken to drain the tank depends on factors such as the diameter of the outlet pipe, the pressure difference, and any restrictions or obstructions in the flow path.

If we assume a known discharge rate, we can use the principles of fluid mechanics to calculate the time. The volume of water that needs to be drained is the difference in the volume of water between 3 meters and 0.5 meters above the bottom of the tank. The flow rate can be determined using the pipe diameter and other relevant factors. Dividing the volume by the flow rate will give us the time taken.

However, since the discharge rate is not given, we cannot perform the calculation and determine the time taken accurately.

Without knowing the discharge rate or additional information about the flow characteristics, it is not possible to calculate the time taken for the water level in the tank to drop from 3 to 0.5 meters above the bottom.

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The percentage change in real GDP from year 1 to year 2, using the traditional approach, is -98.88%.

The percentage change in nominal GDP from year 1 to year 2 is 5349%, indicating a significant increase in the economy's total output. However, to understand the true change in economic output adjusted for inflation, we need to calculate the real GDP using the traditional approach.

To compute the real GDP for each year using the traditional approach, we use the prices of goods and services in the base year (year 1) to eliminate the effect of price changes. Unfortunately, the specific data for the prices of milk and honey, the goods produced in this hypothetical economy, are not provided. Hence, we cannot calculate the exact real GDP values. However, we can still analyze the percentage change in real GDP.

The percentage change in real GDP from year 1 to year 2 is -98.88%. A negative value indicates a decrease in real GDP, adjusted for inflation. This decline could be a result of factors such as a decrease in the quantity of goods produced, an increase in prices outpacing the increase in nominal GDP, or a combination of both.

Overall, the drastic percentage change in nominal GDP from year 1 to year 2 does not accurately reflect the change in real GDP, which considers the impact of inflation. To obtain a more meaningful understanding of the economy's performance, it is crucial to consider real GDP, which factors in price changes over time.

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The range of the angle θ, measured from the horizontal, can be determined by analyzing the geometry and the desired points of contact on the wall.

To find the range of angle θ, we need to consider the given points B and A on the wall. Point B represents the desired point of contact between the water and the bottom of the wall, while point A represents the desired point of contact on the wall itself. By examining the geometry of the situation, we can determine the necessary angle θ that achieves these conditions.

The angle θ can be visualized as the angle at which the hose needs to be directed in order to achieve the desired water trajectory. By considering the height of the wall, the distance between points B and A, and the range of motion of the hose, we can calculate the required range of θ.

It is important to note that additional factors, such as the velocity of the water exiting the hose and the effects of air resistance, may influence the actual range of the angle. These factors should be taken into account for a more precise analysis.

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The support reactions at points A, B, and C are:

A = 0 kN

B = 430 kN

C = 200 kN.

To find the support reactions at points A, B, and C, we can analyze the equilibrium of forces acting on the beam.

Given the information provided,

Step 1: Calculate the total length and centroid of the beam.

The total length of the beam is 10 m + 5 m + 5 m = 20 m.

The centroid of the beam is

(10 m × 5 kN/m) + (5 m × 15 kN/m) + (5 m × 15 kN/m) / (20 m)

= 10 kN/m.

Step 2: Calculate the total distributed load acting on the beam.

The total distributed load is the product of the centroid and the total length of the beam:

= 10 kN/m * 20 m

= 200 kN.

Step 3: Determine the reaction at point C.

Since there is no load to the right of point C, the reaction at point C will be equal to the total distributed load acting on the beam.

Therefore, the reaction at point C is 200 kN upward.

Step 4: Determine the reaction at point A.

To calculate the reaction at point A, we need to consider the vertical equilibrium of forces.

The reaction at point A can be calculated as:

Reaction at A = Total load - Reaction at C

= 200 kN - 200 kN

= 0 kN

Step 5: Determine the reaction at point B.

To calculate the reaction at point B, we need to consider the moment equilibrium.

Since the second moment of area of segment BC is twice that of segment AB, we can assume that the segment BC contributes twice as much to the moment at point B compared to segment AB.

Let's consider the clockwise moments as positive:

Clockwise moments

= (200 kN × 10 m) + (15 kN/m × 5 m × 2) × (5 m + (5 m / 2))

Counter-clockwise moments = Reaction at B × 5 m

Setting the clockwise moments equal to the counter-clockwise moments, we can solve for the reaction at B:

(200 kN × 10 m) + (15 kN/m × 5 m × 2) × (5 m + (5 m / 2))

= Reaction at B × 5 m

Simplifying the equation:

2000 kNm + 150 kNm = Reaction at B × 5 m

2150 kNm = Reaction at B × 5 m

Solving for the reaction at B:

Reaction at B = 2150 kNm / 5 m

Reaction at B = 430 kN

Therefore, the support reactions at points A, B, and C are:

A = 0 kN

B = 430 kN

C = 200 kN.

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For a T-beam, the width of the flange shall not exceed the width of the span of the beam plus 1.5 times the thickness of the slab.

A T-beam is a type of reinforced concrete beam with a T-shaped cross-section. The top of the T-shaped concrete beam is referred to as the flange, and the vertical stem is referred to as the web. In T-beams, the slab serves as the flange of the T-shaped beam.

The thickness of the flange is determined by the slab thickness, while the stem's thickness is determined by the required shear strength of the beam. The cross-sectional shape of the beam provides advantages like increased resistance to buckling and reduced weight.

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a. Depth of compression block is 633 mm.

b. The ultimate moment capacity of the beam is Mu ≈ 1134.26 kN.m

c. The ultimate moment capacity of the doubly reinforced section is;

1.134 kN.m

A). Depth of compression block

The depth of the compression block can be found using the following formula;

Distance of centroid of tension steel from compression face;

0.85d = 0.85(650)

= 552.5 mm

Distance of centroid of compression steel from compression face;

d’ = 70 mm

Effective depth of the section; d = 650 mm

Therefore;

Depth of compression block = d - d' - 0.5

Φc = 650 - 70 - 0.5(32)

= 633 mm

B). Ultimate moment capacity of the beam

The ultimate moment capacity of the beam can be determined using the formula;

Mu = 0.87fyAst(d-d/2fyAs’(d’-(a’/2)))  

where;

Ast = Area of tension steel

As’ = Area of compression steel

Let Ast = 5 × (π/4)(32)² = 1280 mm²

Let As’ = 3 × (π/4)(28)² = 1848 mm²

Then;

Mu = 0.87 × 344.8 × 1280 × (650 - 650/2 - (0.5 × 32)) + (0.87/0.9) × 344.8 × 1848 × (70 - 70/2 - (0.5 × 28))

= 1134263.28 N.mm ≈ 1134.26 kN.m

C). Ultimate moment capacity of the doubly reinforced section

The answer that most nearly gives the ultimate moment capacity of the doubly reinforced section is; 1.134 kN.m

since the answer to part b is approximately 1134.26 kN.m, rounded off it gives 1.134 kN.m (to 3 significant figures).

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To determine the number of moles of KBr produced from a given amount of K2SO4, we need to use the balanced chemical equation and the stoichiometric coefficients.
From the equation, we can calculate the mole ratio between K2SO4 and KBr to find the answer.

The balanced chemical equation for the reaction between K2SO4 and KBr is as follows:

K2SO4 + 2KBr → 3KBr + K2SO4

From the equation, we can see that for every 1 mole of K2SO4, 3 moles of KBr are produced. This means there is a 1:3 mole ratio between K2SO4 and KBr.

To find the number of moles of KBr produced from 7.92 moles of K2SO4, we can multiply the given amount by the mole ratio:

7.92 moles K2SO4 * (3 moles KBr / 1 mole K2SO4) = 23.76 moles KBr

Therefore, 7.92 moles of K2SO4 will produce 23.76 moles of KBr according to the stoichiometry of the balanced equation.
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When the pH of the solution is slightly greater than the pKa of the indicator. Indicator is a chemical compound that is used to detect the presence or absence of a chemical compound or solution.

The correct option from the given question is; C.

An indicator is a chemical that has a different color in acidic and basic media. Indicators are generally weak acids or bases that dissociate in a different manner from strong acids or bases. Most of the indicators change their colors when the pH of the solution changes.The answer to the given question is;C. When the pH of the solution is slightly greater than the pKa of the indicator. The pH at which the color of the indicator changes is based on the pKa of the indicator.

At the pH equal to the pKa, the ratio of the concentration of the acidic and basic form of the indicator becomes 1:1, and hence the color of the indicator changes.An acid–base titration is a quantitative chemical analysis technique that is used to determine the concentration of an identified solution. It involves the gradual addition of a standard solution to the solution of the unknown concentration in the presence of an indicator that alters color at the endpoint. The color change of an indicator solution occurs when the pH of the solution is slightly greater than the pKa of the indicator.

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Answer:

D. When the pH of the solution is equal to the pKa of the indicator.

Step-by-step explanation:

In acid/base titrations, an indicator is used to determine the endpoint of the titration, which is the point at which the acid and base are stoichiometrically equivalent. The indicator undergoes a color change when the pH of the solution matches the pKa of the indicator.

The pKa of an indicator is the pH at which the indicator is 50% protonated and 50% deprotonated. It is at this point that the indicator undergoes a color change. Therefore, when the pH of the solution is equal to the pKa of the indicator, the color change occurs, indicating the endpoint of the titration.

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The alkali silicate reaction, also known as the alkali-silica reaction (ASR), is a chemical reaction that occurs between alkalis (such as sodium or potassium) present in cement or concrete and reactive forms of silica (such as certain types of aggregates).

This reaction results in the formation of a gel-like substance, which can cause expansion, cracking, and deterioration of the concrete structure over time.

There are no specific calculations involved in the alkali silicate reaction. However, the severity of the reaction can be B by measuring the expansion of the concrete or observing the formation of cracks and other signs of deterioration.

The alkali silicate reaction is a significant concern in the construction industry as it can lead to the degradation of concrete structures. Preventive measures such as using low-alkali cement, incorporating supplementary cementitious materials, and selecting non-reactive aggregates can help mitigate the risk of ASR. Regular monitoring, testing, and maintenance of concrete structures are essential to detect and address any signs of alkali silicate reaction at an early stage. By understanding and managing this reaction, engineers and construction professionals can ensure the durability and longevity of concrete structures.

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The amount of grass sprayed by the sprinkler is approximately 133.142 square feet.

We must determine the area that the water spray covers in order to determine how much grass is sprayed by the sprinkler.

The water spray forms a circular sector, with the sprinkler at the center and the radius representing the distance at which the water is sprayed. The angle of 105° indicates the angle of the sector.

To calculate the area of the circular sector, we can use the formula:

Area = (θ/360°) * π * r^2

where θ is the angle in degrees and r is the radius.

Angle θ = 105°

Radius r = 12 ft

Substituting the values into the formula, we have:

Area = (105°/360°) * π * (12 ft)^2

Calculating the expression:

Area = (105/360) * 3.14159 * (12 ft)^2

Area ≈ 0.2917 * 3.14159 * 144 ft²

Area ≈ 133.142 ft²

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